公开(公告)号：JP2002117895A

公开(公告)日：2002-04-19

申请号：JP2000311626

申请日：2000-10-12

Applicant: MATSUSHITA ELECTRIC IND CO LTD ,  UBE INDUSTRIES

Inventor： WATANABE SHOICHIRO ,  GOTO SHUSAKU ,  ISHIDA SUMUTO ,  TAKAGI MASARU ,  HAMAMOTO SHUNICHI ,  UEKI AKIRA ,  ABE KOJI

IPC: H01M6/16 ,  H01M10/05 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/42 ,  H01M10/40

Abstract: PROBLEM TO BE SOLVED: To provide a battery excellent in safety and preservation characteristic. SOLUTION: In the non-aqueous electrolysis liquid secondary battery, which uses a re-chargeable positive pole, negative pole, and the non-aqueous electrolysis liquid, an electrolysis liquid additive agent consists of two or more sorts combined complexly of o-terphenyl, triphenylene, cyclohexylbenzene, and biphenyl preferably.

公开(公告)号：JP2002100399A

公开(公告)日：2002-04-05

申请号：JP2000284790

申请日：2000-09-20

Applicant: UBE INDUSTRIES

Inventor： HAMAMOTO SHUNICHI ,  ABE KOJI ,  USHIGOE YOSHIHIRO ,  HATTORI TAKAYUKI ,  MATSUMORI YASUO

IPC: H01M10/05 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/40

Abstract: PROBLEM TO BE SOLVED: To provide a lithium secondary cell with excellent cell characters such as cycle ability in a wide temperature range, an electric capacity and a storage property. SOLUTION: An electrolyte solution of electrolytes dissolved in a nonaqueous solvent comprises at least one of alkyne derivatives represented by the equation (I). R1 is either alkyl with a C number of 1 to 12, cycloalkyl with a C number of 3 to 6, aryl or hydrogen. R2 and R3 is independently either alkyl with C number of 1 to 12, cycloalkyl with C number of 3 to 6 or aryl. R2 and R3 may combine each other to form cycloalkyl with C number of 3 to 6. Y1 is either -COOR18, -COR18 or -SO2R18. The above R18 is independently either alkyl with C number of 1 to 12, cycloalkyl with C number of 3 to 6 or aryl. However, n is an integer of 1 or 2.

公开(公告)号：JP2001313072A

公开(公告)日：2001-11-09

申请号：JP2000129073

申请日：2000-04-28

Applicant: UBE INDUSTRIES

Inventor： HAMAMOTO SHUNICHI ,  ABE KOJI ,  ITO AKIKAZU ,  MATSUMORI YASUO

IPC: H01M10/05 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/40

Abstract: PROBLEM TO BE SOLVED: To provide a lithium secondary cell having excellent cell characteristics such as cycle characteristics of the cell in a large temperature range, electric capacity, and a preservation characteristics. SOLUTION: In a non-aqueous electrolyte in which the electrolyte is dissolved in a non-aqueous solvent, the non-aqueous electrolyte contains at least one kind of alkyne carbonate derivative expressed with formula (1), and the lithium secondary cell uses the non-aqueous electrolyte. In the formula, R1, R2, R3, and R4 shows 1-12C alkyl group, 3-6C cyclo-alkyl group, allyl group, or hydrogen atom. Whereas, n shows the integer of 1 or 2.

公开(公告)号：JP2001307766A

公开(公告)日：2001-11-02

申请号：JP2000115109

申请日：2000-04-17

Applicant: UBE INDUSTRIES

Inventor： HAMAMOTO SHUNICHI ,  ABE KOJI ,  TAKAI TSUTOMU ,  MATSUMORI YASUO

IPC: H01M10/05 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/40

Abstract: PROBLEM TO BE SOLVED: To provide a lithium secondary battery having improved battery characteristics including cycle characteristics, electric capacity and storage characteristics. SOLUTION: This nonaqueous electrolyte formed by dissolving an electrolyte in a nonaqueous solvent contains a disulfide derivative represented by Formula (I), R1-S-S-R2, where R1, R2 are independently phenyl, benzyl, tolyl, pyridyl, pyrimidy group, an alkyl group having the number of carbon atoms being 1 to 12 or a cycloalkyl group having the number of carbon atoms being 3 to 6. The content x of the derivative (% by weight) is 0.01

公开(公告)号：JP2001167791A

公开(公告)日：2001-06-22

申请号：JP2000170565

申请日：2000-06-07

Applicant: UBE INDUSTRIES

Inventor： HAMAMOTO SHUNICHI ,  ABE KOJI ,  MATSUMORI YASUO

IPC: H01M10/05 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/40

Abstract: PROBLEM TO BE SOLVED: To provide a lithium secondary battery excellent in cycling property capacity and charge holing amount. SOLUTION: In the nonaqueous electrolyte in which electrolyte is dissolved in nonaqueous solvent, the nonaqueous electrolyte contains tort-butye benzene derivative expressed at the following formula (I): wherein, R1, R2, R3, R4 and R5 indicate hydrogen atom or hydrocarbon of 1-12 in carbon number, respectively. And the lithium secondary cell uses the nonaqueous electrolyte.

