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1.发明授权Electrochemical reactors and multicomponent membranes useful for oxidation reactions 失效对于氧化反应有用的电化学反应器和多组分膜
公开(公告)号：EP0438902B1
公开(公告)日：1997-05-07
申请号：EP90314083.8
申请日：1990-12-20
Applicant: THE STANDARD OIL COMPANY
Inventor： Cable, Thomas L. , Frye, John G., Jr. , Kliewer, Wayne R. , Mazanec, Terry J.
CPC classification number: H01M8/1246 , B01D53/326 , B01D67/0041 , B01D67/0044 , B01D67/0046 , B01D69/141 , B01D71/02 , B01D71/022 , B01D71/024 , B01D2323/10 , B01D2325/04 , B01D2325/26 , B01J8/009 , B01J12/007 , B01J19/2475 , B01J2208/00044 , B01J2208/00106 , B01J2208/00309 , B01J2208/00336 , B01J2208/00345 , B01J2208/00548 , B01J2208/00628 , B01J2219/00058 , B01J2219/00117 , B01J2219/00123 , B01J2219/00126 , B01J2219/00164 , B01J2219/00186 , C01B3/36 , C01B3/386 , C01B13/0255 , C01B13/0288 , C01B2203/0261 , C01B2203/1035 , C01B2203/1241 , C01B2203/1258 , C01B2210/0003 , C01B2210/0012 , C01B2210/0071 , C01B2210/0075 , C01C3/0216 , C01C3/0225 , C01C3/0233 , C01G45/006 , C01G45/1221 , C01G49/0018 , C01G49/0036 , C01G49/0063 , C01G51/006 , C01G51/40 , C01G51/68 , C01P2002/34 , C01P2002/54 , C01P2004/03 , C01P2004/84 , C01P2006/12 , C25B3/02 , C25B5/00 , H01M8/1231 , Y02E60/525 , Y02P20/52 , Y02P70/56
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2.发明公开Components for use in electrochemical cells and their use in oxygen separation 无效Sauerstofftrennung的Komponentenfürelektrochemische Zellen und ihre Verwendung
公开(公告)号：EP0766330A1
公开(公告)日：1997-04-02
申请号：EP96117077.6
申请日：1990-12-20
Applicant: THE STANDARD OIL COMPANY
Inventor： Cable, Thomas L. , Kliewer, Wayne R. , Frye, John G., Jr. , Mazanec, Terry J.
CPC classification number: H01M8/1246 , B01D53/326 , B01D67/0041 , B01D67/0044 , B01D67/0046 , B01D69/141 , B01D71/02 , B01D71/022 , B01D71/024 , B01D2323/10 , B01D2325/04 , B01D2325/26 , B01J8/009 , B01J12/007 , B01J19/2475 , B01J2208/00044 , B01J2208/00106 , B01J2208/00309 , B01J2208/00336 , B01J2208/00345 , B01J2208/00548 , B01J2208/00628 , B01J2219/00058 , B01J2219/00117 , B01J2219/00123 , B01J2219/00126 , B01J2219/00164 , B01J2219/00186 , C01B3/36 , C01B3/386 , C01B13/0255 , C01B13/0288 , C01B2203/0261 , C01B2203/1035 , C01B2203/1241 , C01B2203/1258 , C01B2210/0003 , C01B2210/0012 , C01B2210/0071 , C01B2210/0075 , C01C3/0216 , C01C3/0225 , C01C3/0233 , C01G45/006 , C01G45/1221 , C01G49/0018 , C01G49/0036 , C01G49/0063 , C01G51/006 , C01G51/40 , C01G51/68 , C01P2002/34 , C01P2002/54 , C01P2004/03 , C01P2004/84 , C01P2006/12 , C25B3/02 , C25B5/00 , H01M8/1231 , Y02E60/525 , Y02P20/52 , Y02P70/56
Abstract: An element for use in an electrochemical cell has a first zone for introducing an oxygen-containing gas and a second zone separated from first zone by the element, which has a membrane with first and second surfaces, conducts oxygen ions therebetween, and has a catalyst exposed to at least the first zone. The element may be used to separate oxygen.
