公开(公告)号：WO1992018659A1

公开(公告)日：1992-10-29

申请号：PCT/US1992003082

申请日：1992-04-15

Applicant: UNITED TECHNOLOGIES CORPORATION

Inventor： UNITED TECHNOLOGIES CORPORATION ,  ATHEY, Roy, L. ,  MILLER, John, A. ,  GOSTIC, William, J. ,  GENEREUX, Paul, D. ,  FUESTING, Timothy, P.

IPC: C22F01/10

CPC classification number: C22F1/10 ,  C22C19/056

Abstract: A process for producing a fine grain forged superalloy article having a high yield strength at intermediate temperatures. A preferred starting composition comprises, by weight, 15 % Cr, 13.6 % Co, 4.1 % Mo, 4.6 % Ti, 2.2 % Al, 0.01 % C, 0.007 % B, 0.07 % Zr, balance Ni. This material is forged at a temperature above the gamma prime solvus and at a true strain of at least 0.5. Alternately, the material may be forged below the gamma prime solvus temperature with intermediate super solvus anneals. The overaged material is then worked at a temperature below the gamma prime solvus. The resultant fine grain material is then heat treated or can be further isothermally forged prior to heat treatment to produce complex shapes.

Abstract translation: 一种在中间温度下具有高屈服强度的细晶粒锻造超合金制品的制造方法。 优选的起始组合物包含15％Cr，13.6％Co，4.1％Mo，4.6％Ti，2.2％Al，0.01％C，0.007％B，0.07％Zr，余量为Ni。 该材料在高于伽玛质子溶液的温度下锻炼，真实应变至少为0.5。 或者，可以用中等超固溶退火将材料锻造成低于伽马质子溶质温度。 然后将过时的材料在低于伽玛质子溶液的温度下进行加工。 然后将所得细晶粒材料进行热处理，或者可以在热处理之前进一步等温锻造以产生复杂形状。

公开(公告)号：WO1994013849A1

公开(公告)日：1994-06-23

申请号：PCT/US1993010905

申请日：1993-11-10

Applicant: UNITED TECHNOLOGIES CORPORATION

Inventor： UNITED TECHNOLOGIES CORPORATION ,  MILLER, John, A. ,  PAULONIS, Daniel, F. ,  GENEREUX, Paul, D. ,  SAMUELSON, Jeffrey, W. ,  JACKMAN, Laurence, A. ,  VACCARO, Frederick, P. ,  THOMAS, William, M.

IPC: C22F01/10

CPC classification number: C22C19/056 ,  C22F1/10

Abstract: A process for producing a fine grain forged superalloy article having a high yield strength at intermediate temperatures. A preferred starting composition comprises, by weight, 15 % Cr, 13.6 % Co, 4.1 % Mo, 4.6 % Ti, 2.2 % Al, .01 % C, 0.007 % B, 0.07 % Zr, balance Ni. This material is forged at a temperature above the gamma prime solvus and at a true strain of at least .5. Alternately, the material may be forged below the gamma prime solvus temperature with intermediate super solvus anneals. The overaged material is then worked at a temperature below the gamma prime solvus. The resultant fine grain material is then heat treated or can be further isothermally forged prior to heat treatment to produce complex shapes.

Abstract translation: 一种在中间温度下具有高屈服强度的细晶粒锻造超合金制品的制造方法。 优选的起始组合物包含15％Cr，13.6％Co，4.1％Mo，4.6％Ti，2.2％Al，0.01％C，0.007％B，0.07％Zr，余量为Ni。 该材料在高于伽玛质子溶液的温度下锻炼，至少真正的应变为0.5。 或者，可以用中等超固溶退火将材料锻造成低于伽马质子溶质温度。 然后将过时的材料在低于伽玛质子溶液的温度下进行加工。 然后将所得细晶粒材料进行热处理，或者可以在热处理之前进一步等温锻造以产生复杂形状。

公开(公告)号：WO2014035514A1

公开(公告)日：2014-03-06

申请号：PCT/US2013/044009

申请日：2013-06-04

Applicant: UNITED TECHNOLOGIES CORPORATION

Inventor： SHAH, Dilip, M. ,  CHIN, Herbert, A. ,  MARCIN, John, Joseph ,  REYNOLDS, Paul, L. ,  SUCIU, Gabriel, L. ,  GENEREUX, Paul, D.

IPC: F01D5/04 ,  F01D5/28 ,  C22C19/03

CPC classification number: C21D9/085 ,  B22D27/045 ,  C21D1/26 ,  C21D8/105 ,  C22C19/03 ,  C22C19/056 ,  C22C38/00 ,  C22F1/10 ,  C30B29/52 ,  C30B33/02 ,  F01D5/02 ,  F05D2220/323 ,  F05D2230/40 ,  F05D2240/60 ,  F05D2300/171 ,  F05D2300/501 ,  F05D2300/606 ,  Y02T50/672

Abstract: High modulus turbine shafts and high modulus cylindrical articles are described as are the process parameters for producing these shafts and cylindrical articles. The shafts/articles have a high Young's modulus as a result of having high modulus crystal texture along the longitudinal axis of the shaft/article. The shafts are produced from directionally solidified seeded single crystal cylinders that are axisymmetrically hot worked before a limited recrystallization process is carried out at a temperature below the recrystallization temperature of the alloy. The disclosed process produces an intense singular texture and results in shaft or cylindrical article with a Young's modulus that is at least 40% greater than that of conventional nickel or iron alloys or conventional steels.

