Aryl sulfonylurea carbamates and thiolcarbamates and salts thereof: herbicidal antidotes
    1.
    发明公开
    Aryl sulfonylurea carbamates and thiolcarbamates and salts thereof: herbicidal antidotes 失效
    芳基磺酰基硫氰酸盐和硫代硫酸盐 AntieotsfürHerbizide。

    公开(公告)号:EP0052856A2

    公开(公告)日:1982-06-02

    申请号:EP81109748.4

    申请日:1981-11-17

    CPC classification number: A01N25/32 C07C311/62 C07C333/10 C07D213/71

    Abstract: Aryl sulfonylureas as new compositions and included in a two-part herbicide system comprising at least one or more thioicarbamate, thiolcarbamate sulfoxide or haloacetanilide herbicide, and as the second part a non-phytotoxic antidotally effective amount of aryl sulfonylurea as an antidote therefor of the formula


    in which X is oxygen or sulfur; n is an integer; R is lower alkyl, lower alkylthio, halogen, trifluoromethyl, cyano, nitro, lower alkyl sulfonyl;
    R 4 is hydrogen, lower alkyl, lower alkoxyalkyl, phenyl and chlorophenyl;
    R 2 is hydrogen, lower alkyl, alkoxyalkyl and phenyl;
    R' is lower alkyl, alkenyl, alkynyl, haloalkyl, alkoxyalkyl, 1-phenylpropenyl, benzyl, chlorobenzyl, haloalkenyl, phenyl and alkyl substituted phenyl; and

    AR is phenyl, benzyl, naphthyl, pyridyl or styryl; and the inorganic base salts sodium, potassium, ammonium and other inorganic salts; and organic base salts thereof.

    Abstract translation: 1-芳基磺酰基-3-烷氧基羰基脲衍生物。 和式(I)的类似物及其与无机碱如Na,K和NH 4盐的盐,以及它们的苯胺,对甲苯胺,苄胺,单 - ,二 - 和三烯丙胺,单 - ,二 - 和三 - 烷基胺 四烷基铵,乙基氨基乙基,单 - ,二 - 和三 - 链烷醇胺,喹啉,异喹啉,乙二胺,苄基三烷基铵,胆碱,肼,N,N-二烷基肼,吗啉和三苄胺盐是新的。 (R)n-Ar-SO 2 -NR 2 -CO-NR 4 -CO-XR1(I)(X为O或S; n为0-3; R为卤素,CF 3,CN,NO 2, 或烷硫基,或低级烷基磺酰基; R4为H,1-4C烷基,2-6C烷氧基烷基,Ph或氯苯基; R2为H,1-4C烷基,2-6C烷氧基烷基或Ph; R1为1-4C烷基, 6C烯基,3-6C炔基,1-4C卤代烷基,2-6C烷氧基烷基,1-苯基丙烯基,苄基,氯苄基,3-6C卤代链烯基或Ph取代的1-4C烷基; Ar是Ph,苄基, 萘基,吡啶基或苯乙烯基)。 (I)是保护作物的解毒剂,尤其是。 大豆作物,抗硫酸氨基甲酸盐,硫代氨基甲酸亚砜和卤代乙酰苯胺类除草剂的损伤,作物对这些除草剂的耐受性可以通过施肥来增加。 (I)给土壤。 应用于0.01-30点。 每1点 的除草剂。 -

    Aryl sulfonylurea carbamates and thiolcarbamates and salts thereof: herbicidal antidotes
    2.
    发明公开
    Aryl sulfonylurea carbamates and thiolcarbamates and salts thereof: herbicidal antidotes 失效
    ARYL SULFONYLUREA碳酸氢盐和硫酸钠及其盐类:除草剂

    公开(公告)号:EP0052856A3

    公开(公告)日:1982-07-28

    申请号:EP81109748

    申请日:1981-11-17

    CPC classification number: A01N25/32 C07C311/62 C07C333/10 C07D213/71

    Abstract: Aryl sulfonylureas as new compositions and included in a two-part herbicide system comprising at least one or more thioicarbamate, thiolcarbamate sulfoxide or haloacetanilide herbicide, and as the second part a non-phytotoxic antidotally effective amount of aryl sulfonylurea as an antidote therefor of the formula
    in which X is oxygen or sulfur; n is an integer; R is lower alkyl, lower alkylthio, halogen, trifluoromethyl, cyano, nitro, lower alkyl sulfonyl; R 4 is hydrogen, lower alkyl, lower alkoxyalkyl, phenyl and chlorophenyl; R 2 is hydrogen, lower alkyl, alkoxyalkyl and phenyl; R' is lower alkyl, alkenyl, alkynyl, haloalkyl, alkoxyalkyl, 1-phenylpropenyl, benzyl, chlorobenzyl, haloalkenyl, phenyl and alkyl substituted phenyl; and AR is phenyl, benzyl, naphthyl, pyridyl or styryl; and the inorganic base salts sodium, potassium, ammonium and other inorganic salts; and organic base salts thereof.

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