Abstract translation: 用于电化学电池的元件具有用于引入含氧气体的第一区域和通过具有第一和第二表面的膜在第一区域与第一区域分离的第二区域之间，其间具有氧离子，并且具有催化剂 至少暴露于第一个区域。 该元件可用于分离氧气。
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3.发明授权Components for use in electrochemical cells and their use in oxygen separation 无效用于电化学电池的组件和它们的在氧气分离使用
公开(公告)号：EP0766330B1
公开(公告)日：2002-06-05
申请号：EP96117077.6
申请日：1990-12-20
Applicant: The Standard Oil Company
Inventor： Cable, Thomas L. , Kliewer, Wayne R. , Frye, John G., Jr. , Mazanec, Terry J.
CPC classification number: H01M8/1246 , B01D53/326 , B01D67/0041 , B01D67/0044 , B01D67/0046 , B01D69/141 , B01D71/02 , B01D71/022 , B01D71/024 , B01D2323/10 , B01D2325/04 , B01D2325/26 , B01J8/009 , B01J12/007 , B01J19/2475 , B01J2208/00044 , B01J2208/00106 , B01J2208/00309 , B01J2208/00336 , B01J2208/00345 , B01J2208/00548 , B01J2208/00628 , B01J2219/00058 , B01J2219/00117 , B01J2219/00123 , B01J2219/00126 , B01J2219/00164 , B01J2219/00186 , C01B3/36 , C01B3/386 , C01B13/0255 , C01B13/0288 , C01B2203/0261 , C01B2203/1035 , C01B2203/1241 , C01B2203/1258 , C01B2210/0003 , C01B2210/0012 , C01B2210/0071 , C01B2210/0075 , C01C3/0216 , C01C3/0225 , C01C3/0233 , C01G45/006 , C01G45/1221 , C01G49/0018 , C01G49/0036 , C01G49/0063 , C01G51/006 , C01G51/40 , C01G51/68 , C01P2002/34 , C01P2002/54 , C01P2004/03 , C01P2004/84 , C01P2006/12 , C25B3/02 , C25B5/00 , H01M8/1231 , Y02E60/525 , Y02P20/52 , Y02P70/56
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Patent Agency Ranking4.发明公开
公开(公告)号：EP0673675A2
公开(公告)日：1995-09-27
申请号：EP95201914.9
申请日：1990-05-24
Applicant: THE STANDARD OIL COMPANY
Inventor： Cable, Thomas L. , Frye, John G., Jr. , Mazanec, Terry J.
CPC classification number: B01J35/002 , B01D53/326 , B01D67/0044 , B01D71/02 , B01D71/022 , B01D71/024 , B01D2325/08 , B01D2325/26 , B01J8/009 , B01J12/007 , B01J19/2475 , B01J35/065 , B01J2208/00044 , B01J2208/00106 , B01J2208/00309 , B01J2208/00336 , B01J2208/00345 , B01J2208/00548 , B01J2208/00628 , B01J2219/00058 , B01J2219/00117 , B01J2219/00123 , B01J2219/00126 , B01J2219/00164 , B01J2219/00186 , C01B3/36 , C01B3/386 , C01B13/0255 , C01B13/0288 , C01B2203/0261 , C01B2203/1035 , C01B2203/1241 , C01B2203/1258 , C01B2210/0003 , C01B2210/0012 , C01B2210/0071 , C01B2210/0075 , C01C3/0216 , C01C3/0225 , C01C3/0233 , C01G45/1264 , C01G49/0018 , C01G51/68 , C01P2002/34 , C01P2002/52 , C01P2002/54 , C01P2004/03 , C01P2006/12 , C01P2006/40 , C25B3/02 , C25B5/00 , H01M8/12 , H01M8/1231 , H01M8/1246 , Y02E60/525 , Y02P20/52 , Y02P70/56
Abstract: Solid membranes comprising an intimate, gas-impervious, multi-phase mixture of an electronically-conductive material and an oxygen ion-conductive material and/or a mixed metal oxide of a perovskite structure are described. Electrochemical reactor cells and reactors are also described for transporting oxygen from any oxygen-containing gas to any gas that consumes oxygen. The reactor cells generally comprise first and second zones separated by the solid membrane. The reactor cell may further comprise a catalyst in the first zone. Processes described which may be conducted with the disclosed reactor cells and reactors include, for example, the partial oxidation of methane to produce unsaturated compounds or synthesis gas, the partial oxidation of ethane, extraction of oxygen from oxidized gases, ammoxidation of methane, etc. The extraction of oxygen from oxidized gases may be used for flue or exhaust gas clean-up.
