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公开(公告)号:KR810001794B1
公开(公告)日:1981-11-14
申请号:KR790000202
申请日:1979-01-24
Applicant: TEXACO DEVELOPMENT CORP
Inventor: WADDILL H
IPC: C08G59/56
Abstract: Epoxy resins with improved tensile strength and adhesion comprise a vicinal polyepoxide of epoxy equiv.>1.8, polyamine crosslinking agent, and [RNHCONH[CH(R1) CH2O n 2Z (R = H, C1-6 alkyl, monocyclic aryl, alkaryl, C6-8 aralkyl, alkenyl, or alkadienyl; R1 = H, Me, or Et; Z = (CH2)2-5; and n is chosen to give a mol. wt. of 2000-3000).
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公开(公告)号:KR810001048B1
公开(公告)日:1981-09-07
申请号:KR770002647
申请日:1977-11-11
Applicant: TEXACO DEVELOPMENT CORP
Inventor: WADDILL H , SCHULZE HEINZ
IPC: C08G59/00
Abstract: A poly(oxypropylene) diamine (I) was treated with urea, PhNCO, HCO2H, or BzOH to prep. poly(oxypropylene)diureides or diamides which were used as additives to improve the thermal shock resistance of epoxy resins hardened with methyl-5-norbornene-2,3-dicarboxylic anhydride. Thus, 1980g I (mol. wt. 2000, 1.01 mequiv. HN2/g) and 180g urea were heated at 130oC-134≦̸C for 2 hr, treated with 990 g I during 3hr at 132oC, and heated at 134oC for 70min to prep. a diurea.
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公开(公告)号:KR810001793B1
公开(公告)日:1981-11-14
申请号:KR790000749
申请日:1979-03-13
Applicant: TEXACO DEVELOPMENT CORP
Inventor: WADDILL H
IPC: C08G59/50
Abstract: Epoxy resing are hardened with an adduct of the epoxy resin and Jeffamine D 230 BPA or Jeffamine D 400 BPA (aminopropyl derivs. of a polyoxypropylenepolyamine). The hardeners have low volatility and toxicity and give rapid hardening. The epoxy resins also contain Jeffamine BuD 2000 (bisureide of polyoxyalkylenepolyamine) which prevents embrittlement of the hardened resin. The resins are esp. useful as adhesives.
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公开(公告)号:KR810001536B1
公开(公告)日:1981-10-27
申请号:KR780001876
申请日:1978-06-20
Applicant: TEXACO DEVELOPMENT CORP
Inventor: WADDILL H
IPC: C08G59/18
Abstract: Epoxy resins with improved tensile strength and adhesion were prepd. by mixing epoxy resin, crosslinking agent and [R-NHCONH[CH(R1)CH2O n 2Z (R = H, C1-6 alkly, monocyclic, aryl; R1 = H, Me, Et; Z = (CH2)2-5; n = 2000-3000). Thus, a diureido-terminated polyether was prepd. by treating 500 g Jeffamine D2000(I) with 65 g urea 2 hr at 130-134oC. The crude product was stripped at 175-180oC and 2mnHg to give a viscous residuce contg. 1.64 % N. The residuce 5,3-aminopropylethylene diamine 12, and 4,4'-isopropylidenebisphenol diglycidly ether 100 parts were mixed to give a curable epoxy adhesive.
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公开(公告)号:BR7804205A
公开(公告)日:1979-02-28
申请号:BR7804205
申请日:1978-06-30
Applicant: TEXACO DEVELOPMENT CORP
Inventor: WADDILL H
IPC: C08G59/00 , C08G59/50 , C08G59/56 , C08G65/333 , C08L63/00 , C08L77/00 , C09J163/00 , C08G71/00
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公开(公告)号:BE875133A
公开(公告)日:1979-09-27
申请号:BE194249
申请日:1979-03-27
Applicant: TEXACO DEVELOPMENT CORP
Inventor: WADDILL H
Abstract: A process for the accelerated cure of an epoxy resin is disclosed. The resulting epoxy resin may be used in protective coatings, adhesives, seamless and terrazo flooring and caulking and sealing compositions. The resulting resin is also useful, for example, in casting, potting, in escapulating, grouting and patching. The process involves mixing an epoxy resin of the polyhydric phenol, polyglycidyl ether type with a curing agent comprising the reaction product of an epoxy resin with an excess of an aminoalkylene derivative of a polyoxyalkylenepolyamine.
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公开(公告)号:BR7900295A
公开(公告)日:1979-09-11
申请号:BR7900295
申请日:1979-01-17
Applicant: TEXACO DEVELOPMENT CORP
Inventor: WADDILL H
IPC: C08G59/00 , C08G59/50 , C08G65/333 , C08L63/00 , C08L71/02 , C09J163/00 , C08L63/02 , C09J3/14
Abstract: The adhesion properties of amine-cured epoxy resins are enhanced by addition of certain polyether diureide additives in combination with specific amine curing agents. The adhesively superior epoxy resin composition comprises a vincinal polyepoxide, a curing amount of an aminopropyl ethylenediamine curing agent, and an effective amount of a polyether diureide having terminal ureido or monosubstituted ureido groups and a molecular weight of from about 2000 to about 3000.
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公开(公告)号:BR7707718A
公开(公告)日:1978-07-18
申请号:BR7707718
申请日:1977-11-21
Applicant: TEXACO DEVELOPMENT CORP
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公开(公告)号:BR8005841A
公开(公告)日:1981-05-19
申请号:BR8005841
申请日:1980-09-12
Applicant: TEXACO DEVELOPMENT CORP
Inventor: WADDILL H
Abstract: A novel epoxy resin curing system comprises salicylic acid and methyliminobispropylamine (MIBPA). The resins comprise a vicinal polyepoxide and a curing amount of salicylic acid and MIBPA.
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