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    INSECTICIDAL COMPOUNDS
    1.
    发明申请
    INSECTICIDAL COMPOUNDS 审中-公开
    杀虫剂化合物

    公开(公告)号：WO2009138219A3

    公开(公告)日：2010-01-21

    申请号：PCT/EP2009003395

    申请日：2009-05-13

    Applicant: SYNGENTA PARTICIPATIONS AG ,  CASSAYRE JEROME YVES ,  CORSI CAMILLA ,  PITTERNA THOMAS ,  MAIENFISCH PETER

    Inventor： CASSAYRE JEROME YVES ,  CORSI CAMILLA ,  PITTERNA THOMAS ,  MAIENFISCH PETER

    IPC: C07D401/14 ,  A01N43/40 ,  C07D401/04

    CPC classification number: C07D401/14

    Abstract: A compound of formula (I): wherein R1 is pyrid-4-yl optionally substituted by one to four substituents independently selected from halogen, C1-3 alkyl or C1-3 haloalkyl; R2 is hydrogen, halogen, C1-4 haloalkyl or C1-4 haloalkoxy; R3 is trifluoromethyl, difluoromethyl or difluoromethoxy and R4 is hydrogen, fluoro or chloro, or R3 is fluoro, chloro or bromo and R4 is fluoro, chloro or trifluoromethyl; and R5 is hydrogen or halogen; or salts or N-oxides thereof. Furthermore, the present invention relates to intermediates used to prepare compounds of formula (I), to methods of using them to combat and control insect, acarine, mollusc and nematode pests and to insecticidal, acaricidal, molluscicidal and nematicidal compositions comprising them.

    Abstract translation: 式（I）的化合物：其中R 1是任选被一至四个独立地选自卤素，C 1-3烷基或C 1-3卤代烷基的取代基取代的吡啶-4-基; R2是氢，卤素，C1-4卤代烷基或C1-4卤代烷氧基; R3是三氟甲基，二氟甲基或二氟甲氧基，R4是氢，氟或氯，或R3是氟，氯或溴，R4是氟，氯或三氟甲基; R5为氢或卤素; 或其盐或N-氧化物。 此外，本发明涉及用于制备式（I）化合物的中间体，涉及使用它们来对抗和控制昆虫，螨虫，软体动物和线虫以及包含它们的杀虫，杀螨，杀软体动物和杀线虫组合物的方法。

    METHODS OF PEST CONTROL IN SOYBEAN
    2.
    发明申请
    METHODS OF PEST CONTROL IN SOYBEAN 审中-公开
    大豆病虫害防治方法

    公开(公告)号：WO2014019957A2

    公开(公告)日：2014-02-06

    申请号：PCT/EP2013065821

    申请日：2013-07-26

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： EL QACEMI MYRIEM ,  CASSAYRE JEROME YVES

    IPC: A01N43/80 ,  A01N43/40 ,  A01N43/42 ,  A01N43/48

    CPC classification number: C07D261/04 ,  A01N43/36 ,  A01N43/80 ,  C07D207/20 ,  G06Q30/018

    Abstract: The invention provides methods comprising applying to a crop of soybean plants, the locus thereof, or propagation material thereof, a compound of formula (I) wherein -B1-B2-B3- is -C=N-O-, -C=N-CH2- or -N-CH2-CH2-; Y1, Y2 and Y3 are independently CH or nitrogen; wherein no more than two of Y1, Y2 and Y3 are nitrogen and wherein Y2 and Y3 are not both nitrogen; R9 is C1-C4alkyl, C1-C4haloalkyl, C1-C4alkyl-O-CH2-, C1-C4haloalkyl-O-CH2-,C3-C6cycloalkyl, C3-C6cycloalkyl-CH2-, C1-C4alkyl-S-CH2-, C1-C4alkyl-S(O)-CH2-, or C1-C4alkyl-S(O2)-CH2-; X2 is C-X6 or nitrogen; X1, X3 and X6 are independently hydrogen, halogen or trihalomethyl, wherein at least two of X1, X3 and X6 are not hydrogen; X4 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl. Preferably the methods are for control of stinkbugs, in particular from the genus Euschistus and in particular the species Euschistus heros.