Abstract translation: 描述了包含电子导电材料和氧离子传导材料和/或钙钛矿结构的混合金属氧化物的紧密，不透气，多相混合物的固体膜。 还描述了电化学反应器电池和反应器用于将氧从任何含氧气体输送到消耗氧气的任何气体。 反应器电池通常包括由固体膜隔开的第一和第二区域。 反应器电池还可以包括在第一区域中的催化剂。 可以使用所公开的反应器电池和反应器进行的方法包括例如甲烷的部分氧化以产生不饱和化合物或合成气，乙烷的部分氧化，从氧化气体中提取氧气，甲烷的氨氧化等。 从氧化气体中提取氧气可用于烟道或废气净化。
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5.发明授权Electrochemical reactors and multicomponent membranes useful for oxidation reactions 失效对于氧化反应有用的电化学反应器和多组分膜
公开(公告)号：EP0438902B2
公开(公告)日：2003-06-18
申请号：EP90314083.8
申请日：1990-12-20
Applicant: THE STANDARD OIL COMPANY
Inventor： Cable, Thomas L. , Frye, John G., Jr. , Kliewer, Wayne R. , Mazanec, Terry J.
CPC classification number: H01M8/1246 , B01D53/326 , B01D67/0041 , B01D67/0044 , B01D67/0046 , B01D69/141 , B01D71/02 , B01D71/022 , B01D71/024 , B01D2323/10 , B01D2325/04 , B01D2325/26 , B01J8/009 , B01J12/007 , B01J19/2475 , B01J2208/00044 , B01J2208/00106 , B01J2208/00309 , B01J2208/00336 , B01J2208/00345 , B01J2208/00548 , B01J2208/00628 , B01J2219/00058 , B01J2219/00117 , B01J2219/00123 , B01J2219/00126 , B01J2219/00164 , B01J2219/00186 , C01B3/36 , C01B3/386 , C01B13/0255 , C01B13/0288 , C01B2203/0261 , C01B2203/1035 , C01B2203/1241 , C01B2203/1258 , C01B2210/0003 , C01B2210/0012 , C01B2210/0071 , C01B2210/0075 , C01C3/0216 , C01C3/0225 , C01C3/0233 , C01G45/006 , C01G45/1221 , C01G49/0018 , C01G49/0036 , C01G49/0063 , C01G51/006 , C01G51/40 , C01G51/68 , C01P2002/34 , C01P2002/54 , C01P2004/03 , C01P2004/84 , C01P2006/12 , C25B3/02 , C25B5/00 , H01M8/1231 , Y02E60/525 , Y02P20/52 , Y02P70/56
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公开(公告)号：EP0673675A3
公开(公告)日：1995-12-06
申请号：EP95201914.9
申请日：1990-05-24
Applicant: THE STANDARD OIL COMPANY
Inventor： Cable, Thomas L. , Frye, John G., Jr. , Mazanec, Terry J.
