Abstract:
Compositions comprising from 0.1 to 15 weight percent of an inhibitor comprising lead chromate or a coprecipitate of lead chromate wherein lead chromate comprises at least 50 weight percent of the coprecipitate allow the use of significantly reduced concentrations of hexavalent chromium rinse in autodeposition coating applications while affording good corrosion protection to the coated metal substrate.
Abstract:
Autodeposition coating compositions containing certain relatively water-insoluble derivatives of glycoluril will crosslink upon curing. The resulting coating exhibits improved block resistance and solvent resistance over heretofore available autodeposition coatings.
Abstract:
Autodeposition coating compositions containing a polymer which is comprised of from 1 to 30 weight percent of N-(alkoxymethyl) acrylamide will crosslink upon curing. The resulting coating exhibits improved block resistance and solvent resistance over heretofore availalble autodeposition coatings.
Abstract:
An improved process is provided for the preparation of the dimer, 2,2-paracyclophane, which is useful as the starting material for parylene conformal coatings used in the electronics industry for the protection of various sensitive electronic components. The process comprises optimization of the normally low yield of dimer formed by the Hofmann elimination reaction of p-methylbenzyltrimethylammonium halide by conducting the elimination reaction in the presence of dimethylsulfoxide and certain reaction promoters.
Abstract:
A process is provided for the preparation of the dimer, dichloro-[2,2]paracyclophane, which is useful as the starting material for the deposition of conformal parylene coatings employed, for example, in the electronics industry for the protection of various sensitive electronic components. The process avoids the normally low yields of chlorinated dimer formed by the chlorination of 2,2-paracycophane and instead utilizes the Hofmann elimination of 2(3)-chloro-p-methylbenzyltrimethylammonium hydroxide by conducting the elimination reaction under carefully controlled conditions of reaction temperature and profile, reaction feed configuration, water concentration in the reactor and the use of a cosolvent, certain reaction promoters, or a combination thereof.
Abstract:
The present invention deals with acrylic or methacrylic acid copolymers and improved autodeposition coating composition containing the same. The new acrylic polymer contains 1-20% of methacrylic acid or 1-12% of acrylic acid, with 75-99% of at least one vinylenically monounsaturated monomer and optionally a hydroxy-containing monomer and a cross-linker and it has a gloss transition temperature of from 2 to 50°C. This acrylic polymer, used under the form of a latex with water and a source of hydrogen ion, provides an aqueous autodeposition coating composition having improved gloss and corrosion, rinse, heat-aging and gasoline resistance.
Abstract:
An improved process is provided for the preparation of the dimer, 2,2-paracyclophane, which is useful as the starting material for parylene conformal coatings used in the electronics industry for the protection of various sensitive electronic components. The process comprises optimization of the normally low yield of dimer formed by the Hofmann elimination reaction of p-methylbenzyltrimethylammonium hydroxide by conducting the elimination reaction in the presence of a cosolvent and certain reaction promoters.