公开(公告)号：JP2001015155A

公开(公告)日：2001-01-19

申请号：JP18555499

申请日：1999-06-30

Applicant: SANYO ELECTRIC CO ,  UBE INDUSTRIES

Inventor： TAKAHASHI MASATOSHI ,  YASUTAKE ZENSAKU ,  ABE KOJI ,  UEKI AKIRA ,  HAMAMOTO SHUNICHI

IPC: H01M2/34 ,  H01M6/10 ,  H01M6/50 ,  H01M10/05 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/058 ,  H01M10/0585 ,  H01M10/42 ,  H01M10/40

Abstract: PROBLEM TO BE SOLVED: To secure the safety of a battery by using an additive agent that, when added to an electrolytic solution, effectively acts on an overcharge without adversely affecting battery characteristics such as low-temperature characteristics and preservation characteristics. SOLUTION: This electrolytic solution has an organic solvent containing an alkylbenzene derivative or a cycloalkylbenzene derivative having tertiary carbon adjoining a phenyl group. The alkylbenzene derivative is selected from cumene, 1,3-diisopropylbenzene, 1,4-diisopropylbenzene, 1-methylpropylbenzene, 1,3-bis(1-methylpropyl)benzene, and 1,4-bis(1-methylpropyl)benzene, and the cycloalkylbenzene derivative is selected from cyclohexylbenzene and cyclopentylbenzene.

公开(公告)号：JP2000215910A

公开(公告)日：2000-08-04

申请号：JP1757699

申请日：1999-01-26

Applicant: UBE INDUSTRIES

Inventor： HAMAMOTO SHUNICHI ,  MIYOSHI KAZUHIRO ,  ABE KOJI ,  UEKI AKIRA

IPC: H01M10/05 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/40

Abstract: PROBLEM TO BE SOLVED: To provide a lithium secondary battery having excellent battery characteristics such as a batter cycle characteristic, electric capacity and a storage characteristic. SOLUTION: In relation to an electrolytic solution wherein an electrolyte is dissolved in a nonaqueous solution, this electrolytic solution for a lithium secondary battery is characterized by including at least one kind of thiol salts expressed by the following general formula (I) in the electrolytic solution: R-S-M (I) (in the formula, R is a 1-15C alkyl group or 3-12C cycloalkyl group which may be substituted with one or more 1-4C alkyls, a 7-15C benzyl group which may be substituted with one or more 1-4C alkyls, or a 6-15C aryl group, and M is an alkaline metal. R may be substituted with one or more halogen atoms). This lithium secondary battery uses the electrolytic solution.

公开(公告)号：JP2000128867A

公开(公告)日：2000-05-09

申请号：JP30352298

申请日：1998-10-26

Applicant: UBE INDUSTRIES

Inventor： HAMAMOTO SHUNICHI ,  UEKI AKIRA ,  ABE KOJI ,  TAKAI TSUTOMU

IPC: C07D231/12

Abstract: PROBLEM TO BE SOLVED: To obtain a new compound useful as an additive for electrolytic solutions, in which electrolytes are dissolved in nonaqueous solvents, used for enhancing cycle characteristics of battery and battery characteristics such as electric capacity or electric storage characteristic. SOLUTION: This compound is represented by formula I (R is methyl, ethyl, n-propyl, isopropyl, n-butyl or benzyl), e.g. 1-(1-propanesulfonyl)pyrazole. The compound of the formula is obtained by reacting, e.g. (A) pyrazole with (B) the corresponding sulfonic acid chloride derivative in an amount of 1.0-1.5 mol based on 1 mol of the component A in the presence of (C) a base (e.g. triethylamine) in an amount of 1.0-2.0 mol based on 1 mol of the component A in an organic solvent (e.g. dichloromethane) at a ratio of 10-60 pts.wt. to 1 pt. component A at -30 deg.C to 30 deg.C. The component B includes methanesulfonyl chlorxde, ethanesulfonyl chlorxde, 2propanesulfonyl chloride, etc.

公开(公告)号：JPH11329494A

公开(公告)日：1999-11-30

申请号：JP13282998

申请日：1998-05-15

Applicant: UBE INDUSTRIES

Inventor： HAMAMOTO SHUNICHI ,  ABE KOJI ,  TAKAI TSUTOMU

IPC: C07C317/08 ,  C07C317/12 ,  H01M10/05 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/40

Abstract: PROBLEM TO BE SOLVED: To provide a lithium secondary battery excellent in battery characteristics such as cycle characteristics, electrical capacity, and preservation characteristics of the battery. SOLUTION: As this electrolytic solution for a lithium secondary battery, an eletrolytic solution having an electrolyte dissolved in a nonaqueous solvent is provided that contains a vinyl sulfone derivative expressed by the following general formula, (where, R is an alkyl group having the number of carbon atoms of 1 to 12, an alkenyl group having the number of carbon atoms of 1 to 12, or a cycloalkyl group having the number of carbon atoms of 3 to 6.), and a lithium secondary battery using this is also provided.

公开(公告)号：JPH11329490A

公开(公告)日：1999-11-30

申请号：JP13529498

申请日：1998-05-18

Applicant: UBE INDUSTRIES

Inventor： HAMAMOTO SHUNICHI ,  ABE KOJI ,  TAKAI TSUTOMU

IPC: H01M10/05 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M10/40

Abstract: PROBLEM TO BE SOLVED: To provide a lithium secondary battery excellent in battery characteristics such as cycle characteristics, electrical capacity, and preservation characteristics of the battery. SOLUTION: As this electrolytic solution for a lithium secondary battery, an eletrolytic solution having an electrolyte dissolved in a nonaqueous solvent is provided that contains penta-fluoro-benzene derivatives containing electron- attractive substitution groups expressed by a general formula (where, Y stands for an ester group containing an alkyl group or aryl group having the number of carbon atoms of 1 to 12, an acyl group containing an alkyl group or aryl group having the number of carbon atoms of 1 to 12, or a tri-fluoromethyl group. A halogen atom may be substituted for at least one of hydrogen atoms of the alkyl group or aryl group.), and a lithium secondary battery using this is also provided.