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    Upgrading low molecular weight alkanes
    4.
    发明公开
    Upgrading low molecular weight alkanes 失效
    升级低分子重量碱

    公开(公告)号：EP0177327A3

    公开(公告)日：1986-06-18

    申请号：EP85306994

    申请日：1985-10-01

    Applicant: THE STANDARD OIL COMPANY

    Inventor： Brazdil, James F. ,  Grasselli, Robert K. ,  Bartek, Joseph P.

    IPC: C07C02/84 ,  B01J23/00

    CPC classification number: C07C2/84 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/14

    Abstract: Catalysts comprising multicomponent oxide catalysts are provided that are particularly effective in an oxidative process for the upgrading of low molecular weight alkanes to higher molecular weight hydrocarbons especially for the upgrading of methane to form ethane and ethylene and their subsequent upgrading to substantially liquid hydrocarbon products. The catalysts have the formula:
    wherein
    A is Pb, Bi, Sn, Sb, Tl, In, Mn, Cd, Ge or mixtures thereof; B is Mg, Ca. Sr. Ba. Zn. La, Ce, Sc, Y, Cu, Ni. Ti, Zr, Co, V or mixtures thereof; C is Li, Na, K, Rb, Cs or mixtures thereof; and wherein a is from about 0.1 to about 100; b is from about 0.1 to about 100; c is from 0.0 to about 100; and x is the number of oxygens needed to fulfill the valence requirements of the other elements. The process disclosed may be performed in the presence or absence of gaseous oxygen at elevated temperatures in a reactor containing the catalyst. The catalyst compositions remain stable for long periods of time.

    Ammoxidation of paraffins and catalysts therefor
    6.
    发明公开
    Ammoxidation of paraffins and catalysts therefor 失效
    氨基甲酸乙酯和大豆geeigneter Katalysator。

    公开(公告)号：EP0337028A1

    公开(公告)日：1989-10-18

    申请号：EP88303390.4

    申请日：1988-04-14

    Applicant: THE STANDARD OIL COMPANY

    Inventor： Brazdil, James F. ,  Guttmann, Andrew T. ,  Grasselli, Robert K.

    IPC: C07C253/24 ,  C07C255/08 ,  B01J23/22 ,  B01J23/18 ,  B01J23/24 ,  B01J27/18

    CPC classification number: B01J23/8898 ,  B01J23/30 ,  B01J23/888 ,  B01J27/057 ,  B01J2523/00 ,  C07C253/24 ,  Y02P20/52 ,  B01J2523/41 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/69 ,  B01J2523/31 ,  B01J2523/64 ,  B01J2523/43 ,  B01J2523/842 ,  B01J2523/47 ,  B01J2523/48 ,  B01J2523/56 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/22 ,  B01J2523/15 ,  B01J2523/67 ,  B01J2523/305 ,  C07C255/08

    Abstract: Disclosed in a process for ammoxidation of paraffins containing 2-5 C atoms using a complex metal oxide catalyst having ingredients and 3-5 C atoms using a complex metal oxide catalyst which is essentially free of bismuth, and has the elements and the proportions which are represented by the following empirical formula:
    VSb m P n A a D b C c O x
    where A is one or more of W, Sn, B, Mo and As;
    D is one or more of Fe, Co, Ni, Cr, Cu, Mn, Zn, Se, Te, Pb and As;
    C is one or more of an alkali metal, Ca, Sr, Ba, Tl and where m is greater than 1 and up to 20; n is 0-10; a is 0.2-10; b is 0.5; c is 0-1; a is equal to or less than m; b is equal to or less than m; wherein x is determined by oxidation state of the other elements present, and wherein the antimony has an average valency higher than +3 and the vanadium has an average valency lower than +5, wherein A includes at least 0.2 atoms of W, crystalling Sb₂O₄ is present in said catalyst, and wherein the foregoing catalyst is on a specified inorganic oxide support material. Also disclosed is the catalyst and how to make it.

    Abstract translation: 公开了一种使用具有3-5C原子的复合金属氧化物催化剂使用基本上不含铋的复合金属氧化物催化剂对含有2-5个C原子的链烷烃进行氨氧化的方法，并且其元素和比例为 由以下经验公式表示：VSbmPnAaDbCcOx其中A是W，Sn，B，Mo和As中的一种或多种; D是Fe，Co，Ni，Cr，Cu，Mn，Zn，Se，Te，Pb和As中的一种或多种; C是碱金属，Ca，Sr，Ba，Tl中的一种或多种，​​其中m大于1且高达20; n为0-10; a是0.2-10; b为0.5; c为0-1; a等于或小于m; b等于或小于m; 其中x由存在的其他元素的氧化态决定，其中锑的平均价高于+3，钒的平均价低于+5，其中A包含至少0.2个W原子，Sb 2 O 4的结晶为 存在于所述催化剂中，并且其中上述催化剂在特定的无机氧化物载体材料上。 还披露了催化剂以及如何制备它。

    Paraffin ammoxidation using vanadium antimony oxide based catalysts with halide promoters
    9.
    发明公开
    Paraffin ammoxidation using vanadium antimony oxide based catalysts with halide promoters 失效
    氨氧化on on on ter ter ter f f f f f ren ren ren ren ren ren ren ren ren ren ren ren ren ren

    公开(公告)号：EP0747349A1

    公开(公告)日：1996-12-11

    申请号：EP96303754.4

    申请日：1996-05-24

    Applicant: THE STANDARD OIL COMPANY

    Inventor： Brazdil, James F. ,  Cavalcanti, Fernando A.P.

