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    (substituted thio)dibenzoquinone compound and (substituted thio)biaryl compound which is intermediate of the same, and method for producing them
    5.
    发明专利
    (substituted thio)dibenzoquinone compound and (substituted thio)biaryl compound which is intermediate of the same, and method for producing them 审中-公开
    （取代的噻吩）二苯并醌化合物和（取代的噻二唑）二异氰酸酯化合物及其制备方法

    公开(公告)号：JP2011116749A

    公开(公告)日：2011-06-16

    申请号：JP2010240148

    申请日：2010-10-26

    Applicant: Ube Industries Ltd ,  Yamaguchi Univ ,  国立大学法人山口大学 ,  宇部興産株式会社

    Inventor： KAMIMURA AKIO ,  SHIRAI MASASHI

    IPC: C07C319/20 ,  C07B61/00 ,  C07C323/20 ,  C07C323/22

    Abstract: PROBLEM TO BE SOLVED: To provide a method etc., capable of producing a new (substituted thio)dibenzoquinone compound in a high yield and a high regioselectivity by an even industrially simple and suitable method utilizing an aryl-aryl coupling reaction. SOLUTION: This method for producing the (substituted thio)dibenzoquinone compound is characterized by comprising a first process of reacting a (substituted thio)dioxybenzene compound with the (substituted thio)dioxybenzene compound in the presence of a coupling agent to obtain a (substituted thio)tetraoxybiaryl compound, a second process of reacting the (substituted thio)tetraoxybiaryl compound with a hydroxylation agent to obtain a (substituted thio)tetrahydroxybiaryl compound, and a third process of reacting the (substituted thio)tetrahydroxybiaryl compound with an oxidizing agent to obtain the (substituted thio)dibenzoquinone compound. COPYRIGHT: (C)2011,JPO&INPIT

    Abstract translation: 待解决的问题：提供能够通过使用芳基 - 芳基偶联反应的均匀工业上简单且合适的方法以高产率和高选择性产生新的（取代的硫代）二苯并醌化合物的方法等。 解决方案：这种制备（取代的硫代）二苯并醌化合物的方法的特征在于包括在偶联剂存在下使（取代的硫代）二氧基苯化合物与（取代的硫代）二氧基苯化合物反应的第一种方法，以获得 （取代的硫代）四氧基联芳基化合物，使（取代的硫代）四氧基联芳基化合物与羟基化试剂反应得到（取代的硫代）四羟基联芳基化合物的第二种方法和使（取代的硫代）四羟基联芳基化合物与氧化剂 得到（取代的硫代）二苯并醌化合物。 版权所有（C）2011，JPO＆INPIT

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