公开(公告)号：WO2012061101A1

公开(公告)日：2012-05-10

申请号：PCT/US2011/057609

申请日：2011-10-25

Applicant: STEPAN COMPANY ,  ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  SKELTON, Patti ,  SOOK, Brian ,  WEITGENANT, Jeremy, Aaron ,  WOLFE, Patrick, Shane

Inventor： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  SKELTON, Patti ,  SOOK, Brian ,  WEITGENANT, Jeremy, Aaron ,  WOLFE, Patrick, Shane

IPC: C11D1/28

CPC classification number: C07C303/32 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61K2800/10 ,  A61Q5/12 ,  A61Q19/00 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C07C309/17 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K8/524 ,  C09K8/74 ,  C09K15/28 ,  C11C3/00 ,  C11C3/003 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/143 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Sulfonate compositions are disclosed. The compositions include alkanesulfonates, alkenesulfonates, sultones, and hydroxy-substituted alkanesulfonates. The sulfonates comprise a reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1, 18-dioic acid, or their ester derivatives with a sulfonating or sulfitating agent. In one aspect, the sulfonate composition is a sulfo-estolide made by reacting a metathesis-derived C10-C17 monounsaturated acid or octadecene-1,18-dioic acid with a sulfonating agent, optionally in the presence of a saturated fatty acid. The sulfonates are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), paint additives, antimicrobial compositions, agricultural uses, and oil field applications.

Abstract translation: 公开了磺酸盐组合物。 组合物包括烷基磺酸盐，烷基磺酸盐，磺内酯和羟基取代的烷基磺酸盐。 所述磺酸盐包括由以下给出的C 10 -C 17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与磺化或硫酸化剂的反应产物。 一方面，磺酸盐组合物是通过使选择性衍生的C10-C17单不饱和酸或十八碳烯-1,18-二酸与磺化剂任选地在饱和脂肪酸存在下反应而制备的磺基 - 内酯化物。 磺化物对于各种最终用途是有价值的，包括清洁剂，织物处理，头发调理，个人护理（液体清洁产品，调理棒，口腔护理产品），涂料添加剂，抗微生物组合物，农业用途和油田应用。

公开(公告)号：WO2012061110A1

公开(公告)日：2012-05-10

申请号：PCT/US2011/057626

申请日：2011-10-25

Applicant: STEPAN COMPANY ,  ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  DILLAVOU, Scott ,  WOLFE, Patrick, Shane

Inventor： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  DILLAVOU, Scott ,  WOLFE, Patrick, Shane

IPC: C11D3/32

CPC classification number: C11C3/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C08K5/32 ,  C08K5/41 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/003 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Light-duty liquid detergents derived from metathesized natural oil feedstocks are disclosed. The detergents comprise water, at least one anionic surfactant, and at least one secondary surfactant derived from a metathesis-derived C 10 -C 17 monounsaturated acid or its ester derivatives. In particular, the secondary surfactant is selected from C 10 amidoamines, quaternized C 10 or C 12 amidoamines, C 12 amidoamine oxides, C 12 sulfobetaines, C 12 amidoamine sulfobetaines, and C 12 alkanolamides. The detergents noted above rival or outperform commercial baselines in standard foam tests for liquid detergents, particularly those used for dishwashing.

Abstract translation: 公开了衍生自复分解天然油原料的轻质液体洗涤剂。 洗涤剂包括水，至少一种阴离子表面活性剂和至少一种衍生自复分解衍生的C10-C17单不饱和酸或其酯衍生物的次表面活性剂。 特别地，第二表面活性剂选自C 10酰氨基胺，季铵化C 10或C 12酰氨基胺，C 12酰氨基胺氧化物，C 12磺基甜菜碱，C 12酰氨基胺磺基甜菜碱和C 12链烷醇酰胺。 上述洗涤剂在液体洗涤剂，特别是用于洗碗的洗涤剂的标准泡沫测试中，与对照或优于商业基线相比是优于或优于商业基线。

