Abstract:
Provided is a hollow molded article that comes into contact with high-pressure hydrogen and has a bonded section at which two or more split bodies are bonded by welding, wherein the hollow molded article is characterized in that the average spherulites size in a portion extending 500 µm inward from the surface of the hollow molded article is 20 µm or less, and the tensile strength of a test piece including the bonded section of the hollow molded article is 80% or higher in relation to the tensile strength of a test piece that does not include the bonded section of the hollow molded article. The present invention provides a hollow molded article that is brought into contact with high-pressure hydrogen and that has a bonded section, in which the occurrence of cracking at the bonded section can be inhibited even when the filling of the hollow molded article with high-pressure hydrogen and the releasing of the pressure of the high-pressure hydrogen are repeated.
Abstract:
A polyamide resin composition for molded articles to be in contact with high-pressure hydrogen, the polyamide resin composition comprising a blend of a polyamide-6 resin (A) and a polyamide resin (B) which has a melting point, as determined by DSC, that is not higher than the temperature which is higher by 20ºC than the melting point of the polyamide-6 resin (A) and which has a crystallization temperature during cooling, as determined by DSC, that is higher than the crystallization temperature during cooling of the polyamide-6 resin (A), the amount of the polyamide resin (B) being 0.01-5 parts by weight per 100 parts by weight of the polyamide-6 resin (A). The polyamide resin composition can give a molded article which, even when high-pressure hydrogen charging and pressure release are repeated, is inhibited from developing flaws and which has excellent weld properties.
Abstract:
THE POLYLACTIC ACID STEREOCOMPLEX OF THE INVENTION HAS A CRYSTAL MELTING PEAK TEMPERATURE OF 215°C OR MORE, WHEREIN THE CRYSTAL MELTING PEAK IS A SINGLE PEAK AND HAS A PEAK HALF WIDTH OF 12°C OR LESS, AND CRYSTAL MELTING ENTHALPY OF 60 J/G OR MORE AS MEASURED BY DIFFERENTIAL SCANNING CALORIMETRY. THE POLYLACTIC ACID STEREOCOMPLEX OF THE INVENTION HAS A HIGH MELTING POINT, GOOD HEAT RESISTANCES, AND A HIGH LEVEL OF MECHANICAL PROPERTIES AND CHEMICAL RESISTANCE. THE METHOD OF THE INVENTION FOR PRODUCING A POLYLACTIC ACID STEREOCOMPLEX INCLUDES CHAOTIC MIXING OF 30 TO 70 PARTS BY WEIGHT OF (A) POLY-L-LACTIC ACID AND 30 TO 70 PARTS BY WEIGHT OF (B) POLY-D-LACTIC ACID BASED ON 100 PARTS BY WEIGHT OF THE TOTAL OF (A) POLY-L-LACTIC ACID AND (B) POLY-D-LACTICACID. THE POLYLACTIC ACID STEREO COMPLEX PRODUCING METHOD OF THE INVENTION CAN PRODUCE A POLYLACTIC ACID STEREOCOMPLEX HAVING, AS MEASURED BY DIFFERRENTIAL SCANNING CALORIMETRY, A CRYSTAL MELTING PEAK TEMPERATURE OF 215°C OR MORE, WHEREIN THE CRYSTAL MELTING PEAK IS A SINGLE PEAK AND HAS A PEAK HALF WIDTH OF 12°C OR LESS, AND A CRYSTAL MELTING ENTHALPY OF 60 J/G OR MORE
Abstract:
A polyamide resin composition for molded articles to be in contact with high-pressure hydrogen, the polyamide resin composition comprising a blend of a polyamide-6 resin (A) and a polyamide resin (B) which has a melting point, as determined by DSC, that is not higher than the temperature which is higher by 20ºC than the melting point of the polyamide-6 resin (A) and which has a crystallization temperature during cooling, as determined by DSC, that is higher than the crystallization temperature during cooling of the polyamide-6 resin (A), the amount of the polyamide resin (B) being 0.01-5 parts by weight per 100 parts by weight of the polyamide-6 resin (A). The polyamide resin composition can give a molded article which, even when high-pressure hydrogen charging and pressure release are repeated, is inhibited from developing flaws and which has excellent weld properties.
Abstract:
The purpose of the present invention is to provide a polyamide resin composition which has excellent extrusion moldability and retention stability, can suppress the thickness deviation of a molded product, and can be used to obtain an extrusion molded product in which the occurrence of defects is suppressed even after repeated charging and release of high-pressure hydrogen. Provided is a polyamide resin composition for extrusion molded products exposed to high-pressure hydrogen, the polyamide resin composition being obtained by combining 0.005-1 part by weight of a metal halide (C) with 100 parts by weight in total of 70-99 parts by weight of a polyamide 6 resin (A) and 1-30 parts by weight of an impact resistant material (B), wherein the polyamide resin composition has a molten tension of at least 20 mN as measured at 260°C, and a take-up speed at break of at least 30m/min as measured at 260°C.
Abstract:
The purpose of the present invention is to provide a polyamide resin composition which has excellent blow moldability and retention stability, can suppress the residual strain of a molded product from locally increasing, and can be used to obtain a blow-molded product in which the occurrence of defects is suppressed even after repeated charging and release of high-pressure hydrogen. Provided is a polyamide resin composition for blow-molded products exposed to high-pressure hydrogen, the polyamide resin composition being obtained by combining 0.005-1 part by weight of a metal halide (C) with 100 parts by weight in total of 70-99 parts by weight of a polyamide 6 resin (A) and 1-30 parts by weight of an impact resistant material (B), wherein the polyamide resin composition has a molten tension of at least 20 mN as measured at 260°C, and a take-up speed at break of at least 50 m/min as measured at 260°C.
Abstract:
THE PRESENT INVENTION IS A POLYCARBONATE RESIN COMPOSITION CONTAINING A POLYCARBONATE RESIN AND COMPRISING AT LEAST TWO RESINS CONTAINED AS COMPONENTS, WHEREIN THE INTENSITY RATIO OF THE ABSORPTION PEAK APPEARING IN A RANGE OF 2933±5 CM-1 TO THE ABSORPTION PEAK APPEARING IN A RANGE OF 2965±5 CM-1 IS 0.43 OR MORE. THE POLYMER ALLOY OF THIS INVENTION CAN BE USED TO OBTAIN A MATERIAL WITH EXCELLENT IMPACT RESISTANCE.
Abstract:
A polyamide resin composition for a molded article exposed to high-pressure hydrogen contains a polyamide 6 resin (A) and a polyamide resin (B) having a melting point, as determined by DSC, that is not higher than a melting point of the polyamide 6 resin (A) + 20°C and a cooling crystallization temperature, as determined by DSC, that is higher than a cooling crystallization temperature of the polyamide 6 resin (A), the polyamide resin (B) being in an amount of 0.01 to 5 parts by weight based on 100 parts by weight of the polyamide 6 resin (A). Provided is a polyamide resin composition that can provide a molded article having excellent weld properties and less likely to suffer failure points despite repeated charging and discharging of high-pressure hydrogen.
Abstract:
A polyamide resin composition for a molded article exposed to high-pressure hydrogen contains a polyamide resin (A) including a unit derived from hexamethylenediamine and a unit derived from an aliphatic dicarboxylic acid of 8 to 12 carbon atoms and an ethylene/±-olefin copolymer (B) modified with an unsaturated carboxylic acid and/or a derivative thereof. Provided is a polyamide resin composition that can provide a molded article having excellent flexibility and heat cycle resistance and less likely to suffer failure points despite repeated charging and discharging of high-pressure hydrogen.