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公开(公告)号:DE69320880T2
公开(公告)日:1999-03-04
申请号:DE69320880
申请日:1993-06-25
Applicant: SUMITOMO CHEMICAL CO
Inventor: KITAMURA MASARU , TSUCHIMOTO KAZUYA , MURATA SHUZO
Abstract: A process is disclosed wherein a zeolite molding having a high mechanical strength is produced by contacting a pentasil type zeolite molding with water.
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公开(公告)号:DE69005376T2
公开(公告)日:1994-06-01
申请号:DE69005376
申请日:1990-06-21
Applicant: SUMITOMO CHEMICAL CO
Inventor: KITAMURA MASARU , ICHIHASHI HIROSHI , SUZUKAMO GOHFU
IPC: B01J37/08 , C01B37/02 , C01B39/04 , C01B39/06 , C01B39/08 , C01B39/12 , C01B39/36 , C01B33/34 , C01B33/18
Abstract: Nitrogen-containing organic compounds are removed from crystalline metallosilicates containing the same by firing the crystalline metalosilicates in the presence of a gas containing molecular oxygen and additionally a lower alcohol represented by the formula (I): R-OH (I) wherein R represents an alkyl group of 1-4 carbon atoms.
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公开(公告)号:DE3785603T2
公开(公告)日:1993-11-18
申请号:DE3785603
申请日:1987-02-27
Applicant: SUMITOMO CHEMICAL CO
Inventor: SATO HIROSHI , HIROSE KENICHI , KITAMURA MASARU , UMADA YOUICHI , ISHII NORIO , TOJIMA HIDETO
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公开(公告)号:DE3785603D1
公开(公告)日:1993-06-03
申请号:DE3785603
申请日:1987-02-27
Applicant: SUMITOMO CHEMICAL CO
Inventor: SATO HIROSHI , HIROSE KENICHI , KITAMURA MASARU , UMADA YOUICHI , ISHII NORIO , TOJIMA HIDETO
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公开(公告)号:FR2619991B1
公开(公告)日:1991-11-15
申请号:FR8811525
申请日:1988-09-02
Applicant: SUMITOMO CHEMICAL CO
Inventor: SIROSITA MASAO , MIZUTANI MASATO , KIMURA SHIGEKO , OGURI YUKIO , KITAMURA MASARU , UMADA YOUICHI , SATO HIROSHI
Abstract: A novel agricultural and horticultural fungicide is disclosed. It contains as an active ingredient at least one crystalline zeolite selected from the group consisting of the faujasite group, the chabazite group and the phillipsite group represented by the formula aCuO.(1-a)M2O.Al2O3.bSiO2.cH2O wherein M represents a sodium and/or potassium atom, and a, b and c fall in the following ranges 0
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公开(公告)号:GB2209469A
公开(公告)日:1989-05-17
申请号:GB8820587
申请日:1988-08-31
Applicant: SUMITOMO CHEMICAL CO
Inventor: SIROSITA MASAO , MIZUTANI MASATO , KIMURA SHIGEKO , OGURI YUKIO , KITAMURA MASARU , UMADA YOUICHI , SATO HIROSHI
Abstract: A novel agricultural and horticultural fungicide is disclosed. It contains as an active ingredient at least one crystalline zeolite selected from the group consisting of the faujasite group, the chabazite group and the phillipsite group represented by the formula aCuO.(1-a)M2O.Al2O3.bSiO2.cH2O wherein M represents a sodium and/or potassium atom, and a, b and c fall in the following ranges 0
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公开(公告)号:DE602005013853D1
公开(公告)日:2009-05-28
申请号:DE602005013853
申请日:2005-06-28
Applicant: SUMITOMO CHEMICAL CO
Inventor: HOSHINO MASAHIRO , KITAMURA MASARU , SUGITA KEISUKE
IPC: C01B39/04 , B01J29/40 , C01B39/40 , C07D201/04
Abstract: The present invention provides a method for manufacturing a zeolite comprising following steps of: (1): calcining crystals obtained by hydrothermal synthesis reaction of a silicon compound; (2): contact treating a calcined product obtained by the step (1) with an aqueous solution including an amine and/or a quaternary ammonium compound; (3): calcining a treated product obtained by the step (2); and (4): contact treating the calcined product obtained by the step (3) with an aqueous solution including ammonia and/or an ammonium salt. According to the present invention, a method is also provided wherein µ-caprolactam is manufactured by Beckmann rearrangement reaction of cyclohexanone oxime in a gaseous phase in the presence of the zeolite manufactured by the above-described method.
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公开(公告)号:DE602005013846D1
公开(公告)日:2009-05-28
申请号:DE602005013846
申请日:2005-02-08
Applicant: SUMITOMO CHEMICAL CO
Inventor: SUGITA KEISUKE , KITAMURA MASARU , HOSHINO MASAHIRO
IPC: B01J38/62 , C07D223/10 , B01J29/035 , B01J29/90 , B01J38/06 , B01J38/08 , B01J38/12 , B01J38/18 , B01J38/66 , C07B61/00 , C07D201/04 , C07D201/14
Abstract: A method for producing epsilon -caprolactam and a method for reactivating a zeolite catalyst for producing epsilon -caprolactam are provided. In the reactivation step, a zeolite catalyst is allowed to contact a gas containing a carboxylic acid, water and a compound selected from ammonia and amines. In accordance with the present invention, the catalytic activities of a zeolite catalyst used for the Beckmann rearrangement reaction of cyclohexanone oxime can be effectively restored. Consequently, epsilon -caprolactam may be produced with a high production yield for a long period of time by reusing the catalyst by the method described above.
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公开(公告)号:DE69230820T2
公开(公告)日:2000-07-27
申请号:DE69230820
申请日:1992-11-26
Applicant: SUMITOMO CHEMICAL CO
Inventor: KAJIKURI HIROSHI , KITAMURA MASARU , HIGASHIO YASUHIKO
IPC: B01J29/04 , C07D201/04
Abstract: epsilon -Caprolactam is prepared by subjecting cyclohexanone oxime in a gas phase to a catalytic reaction using zeolite catalysts in the presence of water and at least one compound selected from alcohols and ether compounds.
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公开(公告)号:DE69005376D1
公开(公告)日:1994-02-03
申请号:DE69005376
申请日:1990-06-21
Applicant: SUMITOMO CHEMICAL CO
Inventor: KITAMURA MASARU , ICHIHASHI HIROSHI , SUZUKAMO GOHFU
IPC: B01J37/08 , C01B37/02 , C01B39/04 , C01B39/06 , C01B39/08 , C01B39/12 , C01B39/36 , C01B33/34 , C01B33/18
Abstract: Nitrogen-containing organic compounds are removed from crystalline metallosilicates containing the same by firing the crystalline metalosilicates in the presence of a gas containing molecular oxygen and additionally a lower alcohol represented by the formula (I): R-OH (I) wherein R represents an alkyl group of 1-4 carbon atoms.
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