Abstract translation: 高模量涡轮轴和高模量圆柱形制品也被描述为用于生产这些轴和圆柱形制品的工艺参数。 轴/制品由于沿轴/制品的纵向轴线具有高模量<111>晶体结构而具有高的杨氏模量。 这些轴由在低于合金的再结晶温度的温度下进行有限再结晶过程之前轴对称加热的定向凝固的接种<111>单晶圆柱体制成。 所公开的方法产生强烈的单数<111>纹理，并导致具有比常规镍或铁合金或常规钢至少大40％的杨氏模量的轴或圆柱形制品。

公开(公告)号：WO1995018875A1

公开(公告)日：1995-07-13

申请号：PCT/US1995000260

申请日：1995-01-09

Applicant: UNITED TECHNOLOGIES CORPORATION

Inventor： UNITED TECHNOLOGIES CORPORATION ,  ATHEY, Roy, L. ,  MILLER, John, A. ,  GOSTIC, William, J. ,  GENEREUX, Paul, D. ,  FUESTING, Timothy, P.

IPC: C22C19/05

CPC classification number: C22C19/056 ,  C22F1/10

Abstract: A process for producing a fine grain forged superalloy article having a high yield strength at intermediate temperatures. A preferred starting composition comprises, by weight, 15 % Cr, 13.6 % Co, 4.1 % Mo, 4.6 % Ti, 2.2 % Al, 0.01 % C, 0.007 % B, 0.07 % Zr, balance Ni. This material is forged at a temperature above the gama prime solvus and at a true strain of at least 0.5. Alternately, the material may be forged below the gamma prime solvus temperature with intermediate super solvus anneals. The overaged material is then worked at a temperature below the gamma prime solvus. The resultant fine grain material is then heat treated or can be further isothermally forged prior to heat treatment to produce complex shapes.

Abstract translation: 一种在中间温度下具有高屈服强度的细晶粒锻造超合金制品的制造方法。 优选的起始组合物包含15％Cr，13.6％Co，4.1％Mo，4.6％Ti，2.2％Al，0.01％C，0.007％B，0.07％Zr，余量为Ni。 这种材料是在高于高分子溶液的温度下锻造的，真实应变至少为0.5。 或者，可以用中等超固溶退火将材料锻造成低于伽马质子溶质温度。 然后将过时的材料在低于伽玛质子溶液的温度下进行加工。 然后将所得细晶粒材料进行热处理，或者可以在热处理之前进一步等温锻造以产生复杂形状。

公开(公告)号：EP2890871B1

公开(公告)日：2017-08-02

申请号：EP13832481.9

申请日：2013-06-04

Applicant: United Technologies Corporation

Inventor： SHAH, Dilip, M. ,  CHIN, Herbert, A. ,  MARCIN, John, Joseph ,  REYNOLDS, Paul, L. ,  SUCIU, Gabriel, L. ,  GENEREUX, Paul, D.

IPC: F01D5/04 ,  F01D5/28 ,  C22C19/03

CPC classification number: C21D9/085 ,  B22D27/045 ,  C21D1/26 ,  C21D8/105 ,  C22C19/03 ,  C22C19/056 ,  C22C38/00 ,  C22F1/10 ,  C30B29/52 ,  C30B33/02 ,  F01D5/02 ,  F05D2220/323 ,  F05D2230/40 ,  F05D2240/60 ,  F05D2300/171 ,  F05D2300/501 ,  F05D2300/606 ,  Y02T50/672

Abstract: High modulus turbine shafts and high modulus cylindrical articles are described as are the process parameters for producing these shafts and cylindrical articles. The shafts/articles have a high Young's modulus as a result of having high modulus crystal texture along the longitudinal axis of the shaft/article. The shafts are produced from directionally solidified seeded single crystal cylinders that are axisymmetrically hot worked before a limited recrystallization process is carried out at a temperature below the recrystallization temperature of the alloy. The disclosed process produces an intense singular texture and results in shaft or cylindrical article with a Young's modulus that is at least 40% greater than that of conventional nickel or iron alloys or conventional steels.