公开(公告)号：WO2012061098A1

公开(公告)日：2012-05-10

申请号：PCT/US2011/057605

申请日：2011-10-25

Applicant: STEPAN COMPANY ,  ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  GANGULY-MINK, Sangeeta ,  MALEC, Andrew, D. ,  MANUEL, Teresa, C. ,  MASTERS, Ronald, A. ,  MUNIE, Lawrence, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael, R. ,  WEITGENANT, Jeremy, Aaron ,  WHITLOCK, Laura, Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  GANGULY-MINK, Sangeeta ,  MALEC, Andrew, D. ,  MANUEL, Teresa, C. ,  MASTERS, Ronald, A. ,  MUNIE, Lawrence, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael, R. ,  WEITGENANT, Jeremy, Aaron ,  WHITLOCK, Laura, Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C07C211/00

CPC classification number: C07C309/69 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/447 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C04B24/121 ,  C04B24/124 ,  C04B24/16 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C211/63 ,  C07C219/08 ,  C07C229/12 ,  C07C231/12 ,  C07C233/36 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K8/54 ,  C09K8/60 ,  C09K15/22 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Quaternary ammonium, betaine, or sulfobetaine compositions derived from fatty amines, wherein the fatty amine is made by reducing the amide reaction product of of a metathesis-derived C 10 -C 17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives and a secondary amine, are disclosed. Quaternary ammonium, betaine, or sulfobetaine compositions derived from fatty amidoamines, wherein the amidoamine is made by reacting of a metathesis-derived C 10 -C 17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives and an aminoalkyl- substituted tertiary amine, are also disclosed. The quaternized compositions are advantageously sulfonated or sulfitated. In one aspect, the ester derivative of the C 10 - C 17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The quaternary ammonium, betaine, and sulfobetaine compositions and their sulfonated or sulfitated derivatives are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), antimicrobial compositions, agricultural uses, and oil field applications.

Abstract translation: 衍生自脂肪胺的季铵，甜菜碱或磺基甜菜碱组合物，其中脂肪胺是通过还原由复分解衍生的C 10 -C 17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物的酰胺反应产物 和仲胺。 衍生自脂肪酰氨基胺的季铵，甜菜碱或磺基甜菜碱组合物，其中酰氨基胺是由易位素衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与氨基烷基取代的叔碳酸酯 胺也被公开。 季铵化组合物有利地被磺化或硫酸化。 一方面，C10-C17单不饱和酸或十八碳烯-1,18-二酸的酯衍生物是低级烷基酯。 在其它方面，酯衍生物是通过天然油或不饱和甘油三酸酯通过天然油与烯烃的交叉复分解而制备的改性甘油三酸酯。 季铵，甜菜碱和磺基甜菜碱组合物及其磺化或亚硫酸盐衍生物对于各种最终用途是有价值的，包括清洁剂，织物处理，头发调理，个人护理（液体清洁产品，调理棒，口腔护理产品），抗微生物剂 组合物，农业用途和油田应用。

公开(公告)号：WO2016003607A1

公开(公告)日：2016-01-07

申请号：PCT/US2015/034785

申请日：2015-06-09

Applicant: STEPAN COMPANY

Inventor： ALLEN, Dave, R. ,  MALEC, Andrew, D.

IPC: A01N25/30 ,  A01P13/00 ,  A01N57/20

CPC classification number: A01N25/30 ,  A01N57/12 ,  A01N57/20

Abstract: Agricultural compositions having reduced aquatic toxicity are disclosed. The compositions comprise an agricultural active, a monounsaturated C 10 -C 12 fatty amine ethoxylate, and optionally water. The compositions may further comprise an auxiliary surfactant, a solvent, or both. In certain preferred aspects, the agricultural active is a glyphosate salt. Agricultural compositions comprising a monounsaturated C 10 -C 12 fatty amine ethoxylate have good herbicidal efficacy. Unexpectedly, the monounsaturated C 10 -C 12 fatty amine ethoxylates have reduced aquatic toxicity when compared with their saturated analogs.