    Abstract translation: 本发明提供了一种方法，其包括向一系列大豆植物，其基因座或其繁殖材料施用式（I）化合物，其中-B1-B2-B3-为-C = NO-，-C = N-CH2 - 或-N-CH 2 -CH 2 - ; Y1，Y2和Y3独立地为CH或氮; 其中Y1，Y2和Y3中不超过两个是氮，并且其中Y2和Y3不都是氮; R9是C1-C4烷基，C1-C4卤代烷基，C1-C4烷基-O-CH2-，C1-C4卤代烷基-O-CH2-，C3-C6环烷基，C3-C6环烷基-CH2-，C1-C4烷基-S-CH2-，C1- C 4烷基-S（O）-CH 2 - 或C 1 -C 4烷基-S（O 2）-CH 2 - ; X2是C-X6或氮; X1，X3和X6独立地为氢，卤素或三卤代甲基，其中X 1，X 3和X 6中的至少两个不是氢; X4是三氟甲基，二氟甲基或氯二氟甲基。 优选地，这些方法用于控制臭椿，特别是来自Euschistus属，特别是Euschistus heros的物种。

    PESTICIDAL MIXTURES COMPRISING ISOXAZOLINE DERIVATIVES
    3.
    发明申请
    PESTICIDAL MIXTURES COMPRISING ISOXAZOLINE DERIVATIVES 审中-公开
    包含ISOXAZOLINE衍生物的农药混合物

    公开(公告)号：WO2011154494A2

    公开(公告)日：2011-12-15

    申请号：PCT/EP2011059586

    申请日：2011-06-09

    Applicant: SYNGENTA PARTICIPATIONS AG ,  DUTTON ANA CRISTINA ,  CASSAYRE JEROME YVES ,  HAAS ULRICH JOHANNES

    Inventor： DUTTON ANA CRISTINA ,  CASSAYRE JEROME YVES ,  HAAS ULRICH JOHANNES

    IPC: A01P7/04

    CPC classification number: A01N43/80 ,  A01N43/38 ,  A01N43/40 ,  A01N43/54 ,  A01N43/88 ,  A01N43/90 ,  A01N45/02 ,  A01N53/00 ,  A01N2300/00 ,  A01N47/06 ,  A01N47/40 ,  A01N51/00

    Abstract: The present invention provides pesticidal mixtures comprising a component A, a component B and a component C, wherein component A is a compound of formula (I) wherein one of Y1 and Y2 is S, SO or SO2 and the other is CH2; L is a direct bond or methylene; A1 and A2 are C-H, or one of A1 and A2 is C-H and the other is N; R1 is hydrogen or methyl; R2 is chlorodifluoromethyl or trifluoromethyl; R3 is 3,5-dibromo-phenyl, 3,5-dichloro-phenyl, 3,4-dichloro-phenyl, or 3,4,5-trichloro-phenyl; R4 is methyl; R5 is hydrogen; or R4 and R5 together form a bridging 1,3-butadiene group; component B is a compound selected from Sedaxane, Fludioxonil, Metalaxyl, Mefenoxam, Cyprodinil, Azoxystrobin, Tebuconazole, Difenoconazole, Thiabendazole, Fluopyram, Penflufen, N-[9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide and Fuxapyroxad; or component B is a compound selected from Tefluthrin, Lambda-cyhalothrin, Abamectin, Spinosad, Spinetoram, Chlorpyrifos, Thiodicarb, Chlorantraniliprole, Cyantraniliprole, Bacillus firmus, Bacillus subtilis, Pasteuria spp. such as P. penetrans and P. nishizawae, Imidacloprid, Thiacloprid, Acetamiprid, Nitenpyram, Dinotefuran, Thiamethoxam, Clothianidin, Nithiazine, Flonicamid, Fipronil, Pyrifluquinazone, Pymetrozine, Sulfoxaflor and Spirotetramat; and component C is a compound selected from an insecticide, a fungicide and a nematicide, which insecticide is selected from neonicotinoids, carbamates, diamides, spinosyns, phenylpyrazoles, pyrethroids, Pyrifluquinazone, Pymetrozine, Sulfoxaflor and Spirotetramat; which fungicide is selected from Azoxystrobin, Trifloxystrobin, Fluoxastrobin, Cyproconazole, Difenoconazole, Prothioconazole, Tebuconazole, Triticonazole, Fludioxonil, Thiabendazole, Ipconazole, Cyprodinil, Myclobutanil, Metalaxyl, Mefenoxam, Sedaxane, N-[9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-methanonaphthalen-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, Fluopyram, Penflufen, Fuxapyroxad, Fluopyram, and Penthiopyrad; which nematicide is selected from Abamectin, carbamate nematicides organophosphorous nematicides, Captan, Thiophanate-methyl, Thiabendazole, a compound of formula (X), wherein n is 0, 1 or 2 and the thiazole ring may be optionally substituted, Bacillus spp., Streptomyces spp. and Pasteuria spp.; Pochonia spp., Metarhizium spp.; wherein components B and C are different. The invention also provides methods of using the mixtures in the field of agriculture.

