公开(公告)号：CA984211A

公开(公告)日：1976-02-24

申请号：CA157157

申请日：1972-11-22

Applicant: UNION CARBIDE CORP

Inventor： SANDNER MICHAEL R ,  OSBORN CLAIBORN L

IPC: C08F283/01 ,  C09D4/00 ,  C09D11/10 ,  G03F7/031

公开(公告)号：CA1123547A

公开(公告)日：1982-05-11

申请号：CA305699

申请日：1978-06-19

Applicant: UNION CARBIDE CORP

Inventor： CARDER CHARLES H ,  OSBORN CLAIBORN L ,  HODAKOWSKI LEONARD E

IPC: C08F2/00 ,  C08F2/54 ,  C08F290/00 ,  C08F299/00 ,  C08G18/00 ,  C08G18/67 ,  C09D3/72 ,  G03C1/70

Abstract: A radiation curable composition produced by the reaction of poly(alkyleneoxy)polyol or polyester polyol, organic diisocyanate, hydroxyalkyl acrylate, at a temperature of from about 30.degree.C to about 80.degree.C, wherein for each hydroxy equivalent in the polyol, 2.5 to about 8.0 equivalents of organic diisocyanate and 1.5 to about 6.0 equivalents of hydroxyalkyl acrylate is reacted.

公开(公告)号：CA1246290A

公开(公告)日：1988-12-06

申请号：CA457741

申请日：1984-06-28

Applicant: UNION CARBIDE CORP

Inventor： OSBORN CLAIBORN L ,  KOLESKE JOSEPH V ,  DRAKE KENNETH

IPC: C09D5/23 ,  B23D45/12 ,  C08G18/67 ,  C09D5/00 ,  C09D133/00 ,  C09D133/04 ,  C09D175/14 ,  C09D201/02 ,  C08L75/00

Abstract: Described herein are compositions comprising the reaction product of a polyol, a multi-functional isocyanate, a lactone-acrylate adduct and an hydroxyalkyl acrylate. These compositions are suitable for use as curable coatings.

公开(公告)号：CA1131388A

公开(公告)日：1982-09-07

申请号：CA325733

申请日：1979-04-18

Applicant: UNION CARBIDE CORP

Inventor： OSBORN CLAIBORN L

IPC: C08F2/00 ,  C08F2/48 ,  C08F2/54 ,  C08F290/00 ,  C08F299/00 ,  C08F299/06 ,  C08G18/00 ,  C08G18/28 ,  C08G18/67 ,  C09D4/00 ,  C08F220/36 ,  C08F220/20 ,  C08J3/28

Abstract: 10673 RADIATION CURABLE URETHANE COMPOSITIONS Radiation curable urethane compositions obtained by the reaction of an organic polyisocyanate, an hydroxyalkyl acrylyl compound and an hydroxyl compound. The compositions are useful in coatings, inks, adhesives and textile applications. S P E C I F I C A T I O N 1.

公开(公告)号：CA1266345A

公开(公告)日：1990-02-27

申请号：CA476132

申请日：1985-03-08

Applicant: UNION CARBIDE CORP

Inventor： KOLESKE JOSEPH V ,  OSBORN CLAIBORN L

IPC: C08F16/00 ,  C08F2/48 ,  C08F2/50 ,  C08F16/12 ,  C08F16/22 ,  C08F220/36 ,  C08F234/02 ,  C08F290/00 ,  C08F299/00 ,  C08F299/06 ,  C09D5/00 ,  C09D175/14 ,  C09D3/00

Abstract: BLENDS OF CYCLIC VINYL ETHER CONTAINING COMPOUNDS AND URETHANE ACRYLATES Described herein are compositions suitable for photocopolymerization comprising a cyclic vinyl ether containing compound and urethane acrylates. Photocurable coatings can be prepared from such composition and such coatings have markedly improved flexibility and impact resistant properties. S P E C I F I C A T I O N D-13,889

公开(公告)号：CA1091389A

公开(公告)日：1980-12-09

申请号：CA256322

申请日：1976-07-05

Applicant: UNION CARBIDE CORP

Inventor： HODAKOWSKI LEONARD E ,  OSBORN CLAIBORN L ,  HARRIS EDWARD B

IPC: C08F20/00 ,  C08F20/32 ,  C08F290/00 ,  C08F299/00 ,  C08G59/00 ,  C08G59/14 ,  C08G59/17 ,  C08G59/22 ,  C09D4/00 ,  C09D11/00 ,  C09D11/10 ,  C08G59/16 ,  C08L63/10

Abstract: Polymerizable reaction product mixture are prepared by the reaction of an epoxide of a long chain(1) unsaturated fatty oil or (ii) unsaturated fatty acid or ester thereof with a mixture of (a) acrylic acid or methacrylic acid, (b) a diepoxide, and (c) at least one other modifying compound. The modifying compounds contain a group that will react with the epoxidized fatty oil or with the epoxidized fatty acid or ester. The mixtures produced are useful per se and in formulations as inks or coatings that are curable by exposure to radiation or by heating.

