公开(公告)号：JP2013152825A

公开(公告)日：2013-08-08

申请号：JP2012012431

申请日：2012-01-24

Applicant: Sony Corp ,  ソニー株式会社

Inventor： KAWASHIMA ATSUMICHI

IPC: H01M10/0525 ,  H01M4/13 ,  H01M4/36 ,  H01M4/485 ,  H01M4/58 ,  H01M4/62 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/44

CPC classification number: Y02E60/122 ,  Y02T10/7011

Abstract: PROBLEM TO BE SOLVED: To suppress decomposition of an electrolyte near a positive electrode under a high temperature environment.SOLUTION: A battery comprises a positive electrode and an electrolyte, and a phosphorus compound having a P-OH structure is added to at least one of the positive electrode and the electrolyte. As a result of the addition of the phosphorus compound, a protective coating film containing, as a main component, at least one of phosphate derived from the phosphorus compound having the P-OH structure and a metal salt of its derivative is formed on the surface of at least one of the positive electrode and a positive electrode active material as the battery is charged and discharged. The addition of the phosphorus compound having the P-OH structure is particularly effective in a battery which contains, as a negative electrode active material, a lithium transition metal compound having a Spinel structure. The electrolyte is preferably held by a polymer material, thereby making an illiquid electrolyte. This electrolyte is particularly effective in application to a battery having positive and negative electrodes and an electrolyte sheathed by a laminate film.

Abstract translation: 要解决的问题：在高温环境下抑制正电极附近的电解质分解。解决方案：电池包括正电极和电解质，并且将具有P-OH结构的磷化合物加入至 正极和电解液。 作为添加磷化合物的结果，在表面上形成以含有P-OH结构的磷化合物及其衍生物的金属盐为主成分的至少一种磷酸盐保护膜 作为电池的正极和正极活性物质中的至少一个被充放电。 具有P-OH结构的磷化合物的添加在含有作为负极活性物质的具有尖晶石结构的锂过渡金属化合物的电池中是特别有效的。 电解质优选由聚合物材料保持，从而制成非液体电解质。 这种电解质对于具有正极和负极的电池以及由层压膜包覆的电解液是特别有效的。

公开(公告)号：JP2013152824A

公开(公告)日：2013-08-08

申请号：JP2012012430

申请日：2012-01-24

Applicant: Sony Corp ,  ソニー株式会社

Inventor： KAWASHIMA ATSUMICHI

IPC: H01M10/0525 ,  H01M4/36 ,  H01M4/485 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/44 ,  H02J3/38 ,  H02J7/34

CPC classification number: Y02E60/122 ,  Y02T10/7011

Abstract: PROBLEM TO BE SOLVED: To suppress decomposition of an electrolyte under a high temperature environment.SOLUTION: A battery comprises an electrolyte containing: a solvent; an electrolytic salt; and an additive agent which is decomposed at a counter electrode lithium potential of 1.6 to 2.5 V to form a coating film on the negative electrode. The electrolyte is particularly effective in the case of using a negative electrode active material whose potential in a fully charged condition is 1.0 to 1.6 V in terms of the counter electrode lithium potential. The additive agent preferably contains a cyclic carboxylic acid anhydride. The electrolyte preferably contains 0.1 to 1.0 mass% of the cyclic carboxylic acid. The electrolyte is preferably held by a polymer material, thereby making an illiquid electrolyte. This electrolyte is particularly effective in application to a battery having positive and negative electrodes and an electrolyte sheathed by a laminate film.

Abstract translation: 要解决的问题：为了抑制电解质在高温环境下的分解。解决方案：电池包括含有溶剂的电解质; 电解盐; 以及相对电极锂电位分解1.6〜2.5V的添加剂，在负极上形成涂膜。 在使用负极活性物质的情况下，电解质是特别有效的，其负极活性物质的电位在相对电极锂电位方面为1.0〜1.6V。 添加剂优选含有环状羧酸酐。 电解质优选含有0.1〜1.0质量％的环状羧酸。 电解质优选由聚合物材料保持，从而制成非液体电解质。 这种电解质对于具有正极和负极的电池以及由层压膜包覆的电解液是特别有效的。