Abstract translation: 公开了具有降低的水生毒性的农业组合物。 组合物包含农业活性剂，单不饱和C10-C12脂肪胺乙氧基化物和任选的水。 组合物还可以包含辅助表面活性剂，溶剂或两者。 在某些优选方面，农业活性物质是草甘膦盐。 包含单不饱和C10-C12脂肪胺乙氧基化物的农业组合物具有良好的除草效果。 出乎意料的是，与饱和类似物相比，单不饱和C10-C12脂肪胺乙氧基化物具有降低的水生毒性。

公开(公告)号：WO2012061108A1

公开(公告)日：2012-05-10

申请号：PCT/US2011/057622

申请日：2011-10-25

Applicant: STEPAN COMPANY ,  ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  MURPHY, Dennis, S. ,  WOLFE, Patrick, Shane ,  BROWN, Aaron

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  MURPHY, Dennis, S. ,  WOLFE, Patrick, Shane ,  BROWN, Aaron

IPC: C11D3/32

CPC classification number: C11D1/92 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/29 ,  C11D1/62 ,  C11D1/652 ,  C11D1/72 ,  C11D1/74 ,  C11D1/75 ,  C11D1/83 ,  C11D1/86 ,  C11D1/88 ,  C11D1/90 ,  C11D1/94 ,  C11D3/30 ,  C11D3/32 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00 ,  C07C209/14

Abstract: Laundry detergents useful for cold-water cleaning and boosted bargain detergents are disclosed. The detergents include a surfactant composition derived from a metathesis-derived C 10 -C 17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. For fatty alkyl ester sulfonate-containing detergents, the composition is selected from C 10 betaines, C 12 or C 16 amidoamines, C 1 2 ethanolamine amides, C 16 amidoamine sulfonates, C 18 diamidoamine dioxides, quaternized C 18 diamidoamine betaines, sulfonated C 18 low-EO fatty ester alkoxylates, C 18 amidoamine carboxylates, and amidoamine oxides and sulfobetaines derived from cross- metathesis of palm or soybean oil. The bargain detergents include a performance booster selected from C 12 low-EO fatty ester alkoxylate sulfonates, C 18 amidoamine oxide esters, C 18 amidoamine oxide carboxylates, and amidoamine sulfobetaines made from self metathesized palm or soybean oil.

Abstract translation: 公开了用于冷水清洗和增强的便宜清洁剂的洗涤剂。 洗涤剂包括衍生自复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物的表面活性剂组合物。 对于含脂肪烷基酯磺酸盐的洗涤剂，组合物选自C10甜菜碱，C12或C16酰氨基胺，C1 2乙醇胺酰胺，C16酰胺胺磺酸盐，C18二酰胺胺二氧化物，季铵化C18二酰胺胺甜菜碱，磺化C18低EO脂肪酸烷基酯，C18 衍生自棕榈油或大豆油的交叉复分解的酰氨基胺氧化物和磺基甜菜碱。 讨价还价洗涤剂包括选自C12低EO脂肪酸酯烷氧基化物磺酸盐，C18酰氨基胺氧化物酯，C18酰氨基胺氧化物羧酸盐和由自身复分解的棕榈油或大豆油制成的酰氨基胺磺基甜菜碱的性能增强剂。

公开(公告)号：WO2012061103A2

公开(公告)日：2012-05-10

申请号：PCT/US2011/057612

申请日：2011-10-25

Applicant: STEPAN COMPANY ,  ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  MASTERS, Ronald, A. ,  WOLFE, Patrick, Shane

Inventor： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  MASTERS, Ronald, A. ,  WOLFE, Patrick, Shane

