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    SPECTROMETER WITH VALIDATION CELL
    1.
    发明申请
    SPECTROMETER WITH VALIDATION CELL 审中-公开
    带有验证单元的光谱仪

    公开(公告)号：WO2012054095A1

    公开(公告)日：2012-04-26

    申请号：PCT/US2011/024919

    申请日：2011-02-15

    Applicant: SPECTRASENSORS, INC. ,  FEITISCH, Alfred ,  KELLER, Lutz ,  LIU, Xiang ,  SCHREMPEL, Mathias ,  HELBLEY, Keith, Benjamin

    Inventor： FEITISCH, Alfred ,  KELLER, Lutz ,  LIU, Xiang ,  SCHREMPEL, Mathias ,  HELBLEY, Keith, Benjamin

    IPC: G01N21/35 ,  G01N21/61

    CPC classification number: G01J3/28 ,  G01J3/42 ,  G01N21/031 ,  G01N21/274 ,  G01N21/31 ,  G01N21/3504 ,  G01N21/3518 ,  G01N21/39 ,  G01N2021/399

    Abstract: A valid state of an analytical system that includes a light source (102) and a detector (106) can be verified by determining that deviation of first light intensity data quantifying a first intensity of light received at the detector from the light source after the light has passed at least once through each of a reference gas in a validation cell (114) and a zero gas from a stored data set does not exceed a pre-defined threshold deviation. The stored data set can represent at least one previous measurement collected during a previous instrument validation process performed on the analytical system. The reference gas can include a known amount of an analyte. A concentration of the analyte in a sample gas in a measurement cell (112) can be determined by correcting second light intensity data quantifying a second intensity of the light received at the detector after the light passes at least once through each of the reference gas in the validation cell and a sample gas containing an unknown concentration of the analyte compound. Related systems, methods, and articles of manufacture are also described.

    Abstract translation: 包括光源（102）和检测器（106）的分析系统的有效状态可以通过确定量化光检测器上接收的第一光强与光源之后的光的第一光强度数据的偏差来验证 已经通过至少一次通过验证单元（114）中的参考气体，并且来自存储的数据集的零气体不超过预定义的阈值偏差。 存储的数据集可以表示在分析系统上执行的先前的仪器验证过程期间收集的至少一个以前的测量。 参考气体可以包括已知量的分析物。 测量单元（112）中的样本气体中的分析物的浓度可以通过校正第二光强度数据来确定，该第二光强数据定量在光通过至少一次通过每个参考气体之后在检测器处接收的光的第二强度 验证单元和含有未知浓度的分析物的样品气体。 还描述了相关系统，方法和制品。

    SPECTROMETER WITH RANDOM BEAM PROFILES
    2.
    发明申请
    SPECTROMETER WITH RANDOM BEAM PROFILES 审中-公开
    带有随机光束轮廓的光谱仪

    公开(公告)号：WO2016179318A1

    公开(公告)日：2016-11-10

    申请号：PCT/US2016/030833

    申请日：2016-05-04

    Applicant: SPECTRASENSORS, INC.

    Inventor： FEITISCH, Alfred ,  DORN, Peter ,  TEDESCO, James ,  LIU, Xiang

    IPC: G01N21/03 ,  G01J3/42 ,  G01N21/39 ,  G01N21/3504

    CPC classification number: G01N21/39 ,  G01J3/0208 ,  G01N21/031 ,  G01N21/3504 ,  G01N2021/399 ,  G01N2201/0612 ,  G01N2201/0633

    Abstract: A spectrometer includes a light source configured to emit a beam along a beam path through a sample volume comprising an analyte. Also included is at least one detector positioned to detect at least a portion of the beam emitted by the light source, and at least one reflector positioned along the beam path intermediate the light source and the at least one detector having a surface roughness greater than a predefined level such as 20 Å RMS.

    Abstract translation: 光谱仪包括被配置为沿着光束路径发射通过包含分析物的样品体积的光束的光源。 还包括至少一个检测器，其被定位成检测由光源发射的光束的至少一部分，以及沿光束路径定位的至少一个反射器，其位于光源之间，并且至少一个检测器具有大于 预定义的水平，例如20？RMS。

    SPECTROMETER WITH ACTIVE BEAM STEERING
    3.
    发明申请
    SPECTROMETER WITH ACTIVE BEAM STEERING 审中-公开
    具有活动光束转向的光谱仪

    公开(公告)号：WO2016028401A1

    公开(公告)日：2016-02-25

    申请号：PCT/US2015/039668

    申请日：2015-07-09

    Applicant: SPECTRASENSORS, INC.

    Inventor： FEITISCH, Alfred ,  LIU, Xiang ,  HELBLEY, Keith, Benjamin ,  BEYER, Douglas

    IPC: G01J3/02 ,  G01J3/42

    CPC classification number: G01J3/0205 ,  G01J3/0237 ,  G01J3/027 ,  G01J3/0278 ,  G01J3/0291 ,  G01J3/42 ,  G01J2003/421 ,  G01N21/31 ,  G01N2201/06113 ,  G01N2201/062

    Abstract: A spectrometer includes a light source that emits a beam into a sample volume comprising an absorbing medium. Thereafter, at least one detector detects at least a portion of the beam emitted by the light source. It is later determined, based on the detected at least a portion of the beam and by a controller, that a position and/or an angle of the beam should be changed. The beam emitted by the light source is then actively steered by an actuation element under control of the controller. In addition, a concentration of the absorbing media can be quantified or otherwise calculated (using the controller or optionally a different processor that can be local or remote). The actuation element(s) can be coupled to one or more of the light source, a detector or detectors, and a reflector or reflectors intermediate the light source and the detector(s).

