HIGH PERFORMANCE BIFUNCTIONAL POROUS NON-NOBLE METAL PHOSPHIDE CATALYST FOR OVERALL WATER SPLITTING

    公开(公告)号:WO2020033018A3

    公开(公告)日:2020-02-13

    申请号:PCT/US2019/026814

    申请日:2019-04-10

    Abstract: A method of manufacturing a bifunctional electrocatalyst for overall water splitting comprising oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) by growing electrocatalyst comprising primarily metallic phosphides on a three-dimensional substrate by: immersing the substrate in an iron nitrate solution to form a once disposed substrate; subjecting the once disposed substrate to thermal phosphidation with phosphorus powder under inert gas to grow metal phosphides thereupon and form a once subjected substrate; cooling the once subjected substrate to form a cooled, once subjected substrate; immersing the cooled, once subjected substrate in an iron nitrate solution to form a twice disposed substrate; and subjecting the twice disposed substrate to thermal phosphidation with phosphorus powder under inert gas to provide an electrode comprising the bifunctional electrocatalyst on the three-dimensional substrate.

    THREE-DIMENSIONAL POROUS NISE2 FOAM-BASED HYBRID CATALYSTS FOR ULTRA-EFFICIENT HYDROGEN EVOLUTION REACTION IN WATER SPLITTING
    3.
    发明申请
    THREE-DIMENSIONAL POROUS NISE2 FOAM-BASED HYBRID CATALYSTS FOR ULTRA-EFFICIENT HYDROGEN EVOLUTION REACTION IN WATER SPLITTING 审中-公开
    三维多孔NISE2泡沫基混合催化剂在水分离过程中的超高效氢气演化反应

    公开(公告)号:WO2017201186A1

    公开(公告)日:2017-11-23

    申请号:PCT/US2017/033143

    申请日:2017-05-17

    Abstract: A hybrid three dimensional (3D) hydrogen evolution reaction (HER) catalyst that is formed from a porous Ni foam support, a NiSe 2 scaffold positioned on the support; and layered transition metal dichalcogenide (LTMDC) or first-row transition metal dichalcogenide particles positioned on the NiSe 2 scaffold. The catalyst provides a low onset potential, large cathode current density, small Tafel slopes, and large exchange current densities, similar in catalytic power to Pt HER catalysts.

    Abstract translation: 由多孔Ni泡沫载体,位于载体上的NiSe 2支架形成的混合三维(3D)析氢反应(HER)催化剂; 和位于NiSe 2骨架上的层状过渡金属二硫族化合物(LTMDC)或第一行过渡金属二硫属元素化物颗粒。 该催化剂具有低起始电位,大阴极电流密度,小Tafel斜率和大交换电流密度,与Pt HER催化剂的催化能力相似。

    HIGH PERFORMANCE BIFUNCTIONAL POROUS NON-NOBLE METAL PHOSPHIDE CATALYST FOR OVERALL WATER SPLITTING

    公开(公告)号:WO2020033018A2

    公开(公告)日:2020-02-13

    申请号:PCT/US2019/026814

    申请日:2019-04-10

    Abstract: A method of manufacturing a bifunctional electrocatalyst for overall water splitting comprising oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) by growing electrocatalyst comprising primarily metallic phosphides on a three-dimensional substrate by: immersing the substrate in an iron nitrate solution to form a once disposed substrate; subjecting the once disposed substrate to thermal phosphidation with phosphorus powder under inert gas to grow metal phosphides thereupon and form a once subjected substrate; cooling the once subjected substrate to form a cooled, once subjected substrate; immersing the cooled, once subjected substrate in an iron nitrate solution to form a twice disposed substrate; and subjecting the twice disposed substrate to thermal phosphidation with phosphorus powder under inert gas to provide an electrode comprising the bifunctional electrocatalyst on the three-dimensional substrate.

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