Abstract translation: 描述了高模量涡轮轴和高模量圆柱形制品，以及用于生产这些轴和圆柱形制品的工艺参数。 由于沿轴/制品的纵向轴具有高模量<111>晶体结构，轴/制品具有高杨氏模量。 这些轴由在低于合金再结晶温度的温度下进行有限的再结晶过程之前进行轴对称热加工的定向凝固的晶种<111>单晶圆柱体生产。 所公开的方法产生强烈的单一<111>纹理并且导致轴或圆柱形制品的杨氏模量比传统镍或铁合金或常规钢的杨氏模量高至少40％。

公开(公告)号：EP0533914A1

公开(公告)日：1993-03-31

申请号：EP92911977.0

申请日：1992-04-15

Applicant: UNITED TECHNOLOGIES CORPORATION

Inventor： ATHEY, Roy, L. ,  MILLER, John, A. ,  GOSTIC, William, J. ,  GENEREUX, Paul, D. ,  FUESTING, Timothy, P.

IPC: C22C19 ,  C22F1

CPC classification number: C22F1/10 ,  C22C19/056

Abstract: On décrit un procédé pour produire un article en superalliage forgé à grain fin présentant une résistance à la déformation élevée à des températures intermédiaires. Une composition de départ préférée comprend, en poids, 15 % Cr, 13,6 % Co, 4,1 % Mo, 4,6 % Ti, 2,2 % Al, 0,01 % C, 0,007 % B, 0,07 % Zr, solde Ni. On forge cette matière à une température supérieure à la courbe limite de solubilité gamma de base et à un taux de déformation réelle d'au moins 0,5. Dans un autre mode de réalisation, on forge la matière à une température inférieure à la température de la courbe limite de solubilité gamma de base avec des recuits intermédiaires de super courbe limite de solubilité. On effectue ensuite le formage de la matière survieillie à une température inférieure à la courbe limite de solubilité gamma de base. On traite alors à chaud la matière à grain fin obtenue ou l'on peut aussi la forger de manière isothermique avant de la traiter à chaud pour produire des formes complexes.

公开(公告)号：EP2890871A1

公开(公告)日：2015-07-08

申请号：EP13832481.9

申请日：2013-06-04

Applicant: UNITED TECHNOLOGIES CORPORATION

Inventor： SHAH, Dilip, M. ,  CHIN, Herbert, A. ,  MARCIN, John, Joseph ,  REYNOLDS, Paul, L. ,  SUCIU, Gabriel, L. ,  GENEREUX, Paul, D.

IPC: F01D5/04 ,  F01D5/28 ,  C22C19/03

CPC classification number: C21D9/085 ,  B22D27/045 ,  C21D1/26 ,  C21D8/105 ,  C22C19/03 ,  C22C19/056 ,  C22C38/00 ,  C22F1/10 ,  C30B29/52 ,  C30B33/02 ,  F01D5/02 ,  F05D2220/323 ,  F05D2230/40 ,  F05D2240/60 ,  F05D2300/171 ,  F05D2300/501 ,  F05D2300/606 ,  Y02T50/672

Abstract: High modulus turbine shafts and high modulus cylindrical articles are described as are the process parameters for producing these shafts and cylindrical articles. The shafts/articles have a high Young's modulus as a result of having high modulus crystal texture along the longitudinal axis of the shaft/article. The shafts are produced from directionally solidified seeded single crystal cylinders that are axisymmetrically hot worked before a limited recrystallization process is carried out at a temperature below the recrystallization temperature of the alloy. The disclosed process produces an intense singular texture and results in shaft or cylindrical article with a Young's modulus that is at least 40% greater than that of conventional nickel or iron alloys or conventional steels.

Abstract translation: 高模量涡轮轴和高模量圆柱形制品描述了用于生产这些轴和圆柱形制品的工艺参数。 轴/制品由于沿轴/制品的纵向轴线具有高模量<111>晶体结构而具有高的杨氏模量。 这些轴由在低于合金的再结晶温度的温度下进行有限再结晶过程之前轴对称加热的定向固化的<111>单晶圆柱体制成。 所公开的方法产生强烈的单数<111>纹理，并导致具有比常规镍或铁合金或常规钢至少40％的杨氏模量的轴或圆柱形制品。

公开(公告)号：EP0533914B1

公开(公告)日：1997-03-12

申请号：EP92911977.4

申请日：1992-04-15

Applicant: UNITED TECHNOLOGIES CORPORATION

Inventor： ATHEY, Roy, L. ,  MILLER, John, A. ,  GOSTIC, William, J. ,  GENEREUX, Paul, D. ,  FUESTING, Timothy, P.

IPC: C22F1/10 ,  C22C19/05

CPC classification number: C22F1/10 ,  C22C19/056

Abstract: A process for producing a fine grain forged superalloy article having a high yield strength at intermediate temperatures. A preferred starting composition comprises, by weight, 15 % Cr, 13.6 % Co, 4.1 % Mo, 4.6 % Ti, 2.2 % Al, 0.01 % C, 0.007 % B, 0.07 % Zr, balance Ni. This material is forged at a temperature above the gamma prime solvus and at a true strain of at least 0.5. Alternately, the material may be forged below the gamma prime solvus temperature with intermediate super solvus anneals. The overaged material is then worked at a temperature below the gamma prime solvus. The resultant fine grain material is then heat treated or can be further isothermally forged prior to heat treatment to produce complex shapes.