公开(公告)号：DE69936370D1

公开(公告)日：2007-08-09

申请号：DE69936370

申请日：1999-03-30

Applicant: SUMITA OPTICAL GLASS

Inventor： YAMAZAKI MASAAKI ,  YAMAMOTO YOSHINORI ,  SAWANOBORI NARUHITO ,  NAGAHAMA SHINOBU

IPC: C03C4/12 ,  C03C3/062 ,  C03C3/064 ,  C03C3/066 ,  C03C3/068 ,  C03C3/076 ,  C03C3/078 ,  C03C3/083 ,  C03C3/085 ,  C03C3/095 ,  C03C3/12 ,  C03C3/14 ,  C03C3/23 ,  C09K11/00 ,  C09K11/08 ,  C09K11/80 ,  G01T1/10

Abstract: An oxide glass capable of exhibiting photostimulated luminescence by excitation by radiation, characterised in that it is capable of exhibiting a long lasting afterglow and has a constitutional composition comprising, at least, terbium oxide (Tb 2 O 3 ) or manganese oxide (MnO), gallium oxide (Ga 2 O 3 ) or aluminium oxide (Al 2 O 3 ), alkali metal oxide or alkaline earth metal oxide and boron oxide (B 2 O 3 ) or silicon oxide (SiO 2 ) and which is represented, in terms of atoms making up the glass, by the following chemical composition (mol%): SiO 2 0 to 70% B 2 O 3 0 to 80% (SiO 2 + B 2 O 3 = 10 to 80%) Tb 2 O 3 0 to 10% MnO 0 to 2% (Tb 2 O 3 + MnO = 0.01 to 10%) Al 2 O 3 0 to 50% Ga 2 O 3 0 to 60% (Al 2 O 3 + Ga 2 O 3 = 5 to 60%) R 2 O 0 to 65% (R: at least one atom selected from Li, Na, K and Cs) R'O 0 to 70% (R': at least one atom selected from Mg, Ca, Sr and Ba) R 2 O + R'O 10 to 70% ZnO 0 to less than 30% Yb 2 O 3 0 to 10% GeO 2 0 to 20% ZrO 2 0 to 5% Ln 2 O 3 0 to 8% (Ln: at least one atom selected from Y, La, Gd, Lu, Sm, Dy, and Tm) and Sb 2 O 3 0 to 1%

公开(公告)号：DE69904390D1

公开(公告)日：2003-01-23

申请号：DE69904390

申请日：1999-04-28

Applicant: SUMITA OPTICAL GLASS CO

Inventor： YAMAMOTO YOSHINORI ,  YAMAZAKI MASAAKI ,  SAWANOBORI NARUHITO ,  NAGAHAMA SHINOBU

IPC: G01T1/10 ,  C03C3/062 ,  C03C3/12 ,  C03C3/23 ,  C03C3/253 ,  C03C4/04 ,  C03C4/06 ,  C03C4/12 ,  C09K11/00 ,  C03C3/068

Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by gamma -rays, X-rays and UV-rays, light emission can be continued for a long time even after stopping the excitation. Furthermore, the long lasting afterglow and photostimulated luminescence oxide glass capable of exhibiting photostimulated luminescence by irradiation of infrared rays or visible rays can be used not only as a material for confirming an infrared laser or controlling an optical axis, but also as a material for recording or reproducing of gamma -ray, X-ray or UV-ray images and further can be used as an optical recording material of a type that can be read. This glass material is represented, in term of atoms making up the glass, by the following chemical composition (mol %):

公开(公告)号：DE69936370T2

公开(公告)日：2008-03-06

申请号：DE69936370

申请日：1999-03-30

Applicant: SUMITA OPTICAL GLASS

Inventor： YAMAZAKI MASAAKI ,  YAMAMOTO YOSHINORI ,  SAWANOBORI NARUHITO ,  NAGAHAMA SHINOBU

IPC: C03C4/12 ,  C03C3/062 ,  C03C3/064 ,  C03C3/066 ,  C03C3/068 ,  C03C3/076 ,  C03C3/078 ,  C03C3/083 ,  C03C3/085 ,  C03C3/095 ,  C03C3/12 ,  C03C3/14 ,  C03C3/23 ,  C09K11/00 ,  C09K11/08 ,  C09K11/80 ,  G01T1/10

