公开(公告)号：NO801919L

公开(公告)日：1980-12-29

申请号：NO801919

申请日：1980-06-26

Applicant: UNION CARBIDE CORP

Inventor： BARTLEY WILLIAM J ,  WILSON THOMAS PUTNAM

IPC: B01J23/58 ,  B01J23/656 ,  C07C29/151 ,  C07C29/158 ,  C07C45/49 ,  C07C51/10 ,  C07C

公开(公告)号：NO801919A

公开(公告)日：1980-12-29

申请号：NO801919

申请日：1980-06-26

Applicant: UNION CARBIDE CORP

Inventor： BARTLEY WILLIAM J ,  WILSON THOMAS PUTNAM

IPC: B01J23/58 ,  B01J23/656 ,  C07C29/151 ,  C07C29/158 ,  C07C45/49 ,  C07C51/10 ,  C07C

CPC classification number: C07C45/49 ,  B01J23/58 ,  B01J23/6562 ,  C07C29/1512 ,  C07C29/158 ,  C07C51/10 ,  C07C47/06 ,  C07C53/08 ,  C07C31/08

公开(公告)号：NO801917A

公开(公告)日：1980-12-29

申请号：NO801917

申请日：1980-06-26

Applicant: UNION CARBIDE CORP

Inventor： BARTLEY WILLIAM J ,  WILSON THOMAS PUTNAM ,  ELLGEN PAUL CLIFFORD

IPC: C07C53/08 ,  B01J23/00 ,  B01J23/58 ,  B01J23/656 ,  C07B61/00 ,  C07C27/00 ,  C07C27/06 ,  C07C29/15 ,  C07C29/151 ,  C07C29/158 ,  C07C31/08 ,  C07C45/00 ,  C07C45/49 ,  C07C47/06 ,  C07C51/00 ,  C07C51/10 ,  C07C67/00 ,  C07C

CPC classification number: C07C45/49 ,  B01J23/58 ,  B01J23/6562 ,  C07C29/1512 ,  C07C29/158 ,  C07C51/10 ,  C07C47/06 ,  C07C53/08 ,  C07C31/08

公开(公告)号：DE3062016D1

公开(公告)日：1983-03-24

申请号：DE3062016

申请日：1980-06-27

Applicant: UNION CARBIDE CORP

Inventor： BARTLEY WILLIAM J ,  WILSON THOMAS PUTNAM

IPC: B01J23/58 ,  B01J23/656 ,  C07C29/151 ,  C07C29/158 ,  C07C45/49 ,  C07C51/10 ,  C07C27/06 ,  B01J23/64 ,  C07C31/08 ,  C07C47/06 ,  C07C53/08

公开(公告)号：NO801917L

公开(公告)日：1980-12-29

申请号：NO801917

申请日：1980-06-26

Applicant: UNION CARBIDE CORP

Inventor： BARTLEY WILLIAM J ,  WILSON THOMAS PUTNAM ,  ELLGEN PAUL CLIFFORD

IPC: C07C53/08 ,  B01J23/00 ,  B01J23/58 ,  B01J23/656 ,  C07B61/00 ,  C07C27/00 ,  C07C27/06 ,  C07C29/15 ,  C07C29/151 ,  C07C29/158 ,  C07C31/08 ,  C07C45/00 ,  C07C45/49 ,  C07C47/06 ,  C07C51/00 ,  C07C51/10 ,  C07C67/00 ,  C07C

Abstract: A process for selectively preparing a mixture of two-carbon atom oxygenated hydrocarbons, namely, acetic acid, ethanol and acetaldehyde, by continuously contacting a gaseous reaction mixture containing hydrogen and carbon monoxide with a solid catalyst comprising rhodium in combination with one or more alkali metals selected from the group consisting of lithium, potassium, cesium and rubidium at reaction conditions correlated so as to favor the formation of a substantial proportion of such two-carbon atom products.

公开(公告)号：GB1176692A

公开(公告)日：1970-01-07

申请号：GB381267

申请日：1967-01-25

Applicant: UNION CARBIDE CORP

Inventor： MANYIK ROBERT MICHAEL ,  WALKER WELLINGTON EPLER ,  WILSON THOMAS PUTNAM

IPC: C07F5/06 ,  C08F10/00

Abstract: 1,176,692. Polymerisation catalysts. UNION CARBIDE CORP. 25 Jan., 1967, No. 3812/67. Heading B1E. [Also in Division C3] A catalyst complex is formed by a process comprising:-(1) introducing a first stream of a dry, inert, liquid hydrocarbon solvent to a first contact zone containing water to wet said first stream; (2) introducing the watercontaining first stream and a second stream which is a solution of a (C 1-12 ) hydrocarbyl aluminium compound in a dry, inert, liquid hydrocarbon solvent to a second reaction zone, wherein the hydrocarbyl aluminium compound and water react to form a solution of poly (hydrocarbyl aluminium oxide) in the hydrocarbon solvent, and (3) after aging said solution, adding thereto a Group IVA, VA or VIA transition metal compound to complete the formation of the catalyst complex. A flow diagram of the process is provided. Exemplified catalysts are mixtures of poly (isobutyl aluminium oxide) and chromic 2-ethylhexanoate or chromium acetylacetonate.