    Abstract translation: 本发明提供了包含组分A，组分B和组分C的农药混合物，其中组分A是式（I）化合物，其中Y1和Y2之一是S，SO或SO2，另一个是CH2; L是直接键或亚甲基; A1和A2是C-H，A1和A2之一是C-H，另一个是N; R1是氢或甲基; R2是氯二氟甲基或三氟甲基; R3是3,5-二溴 - 苯基，3,5-二氯 - 苯基，3,4-二氯 - 苯基或3,4,5-三氯苯基; R4是甲基; R5是氢; 或R4和R5一起形成桥连1,3-丁二烯基团; 组分B是选自Sedaxane，Fludioxonil，甲霜灵，Mefenoxam，Cyprodinil，Azoxystrobin，Tebuconazole，Difenoconazole，噻苯达唑，Fluopyram，Penflufen，N- [9-（二氯亚甲基）-1,2,3,4-四氢-1,1- 4-甲基萘-5-基] -3-（二氟甲基）-1-甲基-1H-吡唑-4-甲酰胺和Fuxapyroxad; 或组分B是选自三氟氯氰菊酯，三氯氟氰菊酯，阿维菌素，多杀菌素，丝裂霉素，毒死蜱，硫代萜，氯虫胺，氰托吡尼，芽孢杆菌，枯草芽孢杆菌，巴斯德毕赤氏菌的化合物。 如吡虫啉和西沙星，吡虫啉，噻虫啉，吖啶啶，Nitenpyram，Dinotefuran，Thiamethoxam，Clothianidin，Nithiazine，Flonicamid，Fipronil，Pyrifluquinazone，Pymetrozine，Sulfoxaflor和Spirotetramat; 并且组分C是选自杀虫剂，杀真菌剂和杀线虫剂的化合物，该杀虫剂选自新烟碱类，氨基甲酸酯类，二酰胺类，多杀菌素类，苯基吡唑类，拟除虫菊酯类，焦磷酸酯类，吡草胺类，磺呋酮类和Spirotetramat; 哪种杀真菌剂选自嘧菌酯，三氟嘧菌酯，氟草胺，莨菪碱，二苯唑康唑，丙硫菌唑，戊唑醇，三唑菌唑，氟妥乃尼，噻苯达唑，依普康唑，Cyprodinil，Myclobutanil，甲霜灵，Mefenoxam，Sedaxane，N- [9-（二氯亚甲基） （二氟甲基）-1-甲基-1H-吡唑-4-甲酰胺，氟吡嘧啶，Penflufen，Fuxapyroxad，Fluopyram和Penthiopyrad; 所述杀线虫剂选自阿维菌素，氨基甲酸酯杀线虫剂有机磷杀线虫剂，卡普坦，硫代甲基甲基，噻苯达唑，式（X）化合物，其中n为0,1或2，噻唑环可任选被取代，芽孢杆菌属，链霉菌属 属。 和巴斯德毕赤氏菌 马鞭草属，Metarhizium spp。 其中组分B和C不同。 本发明还提供了在农业领域中使用混合物的方法。

    PESTICIDAL MIXTURES
    4.
    发明申请
    PESTICIDAL MIXTURES 审中-公开
    农药混合物

    公开(公告)号：WO2013087710A3

    公开(公告)日：2013-11-07

    申请号：PCT/EP2012075257

    申请日：2012-12-12

    Applicant: SYNGENTA PARTICIPATIONS AG

    Inventor： EL QACEMI MYRIEM ,  CASSAYRE JEROME YVES

    IPC: A01N43/26 ,  A01N53/00

    CPC classification number: A01N43/80 ,  A01N37/38 ,  A01N43/36 ,  A01N43/38 ,  A01N47/06 ,  A01N53/00 ,  A01N2300/00

    Abstract: The present invention relates to pesticidal mixtures comprising a component A and a component B, wherein component A is a compound of formula (I) wherein B1, B2, B3, X1, X2, X3, X4, Y1, Y2, Y3 and R9 are as defined in claim 1 and component B is an insecticide. The present invention also relates to methods of using said mixtures for the control of plant pests.

