公开(公告)号：EP0355837A2

公开(公告)日：1990-02-28

申请号：EP89115647.3

申请日：1989-08-24

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： Abatjoglou, Anthony George ,  Bryant, David Robert

IPC: C22B3/00 ,  C01G55/00 ,  B01J39/12 ,  B01J31/40

CPC classification number: B01J31/24 ,  B01J31/185 ,  B01J31/20 ,  B01J31/2234 ,  B01J31/2404 ,  B01J31/2409 ,  B01J31/4023 ,  B01J31/4046 ,  B01J31/4053 ,  B01J39/12 ,  B01J2231/321 ,  B01J2531/02 ,  B01J2531/0211 ,  B01J2531/80 ,  B01J2531/822 ,  B01J2531/985 ,  B01J2540/12 ,  B01J2540/32 ,  B01J2540/42 ,  B01J2540/525 ,  B01J2540/68 ,  C01G55/001 ,  C07C45/50 ,  C07C45/79 ,  C22B3/42 ,  Y02P10/234 ,  Y02P20/584 ,  C07C47/02

Abstract: A method for recovering a transition metal such as rhodium from a polar or non-polar liquid by contacting said transition metal-­containing liquid with an ion-exchange resin having bonded ionically thereto an organophosphorus ligand; the transition metal can be eluted from the bed using a liquid containing a sufficient concentra­tion of organophosphorus ligand.

Abstract translation: 通过使所述含过渡金属的液体与离子交换树脂离子交联的有机磷配体接触从极性或非极性液体中回收诸如铑的过渡金属的方法; 可以使用含有足够浓度的有机磷配体的液体从床上洗脱过渡金属。

公开(公告)号：EP0357997B1

公开(公告)日：1992-11-25

申请号：EP89114934.6

申请日：1989-08-11

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： Miller, David James ,  Bryant, David Robert ,  Billig, Ernst (NMN) ,  Shaw, Bernard Leslie, Prof.

IPC: B01J31/40 ,  C07C45/50

CPC classification number: B01J31/4046 ,  B01J31/0201 ,  B01J31/0215 ,  B01J31/0231 ,  B01J31/0255 ,  B01J31/04 ,  B01J31/24 ,  B01J31/2404 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/50 ,  Y02P20/582 ,  Y02P20/584 ,  C07C47/02

公开(公告)号：EP0434061A1

公开(公告)日：1991-06-26

申请号：EP90124963.1

申请日：1990-12-20

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Wegman, Richard William ,  Bryant, David Robert

IPC: C07C29/149 ,  B01J23/72

CPC classification number: C07C29/149 ,  B01J23/72 ,  C07C31/08 ,  C07C31/12 ,  C07C31/207

Abstract: A process for hydrogenating bound oxygen-containing organic feeds into their corresponding alcohols by contact with a coprecipitated copper-aluminum catalyst that has been activated by contact with reducing gas at a temperature that gradually increases.

Abstract translation: 通过与在逐渐增加的温度下与还原气体接触而被活化的共沉淀的铜 - 铝催化剂接触，将结合的含氧有机原料氢化为相应的醇。

公开(公告)号：EP0355837A3

公开(公告)日：1990-05-16

申请号：EP89115647.3

申请日：1989-08-24

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： Abatjoglou, Anthony George ,  Bryant, David Robert

IPC: C22B3/00 ,  C01G55/00 ,  B01J39/12 ,  B01J31/40

CPC classification number: B01J31/24 ,  B01J31/185 ,  B01J31/20 ,  B01J31/2234 ,  B01J31/2404 ,  B01J31/2409 ,  B01J31/4023 ,  B01J31/4046 ,  B01J31/4053 ,  B01J39/12 ,  B01J2231/321 ,  B01J2531/02 ,  B01J2531/0211 ,  B01J2531/80 ,  B01J2531/822 ,  B01J2531/985 ,  B01J2540/12 ,  B01J2540/32 ,  B01J2540/42 ,  B01J2540/525 ,  B01J2540/68 ,  C01G55/001 ,  C07C45/50 ,  C07C45/79 ,  C22B3/42 ,  Y02P10/234 ,  Y02P20/584 ,  C07C47/02

Abstract: A method for recovering a transition metal such as rhodium from a polar or non-polar liquid by contacting said transition metal-­containing liquid with an ion-exchange resin having bonded ionically thereto an organophosphorus ligand; the transition metal can be eluted from the bed using a liquid containing a sufficient concentra­tion of organophosphorus ligand.

公开(公告)号：EP0353770A3

公开(公告)日：1990-05-16

申请号：EP89114453.7

申请日：1989-08-04

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： Abatjoglou, Anthony George ,  Bryant, David Robert

IPC: C07F9/6574 ,  C07C45/50 ,  B01J31/28

CPC classification number: C07F9/65746 ,  B01J31/185 ,  B01J2231/321 ,  B01J2531/0266 ,  B01J2531/80 ,  B01J2531/822 ,  C07C45/50 ,  C07F9/65744 ,  Y02P20/582 ,  C07C47/02

Abstract: This invention relates to novel ionic phosphites and the use thereof as ligands in homogenous transition metal catalyzed pro­cesses, especially hydroformylation.