CPC classification number: B01J35/002 , B01D53/326 , B01D67/0044 , B01D71/02 , B01D71/022 , B01D71/024 , B01D2325/08 , B01D2325/26 , B01J8/009 , B01J12/007 , B01J19/2475 , B01J35/065 , B01J2208/00044 , B01J2208/00106 , B01J2208/00309 , B01J2208/00336 , B01J2208/00345 , B01J2208/00548 , B01J2208/00628 , B01J2219/00058 , B01J2219/00117 , B01J2219/00123 , B01J2219/00126 , B01J2219/00164 , B01J2219/00186 , C01B3/36 , C01B3/386 , C01B13/0255 , C01B13/0288 , C01B2203/0261 , C01B2203/1035 , C01B2203/1241 , C01B2203/1258 , C01B2210/0003 , C01B2210/0012 , C01B2210/0071 , C01B2210/0075 , C01C3/0216 , C01C3/0225 , C01C3/0233 , C01G45/1264 , C01G49/0018 , C01G51/68 , C01P2002/34 , C01P2002/52 , C01P2002/54 , C01P2004/03 , C01P2006/12 , C01P2006/40 , C25B3/02 , C25B5/00 , H01M8/12 , H01M8/1231 , H01M8/1246 , Y02E60/525 , Y02P20/52 , Y02P70/56
Abstract: Solid membranes comprising an intimate, gas-impervious, multi-phase mixture of an electronically-conductive material and an oxygen ion-conductive material and/or a mixed metal oxide of a perovskite structure are described. Electrochemical reactor cells and reactors are also described for transporting oxygen from any oxygen-containing gas to any gas that consumes oxygen. The reactor cells generally comprise first and second zones separated by the solid membrane. The reactor cell may further comprise a catalyst in the first zone. Processes described which may be conducted with the disclosed reactor cells and reactors include, for example, the partial oxidation of methane to produce unsaturated compounds or synthesis gas, the partial oxidation of ethane, extraction of oxygen from oxidized gases, ammoxidation of methane, etc. The extraction of oxygen from oxidized gases may be used for flue or exhaust gas clean-up.
Abstract translation: 描述了包含电子导电材料和氧离子导电材料和/或钙钛矿结构的混合金属氧化物的紧密，不透气，多相混合物的固体膜。 还描述了电化学反应器电池和反应器用于将氧气从任何含氧气体输送到任何消耗氧气的气体。 反应器电池通常包括由固体膜分隔的第一和第二区域。 反应器电池还可以在第一区域中包含催化剂。 所描述的可以用所公开的反应器电池和反应器进行的方法包括例如甲烷的部分氧化以生产不饱和化合物或合成气，乙烷的部分氧化，氧化气体中氧的提取，甲烷的氨氧化等 从氧化气体中提取氧气可用于烟道气或废气净化。
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7.发明公开Electrochemical reactors and multicomponent membranes useful for oxidation reactions 失效用于氧化反应的电化学反应器和多组分膜
公开(公告)号：EP0438902A3
公开(公告)日：1992-03-25
申请号：EP90314083.8
申请日：1990-12-20
Applicant: THE STANDARD OIL COMPANY
Inventor： Cable, Thomas L. , Frye, John G., Jr. , Kliewer, Wayne R. , Mazanec, Terry J.
CPC classification number: H01M8/1246 , B01D53/326 , B01D67/0041 , B01D67/0044 , B01D67/0046 , B01D69/141 , B01D71/02 , B01D71/022 , B01D71/024 , B01D2323/10 , B01D2325/04 , B01D2325/26 , B01J8/009 , B01J12/007 , B01J19/2475 , B01J2208/00044 , B01J2208/00106 , B01J2208/00309 , B01J2208/00336 , B01J2208/00345 , B01J2208/00548 , B01J2208/00628 , B01J2219/00058 , B01J2219/00117 , B01J2219/00123 , B01J2219/00126 , B01J2219/00164 , B01J2219/00186 , C01B3/36 , C01B3/386 , C01B13/0255 , C01B13/0288 , C01B2203/0261 , C01B2203/1035 , C01B2203/1241 , C01B2203/1258 , C01B2210/0003 , C01B2210/0012 , C01B2210/0071 , C01B2210/0075 , C01C3/0216 , C01C3/0225 , C01C3/0233 , C01G45/006 , C01G45/1221 , C01G49/0018 , C01G49/0036 , C01G49/0063 , C01G51/006 , C01G51/40 , C01G51/68 , C01P2002/34 , C01P2002/54 , C01P2004/03 , C01P2004/84 , C01P2006/12 , C25B3/02 , C25B5/00 , H01M8/1231 , Y02E60/525 , Y02P20/52 , Y02P70/56
Abstract: A solid multi-component membrane for use in an electrochemical reactor characterized by a mixed metal oxide material having a perovskite structure comprising (1) a lanthanide, Y, or a combination of a lanthanide and Y, (2) at least one alkaline earth metal, (3) Fe, and (4) Cr, Ti or a combination of Cr and Ti. Also claimed is an element for use in an electrochemical reactor or reactor cell having a first surface capable of reducing oxygen to oxygen ions, a second surface capable of reacting oxygen ions with an oxygen-consuming gas, an electron-conductive path between the first and second surfaces and an oxygen ion-conductive path between the first and second surfaces characterized in that the element comprises (A) a mixed metal oxide material having a perovskite structure and (B) a conductive coating, a catalyst, or a conductive coating comprising a catalyst. The invention permits the carrying out of a number of electrochemical reactions.
