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    2.
    发明专利
    未知

    公开(公告)号：DE2855233A1

    公开(公告)日：1979-06-28

    申请号：DE2855233

    申请日：1978-12-21

    Applicant: UNION CARBIDE CORP

    Inventor： TAYLOR GLENN ALFRED ,  WOLF PHILIP FRANK

    IPC: C07C29/12 ,  B01J27/00 ,  B01J27/232 ,  C07C27/00 ,  C07C29/09 ,  C07C31/20 ,  C07C67/00 ,  C07C29/00

    Abstract: This invention is concerned with producing glycols of the formula HOCHRCH2OH from hydrolysis, in a homogeneous liquid phase mixture, of an alkylene carbonate of the formula in which R is either hydrogen or methyl. This is accomplished by using an amount of water in excess of stoichiometry and using potassium carbonate as the preferred catalyst. The reaction is effected under a carbon dioxide pressure of at least 80 psig and the reaction temperature is desirably between about 85 DEG C. and 500 DEG C.

    4.
    发明专利
    未知

    公开(公告)号：BR8404821A

    公开(公告)日：1985-08-13

    申请号：BR8404821

    申请日：1984-09-25

    Applicant: UNION CARBIDE CORP

    Inventor： HOY KENNETH LOOK ,  TAYLOR GLENN ALFRED

    IPC: C08L51/08 ,  C08G18/00 ,  C08G18/48 ,  C08G18/50 ,  C08G18/66 ,  C08G65/26 ,  C08G65/28 ,  C08G65/329 ,  C08L51/00 ,  C08L71/00 ,  C08L71/02 ,  C08G18/60

    Abstract: Novel polyols, useful in, for example, reaction injection molding, high resiliency foams and the preparation of polymer/polyols, characterized by the following formula: wherein A and A', which may be the same or different, are conductive atoms - carbon, oxygen or combinations thereof with hydrogen atoms or the like satisfying the valences; B is nitrogen (N) or CR, R being hydrogen, alkyl, aryl or the like; Q is 0, CH2O, C2H4O, C3H6O, or C4H8O; D is an oxyalkylene or X and X', which may be the same or different, are OH, NH2 or H; Z is OH; n and d are integers of 0 to 10 and the sum of n and d does not exceed 10; s is 0 or 1, and m is an integer of at least about 16, with the proviso that when B is N and either n or d is zero, X and X' are other than H, provide processing advantages and are highly compatible with low molecular weight extenders such as ethylene glycol.

    NOVEL POLYOLS
    6.
    发明专利
    NOVEL POLYOLS 未知

    公开(公告)号：AU3354784A

    公开(公告)日：1985-04-04

    申请号：AU3354784

    申请日：1984-09-26

    Applicant: UNION CARBIDE CORP

    Inventor： HOY KENNETH LOOK ,  TAYLOR GLENN ALFRED

    IPC: C08L51/08 ,  C08G18/00 ,  C08G18/48 ,  C08G18/50 ,  C08G18/66 ,  C08G65/26 ,  C08G65/28 ,  C08G65/329 ,  C08L51/00 ,  C08L71/00 ,  C08L71/02 ,  C07C43/14 ,  C07C93/04 ,  C08F283/06 ,  C08G18/14 ,  C08J5/02

    Abstract: Novel polyols, useful in, for example, reaction injection molding, high resiliency foams and the preparation of polymer/polyols, characterized by the following formula: wherein A and A', which may be the same or different, are conductive atoms - carbon, oxygen or combinations thereof with hydrogen atoms or the like satisfying the valences; B is nitrogen (N) or CR, R being hydrogen, alkyl, aryl or the like; Q is 0, CH2O, C2H4O, C3H6O, or C4H8O; D is an oxyalkylene or X and X', which may be the same or different, are OH, NH2 or H; Z is OH; n and d are integers of 0 to 10 and the sum of n and d does not exceed 10; s is 0 or 1, and m is an integer of at least about 16, with the proviso that when B is N and either n or d is zero, X and X' are other than H, provide processing advantages and are highly compatible with low molecular weight extenders such as ethylene glycol.

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