公开(公告)号：US20210332231A1

公开(公告)日：2021-10-28

申请号：US17267991

申请日：2019-09-13

Applicant: TORAY Industries, Inc.

Inventor： Kohei MIYAMOTO ,  Yusuke TOJO ,  Makito YOKOE ,  Kosuke SHIROTANI ,  Yasuo MAEDA

IPC: C08L67/02 ,  B32B15/09 ,  B32B27/36 ,  B32B27/20

Abstract: Provided is a thermoplastic polyester resin composition comprising 100 parts by weight of (A) a non-liquid crystal thermoplastic polyester resin, 45 to 150 parts by weight of (B) a thermoplastic resin that is different from the non-liquid crystal thermoplastic polyester resin and has a dielectric loss tangent of not more than 0.005 when measured at a frequency of 5.8 GHz by the cavity resonance perturbation method, 2 to 20 parts by weight of (C) a compatibilizer having at least one reactive functional group selected from epoxy, acid anhydride, oxazoline, isocyanate, and carbodiimide groups, and 0.2 to 5 parts by weight of (D) at least one compound selected from tertiary amines, amidine compounds, organic phosphines and salts thereof, imidazoles, and boron compounds, wherein the ratio of the sum of the thermoplastic resin (B) and the compatibilizer (C) is in the range of 50 to 150 parts by weight and the weight ratio (B)/(C) of the thermoplastic resin (B) to the compatibilizer (C) is in the range of 8 to 50. The thermoplastic polyester resin composition can be molded into an article with low dielectric properties, excellent mechanical properties, and high bondability to metals.

公开(公告)号：US20160333178A1

公开(公告)日：2016-11-17

申请号：US15108700

申请日：2015-01-29

Applicant: TORAY INDUSTRIES, INC.

Inventor： Taku SHIMOZAWA ,  Masafumi KOYAMA ,  Kosuke SHIROTANI

IPC: C08L51/04 ,  C08J5/00 ,  C08L33/26

CPC classification number: C08L51/04 ,  C08F220/18 ,  C08F265/04 ,  C08F265/06 ,  C08J5/00 ,  C08J2333/26 ,  C08J2351/04 ,  C08J2433/26 ,  C08J2451/04 ,  C08L25/12 ,  C08L33/26 ,  C08L2201/02 ,  C08L2201/08 ,  C08L2203/20 ,  C08L2205/03 ,  C08L2207/04 ,  C08F212/08 ,  C08F220/44 ,  C08F2220/1825 ,  C08F220/40 ,  C08F2222/1013

Abstract: A thermoplastic resin composition comprising a graft copolymer (I) which is produced by carrying out the graft polymerization of a monomer mixture (B) comprising an aromatic vinyl monomer and a vinyl cyanide monomer in the presence of an acrylic rubbery polymer (A) and a vinyl copolymer (II) which is produced by carrying out the copolymerization of an aromatic vinyl monomer with a vinyl cyanide monomer, wherein the ratio of the content of the former copolymer to that of the latter copolymer is (30 to 70 parts by weight):(70 to 30 parts by weight), the graft copolymer (I) has such a property that the ratio (i.e., (α)/(β)) of the gel swelling degree (α) of the acrylic rubbery polymer (A) in toluene to the grafting ratio (β) of the graft copolymer (I) is 0.4 to 2.0, and the thermoplastic resin composition has such a structure that particles of the graft copolymer (I) are aggregated in the thermoplastic resin composition. From the thermoplastic resin composition, a molded article having excellent fluidability, weather resistance and impact resistance can be produced.

Abstract translation: 一种热塑性树脂组合物，其包含通过在丙烯酸橡胶状聚合物（A）和丙烯酸类橡胶状聚合物（A）的存在下进行包含芳香族乙烯基单体和乙烯基氰单体的单体混合物（B）的接枝聚合而制备的接枝共聚物（I） 乙烯基共聚物（II），其通过使芳族乙烯基单体与乙烯基氰单体进行共聚而制备，其中前者共聚物与后一共聚物的含量之比为（30〜70重量份）： （70〜30重量份），接枝共聚物（I）具有丙烯酸类橡胶状聚合物（A）的凝胶溶胀度（α）的比例（即，（α）/（β）） 甲苯与接枝共聚物（I）的接枝率（β）为0.4〜2.0，热塑性树脂组合物具有使热塑性树脂组合物中的接枝共聚物（I）的粒子聚集的结构。 从热塑性树脂组合物可以制造出具有优异的流动性，耐候性和抗冲击性的成型品。