NONAQUEOUS ELECTROLYTE SOLUTION AND LITHIUM SECONDARY BATTERY USING SAME

    公开(公告)号:CA2568335A1

    公开(公告)日:2005-12-22

    申请号:CA2568335

    申请日:2005-05-18

    Applicant: UBE INDUSTRIES

    Abstract: Disclosed is a lithium secondary battery which is excellent in battery characteristics such as long-term cycle characteristics, capacity and shelf life characteristics. Also disclosed is a nonaqueous electrolyte solution which can be used for such a lithium secondary battery. Specifically disclosed is a nonqueous electrolyte solution for lithium secondary batteries obtained by dissolving an electrolyte salt in a nonaqueous solvent which is characterized by containing 0.01 - 10 % by weight of a carboxylate compound represented by the general formula (1) below and 0.01 - 10 % by weight or 0.01 - 10 % by volume of a vinylene carbonate and/or 1,3-propane sultone. Also disclosed is a lithium secondary battery using such a nonaqueous electrolyte solution. In the formula, R 2 represents a hydrogen atom or COOR 3 group, R 1 and R 3 respectively represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkykynyl goups or a phenyl group, and X represents an alkynylene group or an alkenylene group.

    6.
    发明专利
    未知

    公开(公告)号:DE602005015321D1

    公开(公告)日:2009-08-20

    申请号:DE602005015321

    申请日:2005-05-18

    Applicant: UBE INDUSTRIES

    Abstract: Disclosed is a lithium secondary battery which is excellent in battery characteristics such as long-term cycle characteristics, capacity and shelf life characteristics. Also disclosed is a nonaqueous electrolyte solution which can be used for such a lithium secondary battery. Specifically disclosed is a nonqueous electrolyte solution for lithium secondary batteries obtained by dissolving an electrolyte salt in a nonaqueous solvent which is characterized by containing 0.01 - 10 % by weight of a carboxylate compound represented by the general formula (1) below and 0.01 - 10 % by weight or 0.01 - 10 % by volume of a vinylene carbonate and/or 1,3-propane sultone. Also disclosed is a lithium secondary battery using such a nonaqueous electrolyte solution. In the formula, R 2 represents a hydrogen atom or COOR 3 group, R 1 and R 3 respectively represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkykynyl goups or a phenyl group, and X represents an alkynylene group or an alkenylene group.

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