公开(公告)号：JP2011204666A

公开(公告)日：2011-10-13

申请号：JP2010233925

申请日：2010-10-18

Applicant: Sony Corp ,  ソニー株式会社

Inventor： KAWASHIMA ATSUMICHI ,  WATANABE HARUO ,  ARAKI NORITOSHI ,  SUGITA SHUHEI ,  KATAYAMA SHINICHI ,  NAKAI HIDEKI

IPC: H01M10/0567 ,  H01M4/13 ,  H01M4/131 ,  H01M4/36 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0565

CPC classification number: H01M10/02 ,  Y02E60/122

Abstract: PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte battery improving charge-discharge cycle characteristics and suppressing gas evolution in high temperature storage, and to provide a nonaqueous electrolyte.SOLUTION: The nonaqueous electrolyte battery includes a positive electrode, a negative electrode, and the nonaqueous electrolyte containing a solvent and an electrolyte salt. The nonaqueous electrolyte contains the solvent and the electrolyte salt, and the solvent contains a halogenated cyclic carbonate or an unsaturated cyclic carbonate. A polyacid and/or a polyacid compound are/is contained in the battery. In order to obtain gas generation-suppressing effect even at high charging voltage, the polyacid and/or the polyacid compound, and the halogenated cyclic carbonate such as 4-chloro-1,3-dioxolane-2-on are contained in the battery.

Abstract translation: 要解决的问题：提供一种改善充放电循环特性并抑制高温储存中的气体放出的非水电解质电池，并提供非水电解质。溶液：非水电解质电池包括正极，负极和 含有溶剂的非水电解质和电解质盐。 非水电解质含有溶剂和电解质盐，溶剂含有卤代环状碳酸酯或不饱和环状碳酸酯。 电池中包含多酸和/或多酸化合物。 为了即使在高充电电压下也能获得气体产生抑制效果，电池中包含多酸和/或多酸化合物以及4-氯-1,3-二氧戊环-2-酮等卤代环状碳酸酯。

公开(公告)号：JP2011048987A

公开(公告)日：2011-03-10

申请号：JP2009195589

申请日：2009-08-26

Applicant: Sony Corp ,  ソニー株式会社

Inventor： SAITO SHUNSUKE ,  YAMADA ICHIRO ,  KAWASHIMA ATSUMICHI ,  KUBOTA TADAHIKO

IPC: H01M4/13 ,  H01M2/16 ,  H01M4/62 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0585 ,  H01M10/0587

CPC classification number: H01M10/058 ,  H01M4/139 ,  H01M4/366 ,  H01M10/0565 ,  H01M10/0583 ,  H01M2004/027 ,  H01M2300/0082 ,  Y02E60/122 ,  Y02P70/54 ,  Y10T29/49115

Abstract: PROBLEM TO BE SOLVED: To provide a negative electrode in which swelling-suppression effect during storage under a high temperature can be demonstrated sufficiently, a non-aqueous electrolyte secondary battery, and a manufacturing method of the non-aqueous electrolyte secondary battery. SOLUTION: The negative electrode 21 has a negative electrode current collector 21A and a negative electrode active material layer 21B that covers at least one of the main faces of the negative electrode current collector 21A and contains at least a negative electrode active material 211. The negative electrode active material 211 contained in a region from the surface of the negative electrode active material layer 21B up to at least 50% thickness is the negative electrode active material 213 with a film having the solid electrolyte film. The solid electrolyte film contains a product formed by cross-linking reaction of isocyanate groups of isocyanate compounds. COPYRIGHT: (C)2011,JPO&INPIT

Abstract translation: 要解决的问题：提供一种能够充分证明高温储存期间的溶胀抑制效果的负极，非水电解质二次电池以及非水电解质二次电池的制造方法 。

解决方案：负极21具有负极集电体21A和负极活性物质层21B，负极活性物质层21B覆盖负极集电体21A的至少一个主面，并且至少含有负极活性物质211 包含在从负极活性物质层21B的表面到至少50％厚度的区域中的负极活性物质211是具有固体电解质膜的膜的负极活性物质213。 固体电解质膜含有通过异氰酸酯化合物的异氰酸酯基团的交联反应形成的产物。 版权所有（C）2011，JPO＆INPIT