IPC: C11D1/12

CPC classification number: C11C3/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Aqueous hard surface cleaner compositions derived from metathesized natural oil feedstocks are disclosed. In one aspect, the compositions comprise at least one anionic surfactant derived from a metathesis-derived C 10 -C 17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. Particular classes of sulfonated materials (e.g., certain amide sulfonates, sulfonated fatty ester alkoxylates, amidoamine sulfonates, amidoamine betaine sulfonates, sulfo-estolides) are identified as having value as the anionic surfactant. In another aspect, aqueous hard surface cleaners comprising at least one nonionic or amphoteric surfactant derived from a metathesis- derived C 10 -C 17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. Particular classes of these surfactants (e.g., certain amides, imidazoline quat sulfonates, fatty ester alkoxylates, and amine oxides, betaines, amidoamine sulfobetaines) are also identified. The aqueous cleaners noted above rival or outperform commercial baselines in a Gardner straight-line washability test. Industrial degreasers comprising a C 10 or C 12 amide solvent and derived from a metathesis-derived C 10 -C 17 monounsaturated acid are superior to commercial standards.

Abstract translation: 公开了衍生自复分解天然油原料的水性硬表面清洁剂组合物。 在一个方面，组合物包含衍生自复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物的至少一种阴离子表面活性剂。 特定类别的磺化材料（例如某些酰胺磺酸盐，磺化脂肪酸酯烷氧基化物，酰氨基胺磺酸盐，酰氨基胺甜菜碱磺酸盐，磺基 - 卤化物）被鉴定为具有值作为阴离子表面活性剂。 在另一方面，公开了包含衍生自复分解衍生的C10-C17单不饱和酸，十八烯-1,18-二酸或其酯衍生物的至少一种非离子或两性表面活性剂的水性硬表面清洁剂。 还鉴定了这些表面活性剂（例如某些酰胺，咪唑啉季铵盐，脂肪酸烷氧基化物和胺氧化物，甜菜碱，酰氨基胺磺基甜菜碱）的特定类别。 在Gardner直线可洗性试验中，上述水性清洁剂在竞争对手或优于商业基线中得到了证实。 由C10或C12酰胺溶剂组成的衍生自复分解衍生的C10-C17单不饱和酸的工业脱脂剂优于商业标准。

公开(公告)号：WO2012061095A1

公开(公告)日：2012-05-10

申请号：PCT/US2011/057602

申请日：2011-10-25

Applicant: STEPAN COMPANY ,  ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MUNIE, Lawrence, A. ,  MURPHY, Dennis, S. ,  SHAPIRO, Irene ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael, R. ,  WHITLOCK, Laura, Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  LUEBKE, Gary ,  LUKA, Renee ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MUNIE, Lawrence, A. ,  MURPHY, Dennis, S. ,  SHAPIRO, Irene ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael, R. ,  WHITLOCK, Laura, Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C07C211/00

CPC classification number: C11D1/66 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A01N57/20 ,  A61K8/41 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C04B24/121 ,  C04B24/124 ,  C04B24/16 ,  C04B28/02 ,  C04B28/14 ,  C04B38/10 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C07C309/69 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/17 ,  C08K5/20 ,  C08K5/32 ,  C08K5/42 ,  C09D5/00 ,  C09D7/63 ,  C09K8/00 ,  C09K8/54 ,  C09K8/584 ,  C09K15/28 ,  C09K2208/32 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/75 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00 ,  C07C11/02

Abstract: Fatty amine compositions made from a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives are disclosed. In another aspect, fatty amidoamines made by reacting a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with an aminoalkyl-substituted tertiary amine are disclosed. The fatty amines or amidoamines are advantageously sulfonated, sulfitated, oxidized, or reduced. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin.

