Abstract:
The present invention relates to a polyester polymerization catalyst, comprising a solution containing an aluminum compound and an alkali compound, with water or an organic solvent or a mixture consisting of water and an organic solvent as the medium, a production method thereof, and a polyester production method, in which the product obtained by the esterification reaction or ester interchange reaction between an aromatic dicarboxylic acid or any of its ester forming derivative and a diol is polycondensed, to produce a polyester, comprising the use of said polymerization catalyst containing an aluminum compound. The present invention can provide a polyester excellent in processability and can overcome such problems as spinneret contamination, filtration pressure rise, filament breaking, film breaking and foreign matter production in the production process of products such as fibers, films, resins and bottles.
Abstract:
A polymerization catalyst for polyester production which is a solution of solutes comprising an aluminum compound and an alkali compound in water, an organic solvent, or a mixture of both; and a process for producing a polyester which comprises esterifying or transesterifying an aromatic dicarboxylic acid or an ester-forming derivative thereof with a diol or an ester-forming derivative thereof and condensation-polymerizing the resultant reaction product, characterized by using the polymerization catalyst containing an aluminum compound. The catalyst can yield a polyester having excellent moldability and being usable for producing moldings such as fibers, films, resins, bottles, etc., without posing problems such as nozzle fouling, filtering pressure increase, thread breakage, film breakage, and defects caused by foreign substances.
Abstract:
The present invention relates to a polyester polymerization catalyst, comprising a solution containing an aluminum compound and an alkali compound, with water or an organic solvent or a mixture consisting of water and an organic solvent as the medium, a production method thereof, and a polyester production method, in which the product obtained by the esterification reaction or ester interchange reaction between an aromatic dicarboxylic acid or any of its ester forming derivative and a diol is polycondensed, to produce a polyester, comprising the use of said polymerization catalyst containing an aluminum compound. The present invention can provide a polyester excellent in processability and can overcome such problems as spinneret contamination, filtration pressure rise, filament breaking, film breaking and foreign matter production in the production process of products such as fibers, films, resins and bottles.
Abstract:
The present invention relates to a polyester polymerization catalyst, comprising a solution containing an aluminum compound and an alkali compound, with water or an organic solvent or a mixture consisting of water and an organic solvent as the medium, a production method thereof, and a polyester production method, in which the product obtained by the esterification reaction or ester interchange reaction between an aromatic dicarboxylic acid or any of its ester forming derivative and a diol is polycondensed, to produce a polyester, comprising the use of said polymerization catalyst containing an aluminum compound. The present invention can provide a polyester excellent in processability and can overcome such problems as spinneret contamination, filtration pressure rise, filament breaking, film breaking and foreign matter production in the production process of products such as fibers, films, resins and bottles.
Abstract:
The present invention relates to a polyester polymerization catalyst, comprising a solution containing an aluminum compound and an alkali compound, with water or an organic solvent or a mixture consisting of water and an organic solvent as the medium, a production method thereof, and a polyester production method, in which the product obtained by the esterification reaction or ester interchange reaction between an aromatic dicarboxylic acid or any of its ester forming derivative and a diol is polycondensed, to produce a polyester, comprising the use of said polymerization catalyst containing an aluminum compound. The present invention can provide a polyester excellent in processability and can overcome such problems as spinneret contamination, filtration pressure rise, filament breaking, film breaking and foreign matter production in the production process of products such as fibers, films, resins and bottles.
Abstract:
PROBLEM TO BE SOLVED: To provide a method for manufacturing a polyester composition which contains inorganic porous particles at a high concentration, suppressed in the drop of a limiting viscosity and contains no large-sized particles and is excellent in the particle dispersibility. SOLUTION: The method for manufacturing the polyester composition by means of a vented kneader comprises addition and mixing of the inorganic porous particles having an average particle diameter of 0.01-10 μm and a water content of less than 10 wt.%, to the polyester in the state of substantial powder and of a limiting viscosity of 0.5 or more. COPYRIGHT: (C)2003,JPO
Abstract:
PROBLEM TO BE SOLVED: To provide a moisture-absorbing or releasing fiber which has an excellent moisture-absorbing or releasing property and is therefore especially suitable as a synthetic fiber having good wearing comfortableness. SOLUTION: This fiber comprises a moisture-absorbing or releasing polyester composition containing 1 to 20 wt.% of moisture-absorbing or releasing silica- based inorganic particles having an average particle diameter, a specific surface, a pore volume, and a moisture-absorbing parameter (ΔMR) in specific ranges.
Abstract:
PROBLEM TO BE SOLVED: To obtain polyester fibers containing each a specific aluminum compound and antimony compound, having a dimensional stability parameter below a specified value, with high dimensional stability and in-rubber heat resistance, and alternative to rayon fibers. SOLUTION: The polyester fibers for rubber reinforcement are such fibers as to consist of a polyester containing 2-120 ppm, calculated as aluminum atom, of aluminum compound(s) (pref. at least one selected from aluminum hydroxide, chloride, hydroxychloride, and acetate) and 150-400 ppm, calculated as antimony atom, of an antimony compound (pref. antimony trioxide) and have a dimensional stability parameter (intermediate elongation + dry heat shrinkage) of
Abstract:
PROBLEM TO BE SOLVED: To obtain high-strength polyester fibers containing each a specific aluminum compound and antimony compound, having a dimensional stability parameter within a specified range, with high dimensional stability and durability, therefore suitable for rubber reinforcing use. SOLUTION: The polyester fibers for rubber reinforcement are such fibers as to consist of a polyester containing 2-120 ppm, calculated as aluminum atom, off an aluminum compound and 15-400 ppm, calculated as antimony atom, of an antimony compound and have a dimensional stability parameter (intermediate elongation + dry heat shrinkage) of 8-12%, intrinsic viscosity of pref. >=0.85, terminal carboxyl group level of =30.
Abstract:
PROBLEM TO BE SOLVED: To provide a polyester excellent in moldability and solving problems such as the staining of spinnerets, the rise of filtration pressures and the breakage of fibers on the production of molded products such as fibers, films and bottles, and to provide a method for producing the same. SOLUTION: This polyester contains an organic aluminum compound of the formula: Al[OR1 ]l [OR2 ]m [OR3 ]n [R4 ]o [R1 , R2 , R3 are each an alkyl, an aryl, an acyl; R4 is an alkylacetoacetate ion, acetylacetone ion; wherein R1 , R2 , R3 are each simultaneously not H or acetyl; (l), (m), (n) and (o) are each 0 or a positive number wherein (l)+(m)+(n)+(o)=3] in an amount of 5-500 ppm (converted into aluminum atom) based on the polymer, and a cobalt compound in an aluminum atom/cobalt atom (Al/Co) molar ratio of 0.5-20.