公开(公告)号：JP2009224282A

公开(公告)日：2009-10-01

申请号：JP2008070298

申请日：2008-03-18

Applicant: Sony Corp ,  ソニー株式会社

Inventor： SAITO SHUNSUKE ,  KUBOTA TADAHIKO ,  KAWASHIMA ATSUMICHI

IPC: H01M2/02 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569

CPC classification number: Y02E60/122

Abstract: PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte battery capable of effectively restraining battery expansion at the time of storage at high temperature on the battery where lithium composite oxide with high nickel contents is used as a positive electrode active material.
SOLUTION: An electrolyte is impregnated in a separator 15. The electrolyte includes, for example, a solvent and electrolyte salt dissolved in the solvent. The solvent formed by a nonaqueous solvent contains cyclic pyrrolidone derivative such as 1-methyl-2-pyrrolidone.
COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 解决的问题：提供一种非水电解质电池，其能够在使用高镍含量的锂复合氧化物作为正极活性物质的电池的高温保存时有效地抑制电池膨胀。 解决方案：电解质浸渍在隔板15中。电解质包括例如溶解在溶剂中的溶剂和电解质盐。 由非水溶剂形成的溶剂含有1-甲基-2-吡咯烷酮等环状吡咯烷酮衍生物。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2009224281A

公开(公告)日：2009-10-01

申请号：JP2008070292

申请日：2008-03-18

Applicant: Sony Corp ,  ソニー株式会社

Inventor： SAITO SHUNSUKE ,  KUBOTA TADAHIKO ,  KAWASHIMA ATSUMICHI

IPC: H01M2/02 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568

CPC classification number: Y02E60/122

Abstract: PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte battery capable of restraining an battery expansion at the time of storage at high temperature in spite of the battery at a high discharging state of ≥4.30 volts.
SOLUTION: An electrolyte is impregnated into a separator 15. The electrolyte includes, for example, a solvent and electrolyte salt dissolved in the solvent. The solvent formed by a nonaqueous solvent contains cyclic pyrrolidone derivative such as 1-methyl-2-pyrrolidone.
COPYRIGHT: (C)2010,JPO&INPIT

Abstract translation: 要解决的问题：提供一种非电解电池电池，即使电池处于高于4.30伏的高放电状态，也能够在高温下储存时抑制电池膨胀。 电解质浸渍在隔膜15中。电解质包括例如溶解在溶剂中的溶剂和电解质盐。 由非水溶剂形成的溶剂含有1-甲基-2-吡咯烷酮等环状吡咯烷酮衍生物。 版权所有（C）2010，JPO＆INPIT

公开(公告)号：JP2009099449A

公开(公告)日：2009-05-07

申请号：JP2007271313

申请日：2007-10-18

Applicant: Sony Corp ,  ソニー株式会社

Inventor： KAWASHIMA ATSUMICHI

IPC: H01M10/0565 ,  H01M10/0566 ,  H01M10/0567

CPC classification number: Y02E60/12

Abstract: PROBLEM TO BE SOLVED: To provide a non-aqueous electrolytic liquid capable of improving charge and discharge efficiency while suppressing thermal expansion under a high-temperature environment, and a non-aqueous secondary battery.
SOLUTION: This is a non-aqueous electrolytic liquid secondary battery having a positive electrode, a negative electrode as well as a non-aqueous electrolytic liquid, and the non-aqueous electrolytic liquid contains a halogenated cyclocarbonyl compound of any of formulae (1)-(4).
COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：提供一种能够在抑制高温环境下的热膨胀的同时提高充放电效率的非水电解液和非水二次电池。 解决方案：这是一种具有正极，负极和非水电解液的非水电解液二次电池，非水电解液含有任何式（Ⅴ）的卤化环羰基化合物， 1） - （4）。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008305771A

公开(公告)日：2008-12-18

申请号：JP2007172719

申请日：2007-06-29

Applicant: Sony Corp ,  ソニー株式会社

Inventor： KAWASHIMA ATSUMICHI

IPC: H01M10/0565 ,  H01M10/0567

CPC classification number: Y02E60/12

Abstract: PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte battery with its swelling restrained at high-temperature storage.
SOLUTION: In the nonaqueous electrolyte battery provided with electrolyte solution together with a cathode and an anode, the electrolyte solution contains chlorine-substituted carboxylate expressed in formula (1). In the formula (1), Y, Z are C
m H
2m+1-n X
n (0≤m≤4, 0≤n≤2m+1, X is at least either F, Cl, or Br), and M is either one out of Li, Na, K, Rb, Cs, Ag, 1/2Be, 1/2Mg, and 1/2Ca, 1/2Sr, 1/2Ba, 1/2Zn, 1/2Cd, 1/2Hg, 1/2Sn, 1/2Pb.
COPYRIGHT: (C)2009,JPO&INPIT