Abstract translation: 公开了由复分解衍生的C10-C17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物制成的脂肪胺组合物。 另一方面，公开了通过使由复分解衍生的C10-C17单不饱和酸，十八烯-1,18-二酸或其酯衍生物与氨基烷基取代的叔胺反应制得的脂肪酰氨基胺。 脂肪胺或酰胺胺有利地被磺化，硫酸化，氧化或还原。 在其它方面，酯衍生物是通过天然油或不饱和甘油三酸酯通过天然油与烯烃的交叉复分解而制备的改性甘油三酸酯。

公开(公告)号：WO2012061092A1

公开(公告)日：2012-05-10

申请号：PCT/US2011/057595

申请日：2011-10-25

Applicant: STEPAN COMPANY ,  ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  BUCHEK, Kelly ,  GANGULY-MINK, Sangeeta ,  HOLLAND, Brian ,  MALEC, Andrew, D. ,  MASTERS, Ronald, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C10L1/18

CPC classification number: C11C3/04 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/39 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/86 ,  A61K8/92 ,  A61Q5/12 ,  A61Q17/005 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/02 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Alkoxylated fatty ester compositions are disclosed. In one aspect, the compositions comprise a reaction product of a metathesis-derived C 10 -C 17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives with one or more alkylene oxides in the presence of an insertion catalyst to give an alkoxylated fatty ester. In another aspect, the metathesis-derived C 10 -C 17 monounsaturated acid, octadecene-1,18-dioic acid, or its ester derivative is reacted with a glycol ether or a glycol ether alkoxylate, to give an alkoxylated fatty ester. In yet another aspect, the metathesis-derived C 10 -C 17 monounsaturated acid or octadecene-1,18-dioic acid is reacted with one or more alkylene oxides to give a fatty acid alkoxylate, followed by etherification of the fatty acid alkoxylate.

Abstract translation: 公开了烷氧基化脂肪酸酯组合物。 在一个方面，组合物包含在插入催化剂存在下由易位素衍生的C 10 -C 17单不饱和酸，十八碳烯-1,18-二酸或其酯衍生物与一种或多种烯化氧的反应产物，得到 烷氧基化脂肪酸酯。 另一方面，将复分解衍生的C10-C17单不饱和酸，十八烯-1,18-二酸或其酯衍生物与二醇醚或二醇醚烷氧基化物反应，得到烷氧基化脂肪酸酯。 另一方面，将来自复分解的衍生的C10-C17单不饱和酸或十八碳烯-1,18-二酸与一种或多种烯化氧反应，得到脂肪酸烷氧基化物，然后醚化脂肪酸烷氧基化物。

公开(公告)号：EP2632891A1

公开(公告)日：2013-09-04

申请号：EP11838503.8

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  ALONSO, Marcos ,  BERNHARDT, Randal, J. ,  BROWN, Aaron ,  GANGULY-MINK, Sangeeta ,  MALEC, Andrew, D. ,  MANUEL, Teresa, C. ,  MASTERS, Ronald, A. ,  MUNIE, Lawrence, A. ,  MURPHY, Dennis, S. ,  SKELTON, Patti ,  SOOK, Brian ,  TERRY, Michael, R. ,  WEITGENANT, Jeremy, Aaron ,  WHITLOCK, Laura, Lee ,  WIESTER, Michael ,  WOLFE, Patrick, Shane