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8.发明公开Electrochemical reactors and multicomponent membranes useful for oxidation reactions 失效FürOxydationsreaktionennützlicheelektrochemische Reaktoren und Mehrkomponenten-Membranen。
公开(公告)号：EP0438902A2
公开(公告)日：1991-07-31
申请号：EP90314083.8
申请日：1990-12-20
Applicant: THE STANDARD OIL COMPANY
Inventor： Cable, Thomas L. , Frye, John G., Jr. , Kliewer, Wayne R. , Mazanec, Terry J.
CPC classification number: H01M8/1246 , B01D53/326 , B01D67/0041 , B01D67/0044 , B01D67/0046 , B01D69/141 , B01D71/02 , B01D71/022 , B01D71/024 , B01D2323/10 , B01D2325/04 , B01D2325/26 , B01J8/009 , B01J12/007 , B01J19/2475 , B01J2208/00044 , B01J2208/00106 , B01J2208/00309 , B01J2208/00336 , B01J2208/00345 , B01J2208/00548 , B01J2208/00628 , B01J2219/00058 , B01J2219/00117 , B01J2219/00123 , B01J2219/00126 , B01J2219/00164 , B01J2219/00186 , C01B3/36 , C01B3/386 , C01B13/0255 , C01B13/0288 , C01B2203/0261 , C01B2203/1035 , C01B2203/1241 , C01B2203/1258 , C01B2210/0003 , C01B2210/0012 , C01B2210/0071 , C01B2210/0075 , C01C3/0216 , C01C3/0225 , C01C3/0233 , C01G45/006 , C01G45/1221 , C01G49/0018 , C01G49/0036 , C01G49/0063 , C01G51/006 , C01G51/40 , C01G51/68 , C01P2002/34 , C01P2002/54 , C01P2004/03 , C01P2004/84 , C01P2006/12 , C25B3/02 , C25B5/00 , H01M8/1231 , Y02E60/525 , Y02P20/52 , Y02P70/56
Abstract: A solid multi-component membrane for use in an electrochemical reactor characterized by a mixed metal oxide material having a perovskite structure comprising (1) a lanthanide, Y, or a combination of a lanthanide and Y, (2) at least one alkaline earth metal, (3) Fe, and (4) Cr, Ti or a combination of Cr and Ti. Also claimed is an element for use in an electrochemical reactor or reactor cell having a first surface capable of reducing oxygen to oxygen ions, a second surface capable of reacting oxygen ions with an oxygen-consuming gas, an electron-conductive path between the first and second surfaces and an oxygen ion-conductive path between the first and second surfaces characterized in that the element comprises (A) a mixed metal oxide material having a perovskite structure and (B) a conductive coating, a catalyst, or a conductive coating comprising a catalyst. The invention permits the carrying out of a number of electrochemical reactions.
Abstract translation: 一种用于电化学反应器的固体多组分膜，其特征在于具有钙钛矿结构的混合金属氧化物材料，其包含（1）镧系元素，Y或镧系元素与Y的组合，（2）至少一种碱土金属 ，（3）Fe和（4）Cr，Ti或Cr和Ti的组合。 还要求保护的是用于具有能够将氧还原成氧离子的第一表面的电化学反应器或反应器电池的元件，能够使氧离子与耗氧气体反应的第二表面，第一和第二表面之间的电子传导路径 第二表面和在第一和第二表面之间的氧离子传导路径，其特征在于该元件包括（A）具有钙钛矿结构的混合金属氧化物材料和（B）导电涂层，催化剂或导电涂层，其包含 催化剂。 本发明允许进行许多电化学反应。
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