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1.发明授权
公开(公告)号：EP0057320B1
公开(公告)日：1985-06-05
申请号：EP81305782.5
申请日：1981-12-08
Applicant: THE STANDARD OIL COMPANY
Inventor： Pedersen, Svend Erik , Callahan, James Louis , Hardman, Harley Foch
IPC: B01J27/18 , B01J23/89 , C07C51/377
CPC classification number: B01J27/186 , B01J23/8933 , B01J27/1853 , C07C51/377 , C07C53/124
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2.发明公开A process for the oxidation of propylene to acrylic acid and of isobutylen to methacrylic acid 失效Verfahren zur氧化冯丙烯酸丙烯酸酯和异丁烯酸甲基丙烯酸酯。
公开(公告)号：EP0010206A1
公开(公告)日：1980-04-30
申请号：EP79103676.7
申请日：1979-09-28
Applicant: THE STANDARD OIL COMPANY
CPC classification number: C07C253/26 , B01J8/0453 , B01J8/048 , B01J8/34 , C07C51/252 , C07C57/04 , C07C255/08
Abstract: A combination of fixed and fluid-bed catalytic reactions is achieved by employing fixed-bed catalysts (3) on supports (4) within the fluid-bed (2). The fluid-bed catalysts (2) may move in toth directions through the fixed bed (3), thereby giving advantages of both types of beds in one reactor (1).
Abstract translation: 通过在流化床（2）内的载体（4）上使用固定床催化剂（3）来实现固定和流化床催化反应的组合。 流化床催化剂（2）可以在两个方向上移动通过固定床（3），从而在一个反应器（1）中提供两种类型的床的优点。
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3.发明公开Synthesis of molecular sieving metallosilicates using silica-transition metal oxide sols 失效使用二氧化硅转移金属氧化物溶胶分子筛金属化合物的合成
公开(公告)号：EP0183391A3
公开(公告)日：1988-06-15
申请号：EP85307762
申请日：1985-10-28
Applicant: THE STANDARD OIL COMPANY
Inventor： Pepera, Marc Anthony , Callahan, James Louis , Desmond, Michael Joseph
CPC classification number: C01B33/2884 , B01J29/04 , C01B33/2876
Abstract: A method for preparing a molecular sieving metallosilicate which comprises:
(A) providing an aqueous dispersion of colloidal particles comprising contiguous mixtures of silica and the oxide of a transition metal selected from the group consisting of Sc, Ti, V, Cr, Mn, Fe, Co. Ni, Zn, Zr, Y or a mixture of two or more of said metals; (B) mixing an effective amount of a mineralizing agent and/or synthesis directing agent with said dispersion to form a gel; and (C) maintaining said gel at a temperature of 80°C to 300°C for an effective period of time to provide said metallosilicate.-
4.发明公开Synthesis of molecular sieving metallosilicates using silica-transition metal oxide sols 失效的金属硅酸盐用硅胶Übergangsmetalloxidsolen分子筛类型合成。
公开(公告)号：EP0183391A2
公开(公告)日：1986-06-04
申请号：EP85307762.6
申请日：1985-10-28
Applicant: THE STANDARD OIL COMPANY
Inventor： Pepera, Marc Anthony , Callahan, James Louis , Desmond, Michael Joseph
CPC classification number: C01B33/2884 , B01J29/04 , C01B33/2876
Abstract: A method for preparing a molecular sieving metallosilicate which comprises:
(A) providing an aqueous dispersion of colloidal particles comprising contiguous mixtures of silica and the oxide of a transition metal selected from the group consisting of Sc, Ti, V, Cr, Mn, Fe, Co. Ni, Zn, Zr, Y or a mixture of two or more of said metals;
(B) mixing an effective amount of a mineralizing agent and/or synthesis directing agent with said dispersion to form a gel; and
(C) maintaining said gel at a temperature of 80°C to 300°C for an effective period of time to provide said metallosilicate.-
5.发明授权Preparation of composite oxidation catalyst and use thereof for the production of unsaturated aldehydes and acids from propylene and isobutylene 失效复合氧化催化剂的制备及其用于从丙烯和异丁烯生产不饱和醛和酸的用途
公开(公告)号：EP0061830B1
公开(公告)日：1984-08-29
申请号：EP82300739.8
申请日：1982-02-15
Applicant: THE STANDARD OIL COMPANY
Inventor： Callahan, James Louis , Shaw, Wilfrid Garside , Grasselli, Robert Karl
CPC classification number: B01J37/04 , B01J35/0006 , B01J37/0203 , C07C45/35 , C07C47/22
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Patent Agency Ranking6.发明公开Process for one step esterification using an intermetallic palladium based catalyst system 失效使用基于PADADIUM的基于催化剂体系的一步法的方法
公开(公告)号：EP0199530A3
公开(公告)日：1987-09-09
申请号：EP86302818
申请日：1986-04-16
Applicant: THE STANDARD OIL COMPANY
Inventor： Paparizos, Christos , Shaw, Wilfrid Garside , Callahan, James Louis
Abstract: A process for the one esterification of aldehydes and alcohols comprises the steps of combining an aldehyde with an alcohol, in the presence of oxygen and in contact with a catalyst having the general formula
PdTe.Zn d E. where E is one or more metals from the group consisting of group IA, IIA, IVA, IB, VIIB, or VIII metals, As or Sb; and a, d and e are from about 0 to 3 with the proviso that at least d or e ≠ 0.-
7.发明公开Mixed metal phosphorus oxide catalysts for the oxidative dehydrogenation of carboxylic acids utilizing them and preparation thereof 无效金属 - 磷混合物催化剂的羧酸，它们的制备和使用氧化脱氢。
公开(公告)号：EP0057320A1
公开(公告)日：1982-08-11
申请号：EP81305782.5
申请日：1981-12-08
Applicant: THE STANDARD OIL COMPANY
Inventor： Pedersen, Svend Erik , Callahan, James Louis , Hardman, Harley Foch
IPC: B01J27/18 , B01J23/89 , C07C51/377
CPC classification number: B01J27/186 , B01J23/8933 , B01J27/1853 , C07C51/377 , C07C53/124
Abstract: A catalyst composition represented by the formula
wherein A is selected Cd, Cr, Ge, Te, Th, Ti, U, V, Zr, rare earths and mixtures thereof; wherein D is selected from Ag, Cu, Mn and mixtures thereof; and wherein
a = 0-1.0
b = 0.75-1.5
c = 1.0-2.0
d = 0-2.0
a + d is greater than zero and
x is the number of oxygens needed to satisfy the valence requirements of the remaining elements.