IPC: C07C211/00

CPC classification number: C07C309/69 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/447 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C04B24/121 ,  C04B24/124 ,  C04B24/16 ,  C07C6/04 ,  C07C41/03 ,  C07C43/11 ,  C07C67/26 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C211/63 ,  C07C219/08 ,  C07C229/12 ,  C07C231/12 ,  C07C233/36 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K8/54 ,  C09K8/60 ,  C09K15/22 ,  C09K15/28 ,  C11C3/00 ,  C11C3/08 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Quaternary ammonium, betaine, or sulfobetaine compositions derived from fatty amines, wherein the fatty amine is made by reducing the amide reaction product of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives and a secondary amine, are disclosed. Quaternary ammonium, betaine, or sulfobetaine compositions derived from fatty amidoamines, wherein the amidoamine is made by reacting of a metathesis-derived C10-C17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives and an aminoalkyl-substituted tertiary amine, are also disclosed. The quaternized compositions are advantageously sulfonated or sulfated. In one aspect, the ester derivative of the C10-C17 monounsaturated acid or octadecene-1,18-dioic acid is a lower alkyl ester. In other aspects, the ester derivative is a modified triglyceride made by self-metathesis of a natural oil or an unsaturated triglyceride made by cross-metathesis of a natural oil with an olefin. The quaternary ammonium, betaine, and sulfobetaine compositions and their sulfonated or sulfated derivatives are valuable for a wide variety of end uses, including cleaners, fabric treatment, hair conditioning, personal care (liquid cleansing products, conditioning bars, oral care products), antimicrobial compositions, agricultural uses, and oil field applications.

公开(公告)号：EP2632271A1

公开(公告)日：2013-09-04

申请号：EP11838510.3

申请日：2011-10-25

Applicant: Stepan Company

Inventor： ALLEN, Dave, R. ,  BERNHARDT, Randal, J. ,  MALEC, Andrew, D. ,  WOLFE, Patrick, Shane

IPC: A01N57/18

CPC classification number: C11C3/08 ,  A01N25/02 ,  A01N25/04 ,  A01N25/30 ,  A01N33/12 ,  A01N37/18 ,  A01N37/44 ,  A01N41/04 ,  A61K8/416 ,  A61K8/42 ,  A61K8/44 ,  A61K8/466 ,  A61K8/92 ,  A61Q5/12 ,  A61Q19/10 ,  A62D1/0071 ,  B01F17/0028 ,  B01F17/0057 ,  C07C69/533 ,  C07C69/593 ,  C07C209/12 ,  C07C211/21 ,  C07C219/08 ,  C07C231/12 ,  C07C237/16 ,  C07C303/18 ,  C08G65/2615 ,  C08K5/01 ,  C08K5/20 ,  C09K8/00 ,  C09K15/28 ,  C11C3/00 ,  C11D1/002 ,  C11D1/04 ,  C11D1/28 ,  C11D1/62 ,  C11D1/652 ,  C11D1/74 ,  C11D1/83 ,  C11D1/90 ,  C11D1/92 ,  C11D1/94 ,  C11D3/48 ,  C07C211/63 ,  C07C211/64 ,  C07C233/38 ,  C07C309/14 ,  A01N33/18 ,  A01N39/04 ,  A01N43/653 ,  A01N51/00 ,  A01N57/20 ,  A01N43/40 ,  A01N43/56 ,  A01N53/00

Abstract: Aqueous glyphosate formulations comprising a surfactant derived from metathesized natural oil feedstocks are disclosed. The formulations comprise a glyphosate salt, water, and a surfactant derived from a metathesis-derived C
10 -C
17 monounsaturated acid, octadecene-1,18-dioic acid, or their ester derivatives. The surfactant is selected from C
10 or C
12 amine oxides, C
10 or C
12 quats, C
10 , C
12 , or C
16 amidoamines, C
10 or C
12 amidoamine oxides, C
10 imidazoline quats, C
10 or C
12 amidoamine quats, C
10 , C
12 , or C
16 betaines, C
16 amidoamine betaines, C
18 diamidoamines, C
18 diamidoamine oxides, C
18 diamidoamine diquats, C
18 diamidoamine oxide quats, C
18 diamidoamine oxide betaines, Cis diamidoamine monobetaines, C
18 diamidoamine monobetaine quats, C
18 ester amidoamine quats, and amidoamines and their oxidized or quaternized derivatives made from self- or cross-metathesized palm or soybean oil. The surfactants noted above impart substantial stability to highly concentrated glyphosate formulations at, above, and below room temperature and perform as well or better than commercial alternatives.