Abstract:
An improved burner (10) for partial oxidation process gas generators is provided which has annular passages (26) formed between coaxially aligned conduits (13, 24) extending from upstream sources to the downstream reaction zone. An outer coolant jacket (21), internally baffled (22) from optimum coolant flow and sized for minimum downstream area surrounds a recessed and fuel/oxidizer delivery conduit (13) ending in a nozzle. The central delivery conduit(13) is not attached to the coolant jacket and the annular space between them (26) is connected to a high pressure supply of relatively inert gas which can periodically be vented through the annular space to prevent slag build up on the nozzle (20) or coolant jacket (21).
Abstract:
A gasifier (10) for partially combusting a carbonaceous fuel mixture in the combustion chamber (13) of the gasifier (10). The latter includes a water bath (26) into which the hot effluent or the products of combustion are immersed, including a synthetic gas. The products of combustion are directed into the bath (26) by way of a constricted throat section (31). To avoid excessive erosion action and/or thermal shock to the throat section (31) as a result of exposure to the effluent's high temperatures, the throat section (31) is structured with an internal framework of pipes (32). The framework (32) is communicated with a pressurized source of a cooling fluid (42), preferably water, whereby to cool the throat section (31) sufficiently to counteract the ill effects of exposure to contact with the high temperature effluent.
Abstract:
The progress and completion of slag removal from the quench chamber (26) of a partial oxidation reactor (10) during controlled oxidation can be monitored by measuring such quench water parameters as pH, conductivity, total dissolved solids, and sulfate concentration.
Abstract:
A selective deslagging operation is conducted in a partial oxidation reactor wherein a first predetermined portion of the reactor is selectively deslagged by derivatization while limiting derivatizing slag conditions in a second predetermined portion of the reactor. Selective deslagging can be accomplished by controlled oxidation conditions in the reactor that vary from one predetermined portion of the reactor to another. Thus, the slag present in one predetermined portion is derivatized and fluidized for removal from the reactor at a faster rate than the slag present in another portion of the reactor, which is not derivatized or is subjected to more limited derivatizing slag conditions. Derivatized slag can be differentiated from non-derivatized slag that does not flow or more limited derivatized slag that has a lower mass flow rate then the derivatized slag at conditions of controlled oxidation. The derivatized slag can then be selectively removed because it has attained a lower fluidizing temperature.
Abstract:
Slag deposits in partial oxidation reactors, like coke gasifiers, are removed by controlling temperature and slag derivatization. Derivatized slag is fluidized and leaves the reactor without solidifying in and filling the reactor outlet.
Abstract:
A gasifier for partially combusting a carbonaceous fuel mixture in the combustion chamber of the gasifier. The latter includes a water bath into which the hot effluent or products of combustion are immersed, including a synthetic gas. The products of combustion are directed into the bath by way of a constricted throat section. To avoid excessive erosion action and/or thermal shock to the throat section as a result of exposure to the effluent's high temperatures, the throat section is structured with an internal framework of pipes. The framework is communicated with a pressurized source of a cooling fluid, preferably water, whereby to cool the throat section sufficiently to counteract the ill effects of exposure to contact with the high temperature effluent.