公开(公告)号：EP0353770A2

公开(公告)日：1990-02-07

申请号：EP89114453.7

申请日：1989-08-04

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： Abatjoglou, Anthony George ,  Bryant, David Robert

IPC: C07F9/6574 ,  C07C45/50 ,  B01J31/28

CPC classification number: C07F9/65746 ,  B01J31/185 ,  B01J2231/321 ,  B01J2531/0266 ,  B01J2531/80 ,  B01J2531/822 ,  C07C45/50 ,  C07F9/65744 ,  Y02P20/582 ,  C07C47/02

Abstract: This invention relates to novel ionic phosphites and the use thereof as ligands in homogenous transition metal catalyzed pro­cesses, especially hydroformylation.

Abstract translation: 本发明涉及新型离子亚磷酸酯及其在均相过渡金属催化方法中尤其是加氢甲酰化作用的配体。

公开(公告)号：EP0350922A2

公开(公告)日：1990-01-17

申请号：EP89112857.1

申请日：1989-07-13

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： Abatjoglou, Anthony George ,  Bryant, David Robert ,  Peterson, Ronald Robert

IPC: C07C45/50 ,  C07C45/80 ,  C07C47/02

CPC classification number: C07C45/80 ,  C07C45/50 ,  C07C47/02

Abstract: Process for the separation and recovery of aldehyde product from a non-aqueous hydroformylation reaction product composition comprising the aldehyde product, a rhodium-ionically charged phosphorus ligand complex, a free ionically charged phosphorus ligand and an organic solubilizing agent for said complex and said free ligand via phase separation using added water or both added water and an added non-polar hydrocarbon compound.

Abstract translation: 用于从包含醛产物，铑离子电荷的磷配体络合物，游离离子电荷的磷配体和用于所述络合物和所述游离配体的有机增溶剂的非水羰基化反应产物组合物分离和回收醛产物的方法 通过使用加入的水或加入的水和加入的非极性烃化合物进行相分离。

公开(公告)号：EP0500150A1

公开(公告)日：1992-08-26

申请号：EP92107803.6

申请日：1989-08-11

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： Miller, David James ,  Bryant, David Robert

IPC: B01J31/40 ,  C07C45/50

CPC classification number: B01J31/24 ,  B01J31/0201 ,  B01J31/2404 ,  B01J31/2409 ,  B01J31/2414 ,  B01J31/4046 ,  B01J2231/321 ,  B01J2531/80 ,  B01J2531/822 ,  B01J2531/96 ,  C07C45/50 ,  Y02P20/584 ,  C07C47/02

Abstract: A method for recovering a transition metal, e.g., rhodium, from a polar solution containing a polar solvent-soluble coordination complex of a transition metal and a polar solvent-soluble ionic organophosphine ligand comprising:

(i) treating the polar solution with a conditioning reagent to reduce the amount of said polar solvent-soluble ionic organophosophine ligand capable of forming a coordination complex with the transition metal in the polar solution; and
(ii) contacting the polar solution produced in accordance with step (i) with a non-polar organic solvent containing non-polar organic solvent-soluble and polar solvent-insoluble organophosphorus ligand capable of forming a coordination complex with the transition metal to transfer said transition metal from said polar solution into said non-polar organic solvent.

公开(公告)号：EP0434062A1

公开(公告)日：1991-06-26

申请号：EP90124964.9

申请日：1990-12-20

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Wegman, Richard William ,  Bryant, David Robert

IPC: C07C29/149 ,  B01J23/76

CPC classification number: B01J23/835 ,  B01J23/72 ,  B01J23/74 ,  B01J23/80 ,  B01J37/18

Abstract: A process for hydrogenating feeds into their corresponding alcohols by contact with a coprecipitated catalyst comprising copper, aluminum, and a metal (X) selected from the group consisting of magnesium, zinc, titanium, zirconium, tin, nickel, cobalt and mixtures thereof; that has been reduced with an increasing temperature during the reduction.

Abstract translation: 通过与包含铜，铝和选自镁，锌，钛，锆，锡，镍，钴及其混合物的金属（X）的共沉淀催化剂接触来将进料氢化为相应的醇的方法; 这在还原期间随着温度升高而降低。

公开(公告)号：EP0357997A1

公开(公告)日：1990-03-14

申请号：EP89114934.6

申请日：1989-08-11

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY INC. (a New York corporation)

Inventor： Miller, David James ,  Bryant, David Robert ,  Billig, Ernst (NMN) ,  Shaw, Bernard Leslie, Prof.

IPC: B01J31/40 ,  C07C45/50

CPC classification number: B01J31/4046 ,  B01J31/0201 ,  B01J31/0215 ,  B01J31/0231 ,  B01J31/0255 ,  B01J31/04 ,  B01J31/24 ,  B01J31/2404 ,  B01J2231/321 ,  B01J2531/822 ,  C07C45/50 ,  Y02P20/582 ,  Y02P20/584 ,  C07C47/02

Abstract: A process for improving the catalytic activity of a partially deactivated solubilized rhodium - tertiary organophosphine complex hydroformylation catalyst.

Abstract translation: 一种提高部分失活的溶解铑 - 叔有机膦配合物加氢甲酰化催化剂的催化活性的方法。