ADDITION PROCESS FOR PRODUCING SILOXANE ALCOHOLS

    公开(公告)号:GB1293331A

    公开(公告)日:1972-10-18

    申请号:GB102670

    申请日:1970-01-08

    Inventor: MARLIN LAWRENCE

    Abstract: 1293331 Preparation of siloxane alcohols UNION CARBIDE CORP 8 Jan 1970 [13 Jan 1969] 1026/70 Heading C3T A siloxane alcohol is prepared by reaction of a siloxane containing an SiH group and free of aliphatic unsaturation with a compound containing an alcoholic hydroxy group and an olefinic double bond, in the presence of a platinum catalyst and a base soluble in water or a 6 : 10 v./v. mixture of water and isopropanol at 0-1 N concentration to give a pH of 8-12. Suitable alkenols and alkenyl ethers of polyols are listed, including cyclic acetals; monoalkenyl ethers of polyoxyalkylene glycols are preferred. Preferred siloxanes are linear hydrogen-hydrocarbon polysiloxanes. Examples describe the reaction of polysiloxanes with allyl alcohol or HO(C 2 H 4 O) 7 CH 2 CH=CH 2 or a mixture of this with its methyl ether, in the presence of H 2 PtCl 6 and hexadecyl dimethylamine, NaHCO 3 or Na 2 CO 3 , in xylene. The base suppresses reaction of -OH with SiH groups.

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