    Abstract translation: 光谱仪包括将光束发射到包括吸收介质的样品体积中的光源。 此后，至少一个检测器检测由光源发射的光束的至少一部分。 随后基于检测到的梁的至少一部分和由控制器确定梁的位置和/或角度应被改变。 然后在控制器的控制下由光源发射的光束被致动元件主动地导向。 此外，可以量化或以其他方式计算吸收介质的浓度（使用控制器或可选择地可以是本地或远程的不同处理器）。 致动元件可以耦合到光源，检测器或检测器中的一个或多个，以及在光源和检测器之间的反射器或反射器。

    COLLISIONAL BROADENING COMPENSATION USING REAL OR NEAR-REAL TIME VALIDATION IN SPECTROSCOPIC ANALYZERS
    5.
    发明申请
    COLLISIONAL BROADENING COMPENSATION USING REAL OR NEAR-REAL TIME VALIDATION IN SPECTROSCOPIC ANALYZERS 审中-公开
    在光谱分析仪中使用实时或近似实时时间验证的冲突广播补偿

    公开(公告)号：WO2013142737A1

    公开(公告)日：2013-09-26

    申请号：PCT/US2013/033383

    申请日：2013-03-21

    Applicant: SPECTRASENSORS, INC.

    Inventor： FEITISCH, Alfred ,  LIU, Xiang ,  HUANG, Hsu-hung ,  JI, Wenhai ,  CLINE, Richard, L.

    IPC: G01N21/35

    CPC classification number: G01J3/0297 ,  G01J3/42 ,  G01N21/05 ,  G01N21/274 ,  G01N21/3504 ,  G01N21/39 ,  G01N2021/0314 ,  G01N2021/399 ,  G01N2201/1211 ,  G01N2201/1218 ,  G01N2201/127

    Abstract: Validation verification data quantifying an intensity of light reaching a detector of a spectrometer from a light source of the spectrometer after the light passes through a validation gas across a known path length can be collected or received. The validation gas can include an amount of an analyte compound and an undisturbed background composition that is representative of a sample gas background composition of a sample gas to be analyzed using a spectrometer. The sample gas background composition can include one or more background components. The validation verification data can be compared with stored calibration data for the spectrometer to calculate a concentration adjustment factor, and sample measurement data collected with the spectrometer can be modified using this adjustment factor to compensate for collisional broadening of a spectral peak of the analyte compound by the background components. Related methods, articles of manufacture, systems, and the like are described.

    Abstract translation: 验证验证数据可以收集或接收在光通过已知路径长度的验证气体之后，量化从光谱仪的光源到达光谱仪的检测器的光强度。 验证气体可以包括一定量的分析物化合物和未受干扰的背景组合物，其代表使用光谱仪分析的样品气体的样品气体背景组成。 样品气体背景组合物可以包括一种或多种背景组分。 验证验证数据可以与存储的光谱仪的校准数据进行比较，以计算浓度调节因子，并且可以使用该调整因子修改用光谱仪收集的样品测量数据，以补偿分析物化合物的光谱峰的碰撞展宽 背景组件。 描述了相关方法，制品，系统等。

    DYNAMIC RECONSTRUCTION OF A CALIBRATION STATE OF AN ABSORPTION SPECTROMETER
    10.
    发明申请
    DYNAMIC RECONSTRUCTION OF A CALIBRATION STATE OF AN ABSORPTION SPECTROMETER 审中-公开
    吸收光谱仪校准状态的动态重建

    公开(公告)号：WO2015167961A1

    公开(公告)日：2015-11-05

    申请号：PCT/US2015/027574

    申请日：2015-04-24

    Applicant: SPECTRASENSORS, INC.

    Inventor： LIU, Xiang ,  LEWISON, John ,  JI, Wenhai ,  FEITISCH, Alfred

    IPC: G01N21/3504 ,  G01J3/28 ,  G01J3/42 ,  G01N21/27 ,  G01N21/39 ,  G01J3/433 ,  G01N21/03 ,  G01N33/00

    CPC classification number: G01N21/39 ,  G01J3/433 ,  G01J2003/2873 ,  G01N21/031 ,  G01N21/274 ,  G01N21/3504 ,  G01N2021/399 ,  G01N2201/127

    Abstract: A reference harmonic absorption curve of a laser absorption spectrometer can have a reference curve shape derived from a reference signal generated by the detector in response to light passing from the laser light source through a reference gas or gas mixture. The reference gas or gas mixture can include one or more of a target analyte and a background gas expected to be present during analysis of the target analyte. One or more portions of a test harmonic absorption curve having a test curve shape is compared with one or more portions of the reference harmonic absorption curve arising due to absorption of the background gases and not by absorption of the target analyte. Operating and/or analytical parameters of the laser absorption spectrometer are adjusted to correct the test curve shape to reduce the difference between the test curve shape and the reference curve shape.

    Abstract translation: 激光吸收光谱仪的参考谐波吸收曲线可以具有根据由检测器响应于从激光源通过参考气体或气体混合物的光而产生的参考信号导出的参考曲线形状。 参考气体或气体混合物可以包括目标分析物和预期在目标分析物的分析期间存在的背景气体中的一种或多种。 将具有测试曲线形状的测试谐波吸收曲线的一个或多个部分与由于背景气体的吸收而不是通过吸收目标分析物而产生的参考谐波吸收曲线的一个或多个部分进行比较。 调整激光吸收光谱仪的操作和/或分析参数以校正测试曲线形状，以减小测试曲线形状与参考曲线形状之间的差异。

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