公开(公告)号：EP0422452A2

公开(公告)日：1991-04-17

申请号：EP90118575.1

申请日：1990-09-27

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Rhee, Seung Joon ,  Baker, Edgar Chapman ,  Edwards, David Nicholas ,  Lee, Kiu Hee ,  Moorhouse, John Henry ,  Scarola, Leonard Sebastian ,  Karol, Frederick John

IPC: C08F2/44 ,  C08F2/34 ,  C08F210/16 ,  C08F36/06 ,  C08F297/08

CPC classification number: C08F2/44 ,  B29K2019/00 ,  B29K2021/00 ,  B29K2023/16 ,  B29K2105/16 ,  C08F210/18 ,  Y10S526/901 ,  C08F2/34

Abstract: A process for producing sticky polymers at polymerization reaction temperatures in excess of the softening temperature of the sticky polymers in a fluidized bed reactor catalyzed by a transition metal catalyst, which comprises conducting the polymerization reaction above the softening temperatures of the sticky polymers in the presence of about 0.3 to about 80 weight percent, based on the weight of the final product of an inert particulate material having a mean particle size of from about 0.01 to about 10 microns whereby polymer agglomeration of the sticky polymers is maintained at a size suitable for continuously producing the sticky polymers.

Abstract translation: 在由过渡金属催化剂催化的流化床反应器中的聚合反应温度超过粘性聚合物的软化温度的粘合聚合物生产粘合聚合物的方法，该方法包括在聚合反应温度高于粘聚聚物的软化温度的情况下， 约0.3至约80重量％，基于平均粒度为约0.01至约10微米的惰性颗粒材料的最终产物的重量，由此粘合聚合物的聚合物附聚保持在适于连续生产的尺寸 粘性聚合物。

公开(公告)号：EP0435250A3

公开(公告)日：1992-02-26

申请号：EP90125492.0

申请日：1990-12-27

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Edwards, David Nicholas ,  Jorgensen, Robert James ,  Lee, Kiu Hee ,  Marcinkowsky, Arthur Ernest

IPC: C08F210/02 ,  C08F4/646

CPC classification number: C08F210/16 ,  Y10S526/905 ,  C08F4/646 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/03

Abstract: Ethylene copolymers having a very low molecular weight are continuously prepared in a fluidized bed in the presence of reduced concentrations of hydrogen, at improved catalyst activity and polymer productivity, by effecting polymerization in the presence of a dialkylzinc compound.

Abstract translation: 通过在二烷基锌化合物的存在下进行聚合，在减少浓度的氢的存在下，在改善的催化剂活性和聚合物生产率的情况下，在流化床中连续制备具有非常低分子量的乙烯共聚物。

公开(公告)号：EP0422452B1

公开(公告)日：2000-03-01

申请号：EP90118575.1

申请日：1990-09-27

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Rhee, Seung Joon ,  Baker, Edgar Chapman ,  Edwards, David Nicholas ,  Lee, Kiu Hee ,  Moorhouse, John Henry ,  Scarola, Leonard Sebastian ,  Karol, Frederick John

IPC: C08F2/44 ,  C08F2/34 ,  C08F210/16 ,  C08F36/06 ,  C08F297/08

CPC classification number: C08F2/44 ,  B29K2019/00 ,  B29K2021/00 ,  B29K2023/16 ,  B29K2105/16 ,  C08F210/18 ,  Y10S526/901 ,  C08F2/34

公开(公告)号：EP0422452A3

公开(公告)日：1992-02-05

申请号：EP90118575.1

申请日：1990-09-27

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Rhee, Seung Joon ,  Baker, Edgar Chapman ,  Edwards, David Nicholas ,  Lee, Kiu Hee ,  Moorhouse, John Henry ,  Scarola, Leonard Sebastian ,  Karol, Frederick John

IPC: C08F2/44 ,  C08F2/34 ,  C08F210/16 ,  C08F36/06 ,  C08F297/08

CPC classification number: C08F2/44 ,  B29K2019/00 ,  B29K2021/00 ,  B29K2023/16 ,  B29K2105/16 ,  C08F210/18 ,  Y10S526/901 ,  C08F2/34

Abstract: A process for producing sticky polymers at polymerization reaction temperatures in excess of the softening temperature of the sticky polymers in a fluidized bed reactor catalyzed by a transition metal catalyst, which comprises conducting the polymerization reaction above the softening temperatures of the sticky polymers in the presence of about 0.3 to about 80 weight percent, based on the weight of the final product of an inert particulate material having a mean particle size of from about 0.01 to about 10 microns whereby polymer agglomeration of the sticky polymers is maintained at a size suitable for continuously producing the sticky polymers.

公开(公告)号：EP0435250A2

公开(公告)日：1991-07-03

申请号：EP90125492.0

申请日：1990-12-27

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Edwards, David Nicholas ,  Jorgensen, Robert James ,  Lee, Kiu Hee ,  Marcinkowsky, Arthur Ernest

IPC: C08F210/02 ,  C08F4/646

CPC classification number: C08F210/16 ,  Y10S526/905 ,  C08F4/646 ,  C08F210/14 ,  C08F2500/02 ,  C08F2500/18 ,  C08F2500/12 ,  C08F2500/24 ,  C08F2500/03

Abstract: Ethylene copolymers having a very low molecular weight are continuously prepared in a fluidized bed in the presence of reduced concentrations of hydrogen, at improved catalyst activity and polymer productivity, by effecting polymerization in the presence of a dialkylzinc compound.

Abstract translation: 通过在二烷基锌化合物的存在下进行聚合，在减少浓度的氢的存在下，在改善的催化剂活性和聚合物生产率的情况下，在流化床中连续制备具有非常低分子量的乙烯共聚物。