Abstract: An oxide glass capable of exhibiting photostimulated luminescence by excitation by radiation, characterised in that it is capable of exhibiting a long lasting afterglow and has a constitutional composition comprising, at least, terbium oxide (Tb 2 O 3 ) or manganese oxide (MnO), gallium oxide (Ga 2 O 3 ) or aluminium oxide (Al 2 O 3 ), alkali metal oxide or alkaline earth metal oxide and boron oxide (B 2 O 3 ) or silicon oxide (SiO 2 ) and which is represented, in terms of atoms making up the glass, by the following chemical composition (mol%): SiO 2 0 to 70% B 2 O 3 0 to 80% (SiO 2 + B 2 O 3 = 10 to 80%) Tb 2 O 3 0 to 10% MnO 0 to 2% (Tb 2 O 3 + MnO = 0.01 to 10%) Al 2 O 3 0 to 50% Ga 2 O 3 0 to 60% (Al 2 O 3 + Ga 2 O 3 = 5 to 60%) R 2 O 0 to 65% (R: at least one atom selected from Li, Na, K and Cs) R'O 0 to 70% (R': at least one atom selected from Mg, Ca, Sr and Ba) R 2 O + R'O 10 to 70% ZnO 0 to less than 30% Yb 2 O 3 0 to 10% GeO 2 0 to 20% ZrO 2 0 to 5% Ln 2 O 3 0 to 8% (Ln: at least one atom selected from Y, La, Gd, Lu, Sm, Dy, and Tm) and Sb 2 O 3 0 to 1%

公开(公告)号：DE69904390T2

公开(公告)日：2003-08-28

申请号：DE69904390

申请日：1999-04-28

Applicant: SUMITA OPTICAL GLASS CO

Inventor： YAMAMOTO YOSHINORI ,  YAMAZAKI MASAAKI ,  SAWANOBORI NARUHITO ,  NAGAHAMA SHINOBU

IPC: G01T1/10 ,  C03C3/062 ,  C03C3/12 ,  C03C3/23 ,  C03C3/253 ,  C03C4/04 ,  C03C4/06 ,  C03C4/12 ,  C09K11/00 ,  C03C3/068

Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by gamma -rays, X-rays and UV-rays, light emission can be continued for a long time even after stopping the excitation. Furthermore, the long lasting afterglow and photostimulated luminescence oxide glass capable of exhibiting photostimulated luminescence by irradiation of infrared rays or visible rays can be used not only as a material for confirming an infrared laser or controlling an optical axis, but also as a material for recording or reproducing of gamma -ray, X-ray or UV-ray images and further can be used as an optical recording material of a type that can be read. This glass material is represented, in term of atoms making up the glass, by the following chemical composition (mol %):

公开(公告)号：DE602004018262D1

公开(公告)日：2009-01-22

申请号：DE602004018262

申请日：2004-10-07

Applicant: SUMITA OPTICAL GLASS

Inventor： YAMAMOTO YOSHINORI ,  TSUCHIYA KOICHI ,  NAGAHAMA SHINOBU ,  SAWANOBORI NARUHITO

IPC: C03C3/253

Abstract: The present invention provides a high refractive index, high dispersion optical glass for precision molding, being free from harmful materials causing environmental problems, such as lead oxide, etc., and having a low yield temperature (At), i.e. at most 580 °C, a refractive index (nd) of at least 1.89 and an Abbe number (½d) of at most 23.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented in terms of for making up the glass, by the following chemical composition (wt%): P 2 O 5 3 to 20 % B 2 O 3 0 to 5 % GeO 2 more than 14 to 37 % Sum of P 2 O 5 + B 2 O 3 + GeO 2 24 to 43 % Li 2 O 0 to 5 % Na 2 O 0 to 8 % K 2 O 0 to 10 % Sum of Li 2 O + Na 2 O + K 2 O 1 to 10 % Nb 2 O 5 0 to 50 % Bi 2 O 3 12 to 67 % BaO 0 to 5 % WO 3 0 to 12 %

