公开(公告)号：EP0417710A3

公开(公告)日：1991-07-10

申请号：EP90117422.7

申请日：1990-09-10

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Rifi, Mahmoud Rashad ,  Lee, Kiu Hee ,  Kriss Mark John ,  Liu, Han-Tai

IPC: C08F210/18 ,  C08F4/635 ,  C08F4/637

CPC classification number: C08F210/18 ,  Y10S526/901 ,  Y10S526/905 ,  C08F4/637 ,  C08F4/635 ,  C08F4/68

Abstract: A process for the production of EPDM comprising reacting ethylene, propylene, ethylidene norbornene, and hydrogen, in the gas phase, in a fluidized bed, under polymerization conditions, in the presence of a catalyst system comprising:
(a) the reaction product of a vanadium compound and a electron donor; (b) at least one modifier having the formula BX₃ or AlR (3-a) X a wherein each R is alkyl or aryl and alike or different; each X is independently chlorine, bromine, or iodine; and a is 0, 1, or 2, wherein components (a) and (b) are impregnated into an inorganic support;
(c) a halocarbon promoter; and (d) a hydrocarbyl aluminum cocatalyst with the following proviso:
(i) the partial pressure of ethylene is in the range of about 25 to about 200 psi; (ii) the molar ratio of propylene to ethylene is in the range of about 0.2:1 to about 2:1; (iii) the molar ratio of hydrogen to ethylene is in the range of about 0.0001:1 to about 0.01:1; and (iv) the amount of ethylidene norbornene is about 1.5 to about 15 percent by weight based on the weight of the fluidized bed.

公开(公告)号：EP0417710B1

公开(公告)日：1995-10-11

申请号：EP90117422.7

申请日：1990-09-10

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Rifi, Mahmoud Rashad ,  Lee, Kiu Hee ,  Kriss Mark John ,  Liu, Han-Tai

IPC: C08F210/18 ,  C08F4/635 ,  C08F4/637

CPC classification number: C08F210/18 ,  Y10S526/901 ,  Y10S526/905 ,  C08F4/637 ,  C08F4/635 ,  C08F4/68

公开(公告)号：EP0417711A3

公开(公告)日：1991-11-21

申请号：EP90117423.5

申请日：1990-09-10

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Rifi, Mahmoud Rashad ,  Lee, Kiu Hee ,  Kriss, Mark John ,  Liu, Han-Tai

IPC: C08F210/18 ,  C08F4/656 ,  C08F4/657

CPC classification number: C08F210/18 ,  Y10S526/901 ,  C08F4/6574 ,  C08F4/6555

Abstract: A process for the production of EPDM comprising reacting ethylene, propylene, ethylidene norbornene, and hydrogen, in the gas phase, in a fluidized bed, under polymerization conditions, in the presence of a catalyst system comprising:
(a) a titanium based catalyst having the formula Mg a Ti(OR) b X c (ED) d wherein
R is an aliphatic or aromatic hydrocarbon radical having 1 to 14 carbon atoms or COR′ wherein R′ is an aliphatic or aromatic hydrocarbon radical having 1 to 14 carbon atoms;
each OR group is alike or different;
each X is independently chlorine, bromine, or iodine
ED is an electron donor
a is 0.5 to 56;
b is 0, 1, or 2;
c is 2 to 116; and
d is greater than 1.5 a + 2; (b) at least one modifier having the formula BX₃ or AlR (3-b) X b wherein each R is alkyl or aryl and is alike or different, and X and b are as defined above for component (a), wherein components (a) and (b) are impregnated into an inorganic support; and
(c) a hydrocarbyl aluminum cocatalyst with the following proviso:
(i) the partial pressure of ethylene is in the range of about 10 to about 150 psi; (ii) the molar ratio of propylene to ethylene is in the range of about 1.5:1 to about 5:1; (iii) the molar ratio of hydrogen to ethylene is in the range of about 0.001:1 to about 0.1:1; and (iv) the amount of ethylidene norbornene is about 1.5 to about 15 percent by weight based on the weight of the fluidized bed.