Abstract translation: 要解决的问题：提供一种非水电解质电池，其在高温储存时被抑制。 解决方案：在与阴极和阳极一起设置电解液的非水电解质电池中，电解质溶液含有式（1）表示的氯取代的羧酸盐。 在式（1）中，Y，Z分别为C H 2m + 1-n （0≤m≤4,0 ≤n≤2m+ 1，X至少为F，Cl或Br），M为Li，Na，K，Rb，Cs，Ag，1 / 2Be，1 / 2Mg和1 / 2Ca，1 / 2Sr，1 / 2Ba，1 / 2Zn，1 / 2Cd，1 / 2Hg，1 / 2Sn，1 / 2Pb。 版权所有（C）2009，JPO＆INPIT

公开(公告)号：JP2008192391A

公开(公告)日：2008-08-21

申请号：JP2007023813

申请日：2007-02-02

Applicant: Sony Corp ,  ソニー株式会社

Inventor： KAWASHIMA ATSUMICHI ,  KUBOTA TADAHIKO ,  KITA AKINORI

IPC: H01B1/06 ,  H01M2/02 ,  H01M6/16 ,  H01M10/05 ,  H01M10/052 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/0569

CPC classification number: Y02E60/122

Abstract: PROBLEM TO BE SOLVED: To provide a nonaqueous electrolyte composition capable of suppressing swelling of a battery housing in a high temperature storage without adding divinyl sulfone, and a nonaqueous electrolyte secondary battery using such a nonaqueous electrolyte composition. SOLUTION: By adding electrolyte salt, cyclic carboxylic acid ester such as γ-butyrolactone, and halogenated cyclic carbonate such as fluoroethylene carbonate in a nonaqueous solvent so that the content in the nonaqueous solvent becomes 0.1% or more and less than 1% and 0.5% or more and less than 5% by weight ratio respectively, the nonaqueous electrolyte composition is made and by using such a nonaqueous electrolyte composition, the nonaqueous electrolyte secondary battery is obtained. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 解决的问题：提供一种能够在不添加二乙烯基砜的情况下提供能够抑制电池壳体在高温储存器中的溶胀的非水电解质组合物，以及使用这种非水电解质组合物的非水电解质二次电池。 解决方案：通过在非水溶剂中加入电解质盐，γ-丁内酯等环状羧酸酯和氟代碳酸亚乙酯等卤代环状碳酸酯，使非水溶剂的含量成为0.1％以上且小于1％ 和0.5％以上且小于5％的重量比，制造非水电解质组合物，通过使用这种非水电解质组合物，得到非水电解质二次电池。 版权所有（C）2008，JPO＆INPIT

公开(公告)号：JP2007257961A

公开(公告)日：2007-10-04

申请号：JP2006079695

申请日：2006-03-22

Applicant: Sony Corp ,  ソニー株式会社

Inventor： YAMAGUCHI AKIRA ,  KAWASHIMA ATSUMICHI ,  IHARA MASAYUKI ,  HORIUCHI HIROSHI ,  YAMAGUCHI HIROYUKI ,  KUBOTA TADAHIKO ,  TAKAGI KUMIKO

IPC: H01M6/16 ,  H01M10/05 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569

CPC classification number: H01M10/0587 ,  H01B1/122 ,  H01M6/166 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/4235

Abstract: PROBLEM TO BE SOLVED: To provide electrolyte solution capable of improving battery characteristics even at high temperature, and a battery using the same. SOLUTION: A separator 23 has the electrolyte solution impregnated. The electrolyte solution contains cyclic imide salt such as 1,1,2,2,3,3-hexafluoropropane-1,3-disulfonimide lithium, and light metal salt such as difluoro[oxolato-O,O'] boric acid or bis[oxolato-O,O'] boric acid. COPYRIGHT: (C)2008,JPO&INPIT

Abstract translation: 要解决的问题：即使在高温下也能提供能够改善电池特性的电解质溶液，以及使用其的电池。 解决方案：分离器23具有浸渍的电解质溶液。 电解质溶液包含环状酰亚胺盐，例如1,1,2,2,3,3-六氟丙烷-1,3-二磺酰亚胺锂，和轻金属盐如二氟[氧代醇 - O，O']硼酸或双[ oxolato-O，O']硼酸。 版权所有（C）2008，JPO＆INPIT