公开(公告)号：DE69811324D1

公开(公告)日：2003-03-20

申请号：DE69811324

申请日：1998-12-16

Applicant: SUMITA OPTICAL GLASS

Inventor： YAMAZAKI MASAAKI ,  YAMAMOTO YOSHINORI ,  SAWANOBORI NARUHITO ,  NAGAHAMA SHINOBU

IPC: G21K4/00 ,  C03C3/066 ,  C03C3/068 ,  C03C3/093 ,  C03C3/095 ,  C03C4/04 ,  C03C4/12 ,  C09K11/08 ,  C09K11/63 ,  C09K11/79 ,  G01T1/00

Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by UPSILON -rays, X-rays and/or UV-rays, and light emission can be continued for a time after the excitation has ceased. Furthermore, the long lasting afterglow and photostimulated luminescence oxide glass can be used not only as a phosphorescent material for nigh illumination or a night signal, but also as a material for confirming an infrared laser or controlling an optical axis, because it exhibits photostimulated luminescence by irradiation of infrared rays or visible rays. In addition, this glass is useful for recording or reproducing UPSILON -rays, X-rays or UV-rays images. The oxide glass has a constitutional composition comprising, at least, silicon (Si), boron (B), zinc (Zn) and oxygen (O), and further containing terbium (Tb) or manganese (Mn) as a phosphorescent agent.

公开(公告)号：DE60200080T2

公开(公告)日：2004-08-26

申请号：DE60200080

申请日：2002-06-17

Applicant: SUMITA OPTICAL GLASS

Inventor： OTSUKA MASAAKI ,  YAMAMOTO YOSHINORI ,  TSUCHIYA KOICHI ,  SAWANOBORI NARUHITO ,  NAGAHAMA SHINOBU

IPC: G02B1/00 ,  C03C3/17 ,  C03C4/00

Abstract: The present invention provides an optical glass for press molding, in particular, a low softening point glass which contains, in an oxide glass of phosphate type, a durability improving component in addition to glass forming components, and has a weight loss of at most 0.15 weight % in a durability test, and which is represented, in term of elements for making up the glass, by the following chemical composition (mol %):

公开(公告)号：DE60200080D1

公开(公告)日：2003-12-11

申请号：DE60200080

申请日：2002-06-17

Applicant: SUMITA OPTICAL GLASS

Inventor： OTSUKA MASAAKI ,  YAMAMOTO YOSHINORI ,  TSUCHIYA KOICHI ,  SAWANOBORI NARUHITO ,  NAGAHAMA SHINOBU

IPC: G02B1/00 ,  C03C3/17 ,  C03C4/00

Abstract: The present invention provides an optical glass for press molding, in particular, a low softening point glass which contains, in an oxide glass of phosphate type, a durability improving component in addition to glass forming components, and has a weight loss of at most 0.15 weight % in a durability test, and which is represented, in term of elements for making up the glass, by the following chemical composition (mol %):

公开(公告)号：DE69811324T2

公开(公告)日：2003-10-23

申请号：DE69811324

申请日：1998-12-16

Applicant: SUMITA OPTICAL GLASS

Inventor： YAMAZAKI MASAAKI ,  YAMAMOTO YOSHINORI ,  SAWANOBORI NARUHITO ,  NAGAHAMA SHINOBU

IPC: G21K4/00 ,  C03C3/066 ,  C03C3/068 ,  C03C3/093 ,  C03C3/095 ,  C03C4/04 ,  C03C4/12 ,  C09K11/08 ,  C09K11/63 ,  C09K11/79 ,  G01T1/00