Abstract translation: 一种生产EPDM的方法，包括在聚合条件下，在催化剂体系存在下，在气相中使乙烯，丙烯，亚乙基降冰片烯和氢气在流化床中反应，所述催化剂体系包含：（a） 通式MgaTi（OR）bXc（ED）d其中R是具有1-14个碳原子的脂族或芳族烃基或COR'，其中R'是具有1-14个碳原子的脂族或芳族烃基; 每个OR组相同或不同; 每个X独立地为氯，溴或碘; ED为电子给体a为0.5至56; b是0,1或2; c是2至116; 并且d大于1.5 a + 2; （b）至少一种具有式BX 3或AlR（3-b）X b的改性剂，其中每个R为烷基或芳基且相同或不同，且X和b如上面对组分（a）的定义，其中组分 ）和（b）浸渍到无机载体中; 和（c）具有以下条件的烃基铝助催化剂：（i）乙烯的分压范围为约10至约150psi; （ii）丙烯与乙烯的摩尔比在约1.5:1至约5:1的范围内; （iii）氢与乙烯的摩尔比在约0.001:1至约0.1:1的范围内; 和（iv）亚乙基降冰片烯的量基于流化床的重量为约1.5至约15重量％。

公开(公告)号：EP0417711A2

公开(公告)日：1991-03-20

申请号：EP90117423.5

申请日：1990-09-10

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Rifi, Mahmoud Rashad ,  Lee, Kiu Hee ,  Kriss, Mark John ,  Liu, Han-Tai

IPC: C08F210/18 ,  C08F4/656 ,  C08F4/657

CPC classification number: C08F210/18 ,  Y10S526/901 ,  C08F4/6574 ,  C08F4/6555

Abstract: A process for the production of EPDM comprising reacting ethylene, propylene, ethylidene norbornene, and hydrogen, in the gas phase, in a fluidized bed, under polymerization conditions, in the presence of a catalyst system comprising:

(a) a titanium based catalyst having the formula Mg a Ti(OR) b X c (ED) d wherein
R is an aliphatic or aromatic hydrocarbon radical having 1 to 14 carbon atoms or COR′ wherein R′ is an aliphatic or aromatic hydrocarbon radical having 1 to 14 carbon atoms;
each OR group is alike or different;
each X is independently chlorine, bromine, or iodine
ED is an electron donor
a is 0.5 to 56;
b is 0, 1, or 2;
c is 2 to 116; and
d is greater than 1.5 a + 2;
(b) at least one modifier having the formula BX₃ or AlR (3-b) X b wherein each R is alkyl or aryl and is alike or different, and X and b are as defined above for component (a),
wherein components (a) and (b) are impregnated into an inorganic support; and

(c) a hydrocarbyl aluminum cocatalyst with the following proviso:

(i) the partial pressure of ethylene is in the range of about 10 to about 150 psi;
(ii) the molar ratio of propylene to ethylene is in the range of about 1.5:1 to about 5:1;
(iii) the molar ratio of hydrogen to ethylene is in the range of about 0.001:1 to about 0.1:1; and
(iv) the amount of ethylidene norbornene is about 1.5 to about 15 percent by weight based on the weight of the fluidized bed.

