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    Ionically polymer-bound transition metal complex for photochemical conversion of light energy
    1.
    发明公开
    Ionically polymer-bound transition metal complex for photochemical conversion of light energy 失效
    用于光能光转换的离子聚合物转移金属络合物

    公开(公告)号：EP0168994A3

    公开(公告)日：1987-10-21

    申请号：EP85304563

    申请日：1985-06-26

    Applicant: THE STANDARD OIL COMPANY

    Inventor： Giordano, Paul J. ,  Smierciak, Richard C.

    IPC: B01J31/06 ,  B01J19/12 ,  F24J02/00

    CPC classification number: B01J31/183 ,  B01J19/122 ,  B01J31/08 ,  B01J31/165 ,  B01J2531/0241 ,  B01J2531/845 ,  C07C5/31 ,  C07C13/39

    Abstract: Novel catalyst for the photochemical conversion and storage of radiant energy through the conversion of strained cyclic non-conjugated carbon containing compounds to their corresponding conjugated forms comprises ionically bonding a transition metal complex having a suqare planar geometry and multiple sites of coordination with an anion-exchange resin. The novel catalyst can be made by forming an acid salt derivative of the transition metal complex and mixing it together with an anion-exchange resin. Addition of the novel catalyst is added to a strained cyclic non-conjugated carbon containing compound results in the release of heat energy through the conversion of the non-conjugated carbon containing compound to its conjugated form. The non-conjugated carbon containing compound and the catalyst may be in compartments in a sealed container means which are separated until heat energy is required. The means of separation is then broken and the non-conjugated carbon containing compound is converted to the conjugated form with the release of heat energy. A process and apparatus is also provided wherein the conjugated carbon containing compound is exposed to radiant energy and is converted to the non-conjugated form and the non-conjugated form is then combined with the novel catalyst converting the non-conjugated form to the conjugated form and resulting in the release of heat energy which is collected.

    Abstract translation: 通过使应变的含环状非共轭碳的化合物转化成其相应的共轭形式的用于光化学转化和辐射能量储存的新型催化剂包括将具有正方形平面几何形状的过渡金属络合物和与阴离子交换的多个配位点离子键合 树脂。 提供了制备新型催化剂的方法，包括形成过渡金属配合物的酸盐衍生物，并将其与阴离子交换树脂混合。 一种方法，其中将新型催化剂加入到应变的含环状非共轭碳的化合物中，导致通过使非共轭碳化合物转化成其共轭形式释放热能。 一种方法和密封容器，其中所述非共轭碳化合物和所述催化剂在隔室中并且分离直到需要热能。 然后分离方法被破坏，并且非共轭碳化合物随着热能释放而转化为共轭形式。 一种其中含共轭碳化合物暴露于辐射能并转化为非共轭形式的方法和装置。 然后将非共轭形式与上述催化剂组合，将非共轭形式转化为共轭形式，并导致所收集的热能的释放。

    A process for making a polymer of acrylonitrile, methacrylonitrile and olefinically unsaturated monomers
    4.
    发明公开
    A process for making a polymer of acrylonitrile, methacrylonitrile and olefinically unsaturated monomers 失效
    一种用于制备丙烯腈，甲基丙烯腈的聚合物的方法，和烯属不饱和单体

    公开(公告)号：EP0741150A1

    公开(公告)日：1996-11-06

    申请号：EP95303103.6

    申请日：1995-05-05

    Applicant: THE STANDARD OIL COMPANY

    Inventor： Ball, Lawrence E. ,  Smierciak, Richard C. ,  Wardlow, Eddie Jr.

    IPC: C08F220/44

    CPC classification number: C08F220/44

    Abstract: A process for making a thermally stable melt processable acrylonitrile/methacrylonitrile/olefinically unsaturated multipolymer, comprising polymerizing a mixture of acrylonitrile monomer, methacrylonitrile monomer, and olefinically unsaturated monomer in which the rate of addition of the multimonomer mixture is set by the rate of polymerization so that the concentration of unreacted acrylonitrile monomer, unreacted methacrylonitrile monomer and unreacted olefinically unsaturated monomer is low and the polymerization process is in a monomer starved condition.

    Abstract translation: 一种用于制备热稳定可熔​​融加工的丙烯腈/甲基丙烯腈/烯属不饱和多聚合物，其包括丙烯腈单体的混合物聚合，过程甲基丙烯腈单体和烯属不饱和单体在其中加入的多单体混合物的添加速率是由聚合的速率，从而设置 DASS死未反应的丙烯腈单体，未反应的单体和未反应烯属甲基丙烯腈的浓度不饱和单体是低和聚合过程是在一个单体饥饿条件。

    100 Percent solids epoxy, nitrile coating compositions and method of making same
    8.
    发明公开
    100 Percent solids epoxy, nitrile coating compositions and method of making same 失效
    基于环氧化物百分之百固体涂料组合物，和腈以及它们的制备方法。

    公开(公告)号：EP0199529A2

    公开(公告)日：1986-10-29

    申请号：EP86302817.1

    申请日：1986-04-16

    Applicant: THE STANDARD OIL COMPANY

    Inventor： Giordano, Paul ,  Smierciak, Richard C.

    IPC: C08G59/14 ,  C08G59/36 ,  C08G59/40 ,  C08G65/22 ,  C09D163/00

    CPC classification number: C08F283/10 ,  C08G59/145 ,  C08G59/68

    Abstract: The invention relates to a process for producing the 100 percent solids epoxy nitrile coating compositions comprising:

    1) forming a mixture of the epoxy resins with the epoxy nitrile monomers and curing agents,
    2) applying the mixture to a substrate to form a coating, and
    3) curing the coating so that in situ copolymerization of the epoxy resin and epoxy-nitrile monomer results in a multifunctional epoxy nitrile coating system.

    Abstract translation: 本发明涉及一种用于生产100％固体的环氧腈涂料组合物，包含：...... 1）与环氧腈单体形成环氧树脂的混合物，并且固化剂，... 2）将所述混合物施加到衬底以形成 涂层，和... 3）固化该涂层在环氧树脂和环氧 - 腈单体结果的原位共聚所以没有在多官能环氧丁腈涂层系统。...

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