    Abstract translation: 本发明涉及包含组分A和组分B的杀虫混合物，其中组分A是式（I）的化合物，其中B1，B2，B3，X1，X2，X3，X4，Y1，Y2，Y3和R9为 如权利要求1所定义，组分B是杀虫剂。 本发明还涉及使用所述混合物来控制植物害虫的方法。

    PESTICIDAL MIXTURES INCLUDING ISOXAZOLINE DERIVATIVES
    5.
    发明申请
    PESTICIDAL MIXTURES INCLUDING ISOXAZOLINE DERIVATIVES 审中-公开
    农药混合物包括异辛唑衍生物

    公开(公告)号：WO2011154434A2

    公开(公告)日：2011-12-15

    申请号：PCT/EP2011059445

    申请日：2011-06-08

    Applicant: SYNGENTA PARTICIPATIONS AG ,  CASSAYRE JEROME YVES ,  MOLITOR ELVIRA

    Inventor： CASSAYRE JEROME YVES ,  MOLITOR ELVIRA

    IPC: A01P7/04

    CPC classification number: A01N43/80 ,  A01N43/40 ,  A01N43/54 ,  A01N43/58 ,  A01N43/653 ,  A01N43/56 ,  A01N47/24 ,  A01N2300/00

    Abstract: The present invention provides pesticidal mixtures comprising a component A and a component B, wherein component A is an enantiomeric mixture of a compound of formula (I) that is enantiomerically enriched for the S enantiomer wherein the symbol * indicates the chiral centre; wherein A1, A2, R1, R2, R4, R5, R6 and p are as defined in claim 1, and component B is a fungicide as defined in claim 1. The present invention also relates to methods of using said mixtures for the control of plant pests.

    Abstract translation: 本发明提供了包含组分A和组分B的杀虫混合物，其中组分A是对映体富集S对映异构体的式（I）化合物的对映体混合物，其中符号*表示手性中心; 其中A1，A2，R1，R2，R4，R5，R6和p如权利要求1中所定义，组分B是权利要求1中定义的杀真菌剂。本发明还涉及使用所述混合物来控制 植物害虫

    PROCESSES FOR THE PREPARATION OF THIETANAMINE
    6.
    发明申请
    PROCESSES FOR THE PREPARATION OF THIETANAMINE 审中-公开
    制备THETETANINE的过程

    公开(公告)号：WO2013007582A2

    公开(公告)日：2013-01-17

    申请号：PCT/EP2012063080

    申请日：2012-07-05

    Applicant: SYNGENTA PARTICIPATIONS AG ,  CASSAYRE JEROME YVES ,  GODINEAU EDOUARD ,  BOUSSEMGHOUNE MOHAMED ABDELOUAHAB ,  SMITS HELMARS

    Inventor： CASSAYRE JEROME YVES ,  GODINEAU EDOUARD ,  BOUSSEMGHOUNE MOHAMED ABDELOUAHAB ,  SMITS HELMARS

    IPC: C07D331/04 ,  C07D409/12

    CPC classification number: C07D331/04 ,  C07D409/04 ,  C07D409/12

    Abstract: The present invention provides processes for the preparation of compounds of formula (I) including processes comprising a. reacting a compound of formula (II) with a nucleophile in the presence of water to give a compound comprising a thietane moiety in which the carbon atom at the 3 position of the thietane moiety is bonded to a nitrogen atom; wherein the nucleophile is selected the group consisting of: N3 -, a sulfonamide having two hydrogen atoms bound to the nitrogen atom, a diimide having a hydrogen atom bound to the nitrogen atom or an anion thereof, NH2OH and NH3; and b. when the nucleophile used in step a. is N3 - or NH2OH, reacting the compound produced in step a. with a suitable reducing agent to give a compound of formula (I); or when the nucleophile used in step a. is a sulfonamide, reacting the compound produced in step a. with a reagent suitable for cleaving the S-N bond of the sulfonamide group to give a compound of formula (I); or when the nucleophile used in step a. is a diimide, reacting the compound produced in step a. with a reagent suitable for cleaving the C-N bond of the amide group to give a compound of formula (I). The invention also relates to intermediates useful for the preparation of compounds of formula (I).

    Abstract translation: 本发明提供了制备式（I）化合物的方法，包括包含以下步骤的方法：a。 使式（II）化合物与亲核试剂在水存在下反应，得到包含硫杂丁环部分的化合物，其中硫杂环丁烷部分的3位碳原子与氮原子键合; 其中所述亲核试剂选自：N 3 - ，具有与氮原子结合的两个氢原子的磺酰胺，具有与氮原子结合的氢原子的二酰亚胺或其阴离子，NH 2 OH和NH 3; 和b。 当在步骤a中使用亲核试剂时。 是N 3 - 或NH 2 OH，使步骤a中产生的化合物反应。 与合适的还原剂反应，得到式（I）化合物; 或者当步骤a中使用的亲核试剂时。 是磺酰胺，使步骤a中产生的化合物反应。 用适于裂解磺酰胺基团的S-N键的试剂得到式（I）化合物; 或者当步骤a中使用的亲核试剂时。 是二酰亚胺，使步骤a中产生的化合物反应。 与适于裂解酰胺基团的C-N键的试剂反应，得到式（I）化合物。 本发明还涉及用于制备式（I）化合物的中间体。

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