    IPC: C07C253/24

    CPC classification number: B01J23/18 ,  B01J23/22 ,  C07C253/24 ,  Y02P20/52 ,  C07C255/08

    Abstract: The process for the ammoxidation of a C 3 to C 5 paraffinic hydrocarbon to its corresponding α,β-unsaturated hydrocarbon comprising reacting the C 3 to C 5 paraffinic hydrocarbon with ammonia and oxygen in a fluid bed reactor at a temperature of between 250°C to 600°C in the presence of a catalyst having the empirical formula as follows:

            V v Sb m A a D d O x

    wherein

    A when present is Sn and/or Ti
    D when present is one or more of Li, Mg, Na, Ca, Sr, Ba, Co, Fe, Cr, Ga, Ni, Zn, Ge, Nb, Zr, Mo, W, Cu, Te, Ta, Se, Bi, Ce, In, As, B, Al, P and Mn; and
    wherein v is 1, m is 0.5-75, a is 0 to 25, d is 0 to 25, and x is determined by the oxidation state of the cations present,
    and a minor quantity of an halogen-containing component, preferably characterized by the following formula:

            R-X or X 2

       where R=Hydrogen, C 1 -C 20 alkyl
       and X=F, Cl, Br, I or mixtures thereof.

    Abstract translation: 包括将C3至C5链烷烃的氨氧化为其相应的α，β-不饱和烃的方法，包括在流化床反应器中在250℃至600℃的温度下使C3至C5链烷烃与氨和氧反应 在具有以下经验公式的催化剂的存在下，VvSbmAaDdOx其中存在的A是存在的Sn和/或Ti D，当存在Li，Mg，Na，Ca，Sr，Ba，Co，Fe，Cr中的一种或多种时， Ga，Ni，Zn，Ge，Nb，Zr，Mo，W，Cu，Te，Ta，Se，Bi，Ce，In，As，B，Al，P和Mn; 并且其中v为1，m为0.5-75，a为0至25，d为0至25，x由存在的阳离子的氧化态和少量含卤素组分，优选表征 通过下式：RX或X2，其中R =氢，C 1 -C 20烷基和X = F，Cl，Br，I或其混合物。

    Upgrading low molecular weight alkanes
    10.
    发明公开
    Upgrading low molecular weight alkanes 失效
    Verfahren zur Umsetzung von Alkanen mit niedrigem Molekulargewicht。

    公开(公告)号：EP0177327A2

    公开(公告)日：1986-04-09

    申请号：EP85306994.6

    申请日：1985-10-01

    Applicant: THE STANDARD OIL COMPANY

    Inventor： Brazdil, James F. ,  Grasselli, Robert K. ,  Bartek, Joseph P.

    IPC: C07C2/84 ,  B01J23/00

    CPC classification number: C07C2/84 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/14

    Abstract: Catalysts comprising multicomponent oxide catalysts are provided that are particularly effective in an oxidative process for the upgrading of low molecular weight alkanes to higher molecular weight hydrocarbons especially for the upgrading of methane to form ethane and ethylene and their subsequent upgrading to substantially liquid hydrocarbon products. The catalysts have the formula:
    wherein

    A is Pb, Bi, Sn, Sb, Tl, In, Mn, Cd, Ge or mixtures thereof;
    B is Mg, Ca. Sr. Ba. Zn. La, Ce, Sc, Y, Cu, Ni. Ti, Zr, Co, V or mixtures thereof;
    C is Li, Na, K, Rb, Cs or mixtures thereof; and wherein
    a is from about 0.1 to about 100;
    b is from about 0.1 to about 100;
    c is from 0.0 to about 100; and
    x is the number of oxygens needed to fulfill the valence requirements of the other elements.

    The process disclosed may be performed in the presence or absence of gaseous oxygen at elevated temperatures in a reactor containing the catalyst. The catalyst compositions remain stable for long periods of time.

    Abstract translation: 提供了包含多组分氧化物催化剂的催化剂，其在用于将低分子量烷烃升级为更高分子量烃的氧化方法中特别有效，特别是用于升级甲烷以形成乙烷和乙烯，并随后升级为基本上液体烃产物。 催化剂具有下式：Aa Bb Cc Ox其中A是Pb，Bi，Sn，Sb，Tl，In，Mn，Cd，Ge或其混合物; B是Mg，Ca，Sr，Ba，Zn，La，Ce，Sc，Y，Cu，Ni，Ti，Zr，Co，V或它们的混合物; C是Li，Na，K，Rb，Cs或其混合物; 并且其中a为约0.1至约100; b为约0.1至约100; c为0.0〜约100; x是满足其他元素的化合价要求所需的氧数。 所公开的方法可以在含有催化剂的反应器中在升高的温度存在或不存在气态氧的情况下进行。 催化剂组合物长时间保持稳定。

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