Abstract translation: 一种制备EPDM的方法，包括在气相中在流化床中，在聚合条件下，在催化剂体系存在下，使乙烯，丙烯，亚乙基降冰片烯和氢反应，所述催化剂体系包含：（a）钛基催化剂，其具有 式MgaTi（OR）bXc（ED）d其中R是具有1至14个碳原子的脂族或芳族烃基或COR min，其中R min是具有1至14个碳原子的脂族或芳族烃基; 每个OR组是相似或不同的; 每个X独立地是氯，溴或碘ED是电子给体a是0.5至56; b为0,1或2; c为2至116; d大于1.5a + 2; （b）具有式BX3或AlR（3-b）Xb的至少一种改性剂，其中每个R是烷基或芳基，并且相同或不同，X和b如上对组分（a）的定义，其中组分 ）和（b）浸渍到无机载体中; 和（c）烃基铝助催化剂，具有以下条件：（i）乙烯的分压在约10至约150psi的范围内; （ii）丙烯与乙烯的摩尔比在约1.5:1至约5:1的范围内; （iii）氢与乙烯的摩尔比在约0.001:1至约0.1:1的范围内; 和（iv）基于流化床的重量，亚乙基降冰片烯的量为约1.5至约15重量％。

公开(公告)号：EP0417711B1

公开(公告)日：1994-11-30

申请号：EP90117423.5

申请日：1990-09-10

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Rifi, Mahmoud Rashad ,  Lee, Kiu Hee ,  Kriss, Mark John ,  Liu, Han-Tai

IPC: C08F210/18 ,  C08F4/656 ,  C08F4/657

CPC classification number: C08F210/18 ,  Y10S526/901 ,  C08F4/6574 ,  C08F4/6555

公开(公告)号：EP0417710A2

公开(公告)日：1991-03-20

申请号：EP90117422.7

申请日：1990-09-10

Applicant: UNION CARBIDE CHEMICALS AND PLASTICS COMPANY, INC.

Inventor： Rifi, Mahmoud Rashad ,  Lee, Kiu Hee ,  Kriss Mark John ,  Liu, Han-Tai

IPC: C08F210/18 ,  C08F4/635 ,  C08F4/637

CPC classification number: C08F210/18 ,  Y10S526/901 ,  Y10S526/905 ,  C08F4/637 ,  C08F4/635 ,  C08F4/68

Abstract: A process for the production of EPDM comprising reacting ethylene, propylene, ethylidene norbornene, and hydrogen, in the gas phase, in a fluidized bed, under polymerization conditions, in the presence of a catalyst system comprising:

(a) the reaction product of a vanadium compound and a electron donor;
(b) at least one modifier having the formula BX₃ or AlR (3-a) X a wherein each R is alkyl or aryl and alike or different; each X is independently chlorine, bromine, or iodine; and a is 0, 1, or 2,
wherein components (a) and (b) are impregnated into an inorganic support;

(c) a halocarbon promoter; and
(d) a hydrocarbyl aluminum cocatalyst
with the following proviso:

(i) the partial pressure of ethylene is in the range of about 25 to about 200 psi;
(ii) the molar ratio of propylene to ethylene is in the range of about 0.2:1 to about 2:1;
(iii) the molar ratio of hydrogen to ethylene is in the range of about 0.0001:1 to about 0.01:1; and
(iv) the amount of ethylidene norbornene is about 1.5 to about 15 percent by weight based on the weight of the fluidized bed.

Abstract translation: 一种生产EPDM的方法，包括在聚合条件下，在催化剂体系存在下，在气相中使乙烯，丙烯，亚乙基降冰片烯和氢气在流化床中反应，所述催化剂体系包含：（a） 钒化合物和电子给体; （b）至少一种具有式BX 3或AlR（3-a）X a的改性剂，其中每个R为烷基或芳基并且可以相同或不同; 每个X独立地为氯，溴或碘; a为0,1或2，其中组分（a）和（b）浸渍到无机载体中; （c）卤化碳促进剂; 和（d）烃基铝助催化剂，其条件如下：（i）乙烯的分压范围为约25至约200psi; （ii）丙烯与乙烯的摩尔比在约0.2:1至约2:1的范围内; （iii）氢与乙烯的摩尔比在约0.0001:1至约0.01:1的范围内; 和（iv）亚乙基降冰片烯的量基于流化床的重量为约1.5至约15重量％。