公开(公告)号：EP0853977B1

公开(公告)日：2003-10-08

申请号：EP98300250.2

申请日：1998-01-14

Applicant: The Standard Oil Company

Inventor： Brazdil, James Frank, Jr. ,  Bartek, Joseph Peter

IPC: B01J23/22 ,  B01J23/18 ,  C07C253/24

CPC classification number: C07D213/84 ,  B01J23/18 ,  B01J23/22 ,  C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C255/08 ,  C07C255/51

公开(公告)号：EP0000617B1

公开(公告)日：1981-08-12

申请号：EP78300066.4

申请日：1978-06-22

Applicant: THE STANDARD OIL COMPANY

Inventor： Grasselli, Robert Karl ,  Bartek, Joseph Peter

IPC: C07C13/465 ,  C07C5/48

CPC classification number: B01J27/18 ,  C07C5/48 ,  C07C13/465

公开(公告)号：EP0853977A1

公开(公告)日：1998-07-22

申请号：EP98300250.2

申请日：1998-01-14

Applicant: THE STANDARD OIL COMPANY

Inventor： Brazdil, James Frank, Jr. ,  Bartek, Joseph Peter

IPC: B01J23/22 ,  B01J23/18 ,  C07C253/24

CPC classification number: C07D213/84 ,  B01J23/18 ,  B01J23/22 ,  C07C253/24 ,  C07C253/26 ,  Y02P20/52 ,  C07C255/08 ,  C07C255/51

Abstract: A method of preparing a catalyst having the elements and the proportions indicated by the following empirical formula:

        VSb m A a D d O x

   where

A is one or more Ti, Sn, where Sn is always present
D is one or more Li, Mg, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn,
Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al
and Mn wherein
m is 0.5 to 10
a is greater than zero to 10
d is zero to 10
x is determined by the oxidation state of the cations present,
comprising making an aqueous slurry of a mixture of source batch materials comprising compounds of said elements to be included in the final catalyst, followed by drying and heat calcining the mixture to an active catalyst, wherein the source batch material for the tin is a solution which comprises SnO 2 ·xH 2 O wherein x ≥ 0 dispersed in tetraalkyl ammonium hydroxide wherein the tetraalkyl ammonium hydroxide is defined by the following formula:

        C n H 2n+1 NOH

   wherein 5 ≥ n ≥ 1,
drying said slurry and calcining the mixture to an upper calcination temperature of at least 500°C.

Abstract translation: 通过制备所需元素化合物的混合物（II）的水性浆料，然后干燥并煅烧混合物以形成活性催化剂（I），制备含有氧化态的钒，锑和锡的催化剂（I）。 （II）是分散在式（CnH2n + 14NOH（1）的四烷基氢氧化铵中的SnO 2·xH 2 O（其中x> = 0）的溶液，还要求的是制备α，β-不饱和单腈，优选丙烯腈 或甲基丙烯腈在丙烷或异丁烷的气相中与氧和氨在催化剂（I）的存在下，通式为VSbmAaDdOx（2）的催化反应，石蜡与NH 3的摩尔比为2.5-16，摩尔比为 石蜡至O2为1-10，n = 1-5; A =总是存在Sn的Ti和/或Sn D = Li，Mg，Ca，Sr，Ba，Co，Fe，Cr，Ga，Ni，Zn， Ge，Nb，Zr，Mo，W，Cu，Te，Ta，Se，Bi，Ce，In，As，B，Al和/或Mn，m = 0.5-10; a = 0-10; d = 10; x由存在的阳离子的氧化态决定。

公开(公告)号：EP0023382A1

公开(公告)日：1981-02-04

申请号：EP80301602.1

申请日：1980-05-16

Applicant: THE STANDARD OIL COMPANY

Inventor： Bartek, Joseph Peter ,  Grasselli, Robert Karl ,  Cepulis, Rimvydas L.

IPC: C07D307/36 ,  B01J23/18 ,  B01J27/18

CPC classification number: B01J27/186 ,  B01J23/18 ,  B01J23/68 ,  B01J23/76 ,  B01J23/8933 ,  B01J27/0573 ,  B01J27/0576 ,  C07D307/36

Abstract: Alkenes and/or alkadienes are oxidized with molecular oxygen in the presence of an antimony catalyst to produce oxole compounds, such as furan, without substantial conversion of the oxole compounds to undesirable products. The catalyst preferably has the formula

A a D b Sbc Pd O x

wherein A is one or more of the following elements:

Fe, Co, Ni, U, Sn, Mn, La, and rare earth elements; and
D is one or more of the following elements:

Ag, Cu, Mo, V, W, Bi, Te, As, Se, Cr, Zr, Pb, Nb, Ti, Zn, Cd, alkaline earth elements and alkali metal elements; and


wherein a is 0 - 10;

bisO-10;
c is 1-10;
d is 0-20; and
x is the number of oxygens required to satisfy the valence requirements of the other elements present.

In a particular embodiment butadiene is converted to furan by contacting it with air in the presence of a catalyst comprising an oxide complex of antimony and phosphorous.

公开(公告)号：EP0000617A1

公开(公告)日：1979-02-07

申请号：EP78300066.4

申请日：1978-06-22

Applicant: THE STANDARD OIL COMPANY

Inventor： Grasselli, Robert Karl ,  Bartek, Joseph Peter

IPC: C07C13/465 ,  C07C5/48

CPC classification number: B01J27/18 ,  C07C5/48 ,  C07C13/465

Abstract: The problem exists of finding a simple, economic and straightforward process for the production of indene monomer. This problem is solved by making indene monomer and substituted indene monomers by a dehydrogenation process in which an indene precursor more saturated than indene is contacted with an oxygen donor with a phosphate catalyst An oxygen donor is O 2 . The process is carried out a temperature above 100°C.
The phosphate catalyst is represented by the formula MaPxOy in which M is one or more elements selected from Mg, Sr, Ca, Ba, La, Ce, other rare earths, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sn, Pb, Bi, Te, B, Al, Rh, Sb, As, Ge, U, Th and Ru.
In a representative Example a mixture of indane, approximately five parts of air and three parts of nitrogen for each part of indane vapour are fed to a reactor containing.a phosphate catalyst and maintained at a temperature of 550°C.