公开(公告)号：EP0127976A2

公开(公告)日：1984-12-12

申请号：EP84303401.8

申请日：1984-05-18

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： DiSalvo, Anthony Leonard ,  Tsai, Chung-Chieh

IPC: C08G18/58 ,  C08G18/63 ,  C08F283/10

CPC classification number: C08G18/58 ,  C08G18/63

Abstract: lsocyanate-reactive prepolymers containing at least one terminal epoxide group with an associated secondary hydroxy group and grafted thereto a polymeric moiety derived from polymerizing an ethylenically unsaturated monomer are disclosed. When reacted with isocyanate, these prepolymers form thermoset compositions which comprise oxazolidone groups in the backbone that are separated by ester linkages, urethane linkages in side chains attached to the backbone, and polymeric moieties derived from one or more ethylenically unsaturated monomer grafted to the polymer backbone.

公开(公告)号：EP0077174B1

公开(公告)日：1989-09-06

申请号：EP82305312.9

申请日：1982-10-06

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： DiSalvo, Anthony Leonard ,  Tsai, Chung-Chieh

IPC: C08G59/02 ,  C08G59/18 ,  C08G59/42 ,  C08G59/40 ,  C08G18/58

CPC classification number: C08G59/02 ,  C08G18/58 ,  C08G18/581 ,  C08G2120/00

公开(公告)号：EP0079714A1

公开(公告)日：1983-05-25

申请号：EP82305787.2

申请日：1982-11-01

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Tsai, Chung-Chieh

IPC: C08G59/14 ,  C08G18/58 ,  C08G18/10 ,  C08G18/12

CPC classification number: C08G18/58 ,  C08G18/581 ,  C08G18/6511 ,  C08G2130/00 ,  Y10T428/31601

Abstract: Phase stable compositions containing a paraffinic polyol chain extender, e.g., 1,4-butanediol, and an isocyanate-reactive prepolymer containing hydroxy and epoxy groups are formed by heating the polyol and prepolymer in the presence of one another to yield the phase stable composition. The composition, when reacted with a polyisocyanate, yields poly(oxazolidonelurethane) thermoset compositions.

公开(公告)号：EP0079714B1

公开(公告)日：1987-03-18

申请号：EP82305787.2

申请日：1982-11-01

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： Tsai, Chung-Chieh

IPC: C08G59/14 ,  C08G18/58 ,  C08G18/10 ,  C08G18/12

CPC classification number: C08G18/58 ,  C08G18/581 ,  C08G18/6511 ,  C08G2130/00 ,  Y10T428/31601

公开(公告)号：EP0127976A3

公开(公告)日：1986-05-07

申请号：EP84303401

申请日：1984-05-18

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： DiSalvo, Anthony Leonard ,  Tsai, Chung-Chieh

IPC: C08G18/58 ,  C08G18/63 ,  C08F283/10

CPC classification number: C08G18/58 ,  C08G18/63

Abstract: lsocyanate-reactive prepolymers containing at least one terminal epoxide group with an associated secondary hydroxy group and grafted thereto a polymeric moiety derived from polymerizing an ethylenically unsaturated monomer are disclosed. When reacted with isocyanate, these prepolymers form thermoset compositions which comprise oxazolidone groups in the backbone that are separated by ester linkages, urethane linkages in side chains attached to the backbone, and polymeric moieties derived from one or more ethylenically unsaturated monomer grafted to the polymer backbone.

公开(公告)号：EP0077174A3

公开(公告)日：1983-08-24

申请号：EP82305312

申请日：1982-10-06

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： DiSalvo, Anthony Leonard ,  Tsai, Chung-Chieh

IPC: C08G59/02 ,  C08G59/18 ,  C08G59/42 ,  C08G59/40 ,  C08G18/58

CPC classification number: C08G59/02 ,  C08G18/58 ,  C08G18/581 ,  C08G2120/00

Abstract: A process for the production of a prepolymer containing two terminal epoxide groups and two-non-terminal, secondary hydroxy groups characterised in that it comprises reacting, in a single step, a polyol, an acid anhydride and a diepoxide is disclosed. A composition for the production of a thermoset composition containing oxazolidone and urethane linkages characterised in that it comprises a polyisocyanate and a prepolymer composition comprising a prepolymer containing two terminal epoxy groups and two non-terminal, secondary hydroxy groups is also disclosed. A thermoset composition characterised in that it comprises oxazolidone and urethane linkages in the recurring unit which is essentially free of isocyanurate linkages, the said oxazolidone linkages being present in the polymer backbone and being separated from one another by ester linkages and the said urethane linkages being present in side chains attached to the polymer backbone is further disclosed. The present invention provides advantages over the prior art.

公开(公告)号：EP0077174A2

公开(公告)日：1983-04-20

申请号：EP82305312.9

申请日：1982-10-06

Applicant: STAUFFER CHEMICAL COMPANY

Inventor： DiSalvo, Anthony Leonard ,  Tsai, Chung-Chieh

IPC: C08G59/02 ,  C08G59/18 ,  C08G59/42 ,  C08G59/40 ,  C08G18/58

CPC classification number: C08G59/02 ,  C08G18/58 ,  C08G18/581 ,  C08G2120/00

Abstract: A process for the production of a prepolymer containing two terminal epoxide groups and two-non-terminal, secondary hydroxy groups characterised in that it comprises reacting, in a single step, a polyol, an acid anhydride and a diepoxide is disclosed.
A composition for the production of a thermoset composition containing oxazolidone and urethane linkages characterised in that it comprises a polyisocyanate and a prepolymer composition comprising a prepolymer containing two terminal epoxy groups and two non-terminal, secondary hydroxy groups is also disclosed.
A thermoset composition characterised in that it comprises oxazolidone and urethane linkages in the recurring unit which is essentially free of isocyanurate linkages, the said oxazolidone linkages being present in the polymer backbone and being separated from one another by ester linkages and the said urethane linkages being present in side chains attached to the polymer backbone is further disclosed.
The present invention provides advantages over the prior art.

Abstract translation: 一种制备含有两个末端环氧基团和两个非末端仲羟基的预聚物的方法，其特征在于它包括在单一步骤中使多元醇，酸酐和二环氧化物反应。 ...＆lt;＆lt;用于制备含有恶唑烷酮和氨基甲酸酯键的热固性组合物的组合物，其特征在于其包含多异氰酸酯和包含含有两个末端环氧基和两个非末端仲羟基的预聚物的预聚物组合物 。 一种热固性组合物，其特征在于其在重复单元中包含基本上不含异氰脲酸酯键的恶唑烷酮和氨基甲酸酯键，所述恶唑烷酮键存在于聚合物主链中并通过酯键彼此分离， 所述氨基甲酸酯键存在于与聚合物主链相连的侧链中。 本发明提供了优于现有技术的优点。