This catalyst is particularly suitable for the oxydehydrogenation of saturated carboxylic acids, such as isobutyric acid, to form alpha, beta unsaturated carboxylic acids, such as methacrylic acid.Abstract translation: 由式AaFebPcDdOx worin甲表示的催化剂组合物被选择镉，铬，锗，碲，钍，钛，U，V，锆，稀土和它们的混合物; worin D被选自Ag，Cu，Mn和它们的混合物; 和worin A = 0-1.0 B = C = 0.75-1.5 1.0-2.0 D = 0-2.0 A + D大于零，x是满足其余元素的化合价要求所需的氧的数量。 这种催化剂特别适用于饱和羧酸氧化脱氢，求作为异丁酸，形成α，β-不饱和羧酸，：如甲基丙烯酸。
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8.发明公开Process for the production of a supported solid oxide complex catalyst and use thereof 失效Verfahren zur Herstellung eines festen Oxidkomplex-Trägerkatalysatorsund seine Verwendung。
公开(公告)号：EP0025715A1
公开(公告)日：1981-03-25
申请号：EP80303234.1
申请日：1980-09-15
Applicant: THE STANDARD OIL COMPANY
Inventor： Shaw Wilfrid Garside , Paperizos, Christos , Callahan, James Louis
Abstract: A process for preparing a supported solid oxide complex catalyst using silica as support characterised in that one adds fumed silica to a mixture containing one or more active components of the catalyst; dries said mixture to form a dried first-stage mixture; adds, in solution. silica or a silica-containing compound other than fumed silica to the dried first stage mixture optionally with further fumed silica; and dries and calcines the resulting mixture is provided.
The use of fumed silica produces a supported solid oxide complex catalyst of increased attrition resistance. Such catalyst is useful in the preparation of unsaturated aldehydes and acids from propylene or isobutylene by vapour phase oxidation. The use of inert or recycle gas increases the performance of such catalyst in this reaction.Abstract translation: 一种使用二氧化硅作为载体制备负载型固体氧化物配合物催化剂的方法，其特征在于，将一种热解法二氧化硅加入含有一种或多种催化剂活性组分的混合物中; 干燥所述混合物以形成干燥的第一阶段混合物; 在溶液中，二氧化硅或除热解法二氧化硅以外的含二氧化硅的化合物在任选地与另外的热解法二氧化硅一起加入干燥的第一阶段混合物中 并干燥并煅烧得到的混合物。 使用热解法二氧化硅产生具有增加耐磨性的负载型固体氧化物配合物催化剂。 这种催化剂可用于通过气相氧化从丙烯或异丁烯制备不饱和醛和酸。 惰性或循环气体的使用增加了该反应中这种催化剂的性能。
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9.发明授权Process for the production of a supported solid oxide complex catalyst and use thereof 失效生产支持的固体氧化物复合催化剂的方法及其用途
公开(公告)号：EP0025715B1
公开(公告)日：1983-06-29
申请号：EP80303234.1
申请日：1980-09-15
Applicant: THE STANDARD OIL COMPANY
Inventor： Shaw Wilfrid Garside , Paperizos, Christos , Callahan, James Louis
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10.发明授权A process for the oxidation of propylene to acrylic acid and of isobutylen to methacrylic acid 失效将丙烯氧化成丙烯酸和将异丁烯氧化成甲基丙烯酸的方法
公开(公告)号：EP0010206B1
公开(公告)日：1983-05-04
申请号：EP79103676.7
申请日：1979-09-28
Applicant: THE STANDARD OIL COMPANY
CPC classification number: C07C253/26 , B01J8/0453 , B01J8/048 , B01J8/34 , C07C51/252 , C07C57/04 , C07C255/08
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