公开(公告)号：CA1083598A

公开(公告)日：1980-08-12

申请号：CA264395

申请日：1976-10-28

Applicant: UNION CARBIDE CORP

Inventor： HODAKOWSKI LEONARD E ,  OSBORN CLAIBORN L

IPC: C08F2/46 ,  C08F32/00 ,  C09D11/10 ,  C07C69/74

Abstract: Polymerizable reaction product mixtures containing cycloalkenylcarbonyloxy compounds are produced by the reaction of a conjugated diene with (i) an acrylate or methacrylate ester of an epoxidized long chain unsaturated fatty oil or (ii) an acrylate or methacrylate of an epoxidized long chain unsaturated fatty acid or ester thereof. The reaction product mixtures obtained are useful per se and in formulations as inks or coatings that can be cured by exposure to radiation or heat. 1.

公开(公告)号：CA1183299A

公开(公告)日：1985-02-26

申请号：CA374363

申请日：1981-04-01

Applicant: UNION CARBIDE CORP

Inventor： WANG ALAN E ,  KNOPF ROBERT J ,  OSBORN CLAIBORN L

IPC: C08F2/00 ,  C07D309/22 ,  C08F2/50 ,  C08F2/54 ,  C08F34/00 ,  C08G65/00 ,  C08G65/22 ,  C08G83/00 ,  C09D145/00 ,  C09D171/00 ,  C08K5/23 ,  C08K5/00 ,  C08K5/41 ,  C09D3/727

Abstract: CATIONICALLY POLYMERIZABLE RADIATION CURABLE COMPOSITIONS Compositions of a compound having at least one cyclic vinyl ether moiety and a catalyst capable of forming an acid when exposed to ultraviolet light. The compositions cure via a cationic polymerization mechanism when exposed to the ultraviolet. Particularly useful compounds are the derivatives of 3,4-dihydropyran-2-methanol. S P E C I F I C A T I O N

公开(公告)号：CA986879A

公开(公告)日：1976-04-06

申请号：CA173054

申请日：1973-06-04

Applicant: UNION CARBIDE CORP

Inventor： OSBORN CLAIBORN L ,  TROUE HARDEN H

IPC: C08F2/00 ,  B05D3/06 ,  C08F2/02 ,  C08F2/46 ,  C08F2/48 ,  C08J3/28 ,  C09D5/00

Abstract: 1423548 Coated products UNION CARBIDE CORP 25 June 1973 [26 June 1972] 30020/73 Heading B2E [Also in Division C3] A process for preferentially curing the exterior surface of a coating, on a substrate, of a composition containing a photo curable monomer or polymer having at least one polymerisable acrylyl or methacrylyl group comprises exposing said layer under an inert gas atmosphere to a low pressure mercury shortwave ultra violet radiation source, at least 75% of the radiated power being at a wavelength of 2537A, in the presence or absence of a photo sensitiser, (the term "preferentially curing the exterior surface" is used to mean that curing commences on the film surface and the bulk or body of the film subsequently cures (or crosslinks) by further treatment). In various embodiments the specified radiation can be used sequentially, in any order, together with another form of radiation selected from ultra violet radiation from medium pressure mercury lamps; high intensity predominantly continuum light radiation from a swirlflow plasma arc radiation source; radiation from radio active materials; and electron beam radiation. Heating may also be employed. The photocurable composition may optionally include pigments, fillers, stabilisers, and polymers or oligomers. Various (meth)acrylic compounds are listed as the curable component and several examples of photo sensitisers are disclosed, as well as polymeric additives. Curable components used in the Examples are acrylate and methacrylate esters of monohydric and polyhydric alcohols, including such esters as 2- (methyl carbamyl)-ethyl acrylate, dicyclopentenyl acrylate, 2-phenoxyethyl acrylate, pentaerythritol triacrylate, 2-hydroxyethyl acrylate and neopentyl glycol diacrylate, acrylate-containing urethane oligomers, and acrylated epoxidised soya bean oil; photosensitisers used are diphenyl ketone, benzoin butyl ether, benzoin methyl ether, 2, 2-diethoxyacetophenone and 2-chlorothioxanthone/methyldiethanolamine. Coatings can be cured on such substrates as paper, glass, fabric, metal coil, wood, metal or plastics panels, floor coverings, composition boards, asbestos panels, electrical conductors and magnet wires.

公开(公告)号：CA980718A

公开(公告)日：1975-12-30

申请号：CA155490

申请日：1972-11-03

Applicant: UNION CARBIDE CORP

Inventor： OSBORN CLAIBORN L ,  SANDNER MICHAEL R ,  TRECKER DAVID J

IPC: B01J19/12 ,  C07C2/42 ,  C07C17/02 ,  C07C17/14 ,  C07C51/567 ,  C07C303/04 ,  C07C309/25 ,  C07D305/14