Abstract: The present invention provides an oxide glass capable of exhibiting a long lasting afterglow and photostimulated phosphorescence, whereby energy can be accumulated by radiation excitation, for example, by UPSILON -rays, X-rays and/or UV-rays, and light emission can be continued for a time after the excitation has ceased. Furthermore, the long lasting afterglow and photostimulated luminescence oxide glass can be used not only as a phosphorescent material for nigh illumination or a night signal, but also as a material for confirming an infrared laser or controlling an optical axis, because it exhibits photostimulated luminescence by irradiation of infrared rays or visible rays. In addition, this glass is useful for recording or reproducing UPSILON -rays, X-rays or UV-rays images. The oxide glass has a constitutional composition comprising, at least, silicon (Si), boron (B), zinc (Zn) and oxygen (O), and further containing terbium (Tb) or manganese (Mn) as a phosphorescent agent.

公开(公告)号：EP1603170A4

公开(公告)日：2010-09-22

申请号：EP04719060

申请日：2004-03-10

Applicant: TOYODA GOSEI KK ,  SUMITA OPTICAL GLASS

Inventor： SUEHIRO YOSHINOBU ,  INOUE MITSUHIRO ,  KATO HIDEAKI ,  HADAME KUNIHIRO ,  TOHMON RYOICHI ,  WADA SATOSHI ,  OTA KOICHI ,  AIDA KAZUYA ,  WATANABE HIROKI ,  YAMAMOTO YOSHINORI ,  OHTSUKA MASAAKI ,  SAWANOBORI NARUHITO

IPC: H01L33/48 ,  H01L33/56 ,  H01L33/62 ,  H01L33/00 ,  H01L23/28 ,  H01L31/02

CPC classification number: H01L33/56 ,  C03B23/20 ,  C03C8/24 ,  C03C27/06 ,  H01L24/17 ,  H01L24/45 ,  H01L24/73 ,  H01L2224/14 ,  H01L2224/16225 ,  H01L2224/32225 ,  H01L2224/45144 ,  H01L2224/48091 ,  H01L2224/48227 ,  H01L2224/48237 ,  H01L2224/48247 ,  H01L2224/48257 ,  H01L2224/48465 ,  H01L2224/73204 ,  H01L2224/73265 ,  H01L2224/92125 ,  H01L2224/97 ,  H01L2924/01057 ,  H01L2924/01322 ,  H01L2924/12035 ,  H01L2924/12036 ,  H01L2924/12041 ,  H01L2924/12042 ,  H01L2924/15787 ,  H01L2924/181 ,  H01L2924/3025 ,  H01L2933/005 ,  H01L2924/00014 ,  H01L2924/00 ,  H01L2924/00012

Abstract: A method for manufacturing a solid element device, which comprises providing a glass-containing Al2O3 substrate (3) having a GaN based LED element (2) placed thereon, setting a P2O5-ZnO based low melting point glass in parallel with the substrate, and carrying out a press working at a temperature of 415 DEG C or higher under a pressure of 60 kgf in a nitrogen atmosphere. Under these conditions, the low melting point glass has a viscosity of 10 poise, and is adhered via an oxide formed on the surface of the glass-containing Al2O3 substrate (3). A solid element device manufactured by the above method can be manufactured through a glass sealing working at a low temperature and also has a highly reliable sealing structure.

Abstract translation: 一种固体元件器件的制造方法，其特征在于，提供具有GaN基LED元件（2）的含有玻璃的Al 2 O 3衬底（3），与基板平行地设置P2O5-ZnO系低熔点玻璃，以及 在氮气氛下，在压力为60kgf的温度下进行415℃以上的压力加工。 在这些条件下，低熔点玻璃的粘度为10泊，并通过形成在含玻璃Al 2 O 3衬底（3）的表面上的氧化物粘合。 通过上述方法制造的固体元件装置可以通过在低温下工作的玻璃密封而制造，并且还具有高度可靠的密封结构。