公开(公告)号：EP2262874A4

公开(公告)日：2011-09-28

申请号：EP09730248

申请日：2009-04-02

Applicant: UOP LLC

Inventor： MCCALL MICHAEL J ,  BRANDVOLD TIMOTHY A

IPC: C10G69/06 ,  C10G3/00 ,  C10G45/02 ,  C10L1/04

CPC classification number: C10G3/49 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/4081 ,  C10G2300/42 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  Y02P30/20

公开(公告)号：WO2012092046A2

公开(公告)日：2012-07-05

申请号：PCT/US2011066346

申请日：2011-12-21

Applicant: UOP LLC ,  BRANDVOLD TIMOTHY A ,  ELLIG DANIEL ,  LUPTON FRANCIS STEPHEN

Inventor： BRANDVOLD TIMOTHY A ,  ELLIG DANIEL ,  LUPTON FRANCIS STEPHEN

IPC: C10G25/02 ,  C07C7/12 ,  C10G67/06 ,  C10L1/02 ,  C11C1/08

CPC classification number: C11B3/04 ,  C10G2300/1011 ,  C10L1/026 ,  C11B3/008 ,  C11B3/06 ,  C11B3/10 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

Abstract: Methods are disclosed for the treatment of feedstocks comprising a fatty acid- or triglyceride-containing component to remove contaminants that are detrimental to the conversion of such feedstocks to hydrocarbons, and especially biofuel fractions such as diesel or aviation biofuels. Contaminants contributing to the presence of trace elements in animal fats and/or plant oils, as components of feedstocks, hinder the ability to catalytically convert these feedstocks, for example by hydroprocessing, to biofuels.

Abstract translation: 公开了用于处理包含含脂肪酸或甘油三酯组分的原料的方法，以除去对这些原料转化成烃，特别是生物燃料馏分如柴油或航空生物燃料有害的污染物。 导致作为原料成分的动物脂肪和/或植物油中微量元素的存在的污染物阻碍了将这些原料例如通过加氢处理催化转化为生物燃料的能力。

公开(公告)号：WO2011103054A2

公开(公告)日：2011-08-25

申请号：PCT/US2011024722

申请日：2011-02-14

Applicant: UOP LLC ,  MARINANGELI RICHARD ,  BRANDVOLD TIMOTHY A ,  KOCAL JOSEPH A

Inventor： MARINANGELI RICHARD ,  BRANDVOLD TIMOTHY A ,  KOCAL JOSEPH A

IPC: C10B53/02 ,  B01J23/38 ,  B01J29/04 ,  C10G3/00 ,  F25J1/00

CPC classification number: C10G3/44 ,  C10G3/45 ,  C10G3/47 ,  C10G3/48 ,  C10G3/49 ,  C10G2400/30 ,  Y02E50/14 ,  Y02P30/20

Abstract: Low oxygen biomass-derived pyrolysis oils and methods for producing them from carbonaceous biomass feedstock are provided. The carbonaceous biomass feedstock is pyrolyzed in the presence of a catalyst comprising base metal-based catalysts, noble metal- based catalysts, treated zeolitic catalysts, or combinations thereof to produce pyrolysis gases. During pyrolysis, the catalyst catalyzes a deoxygenation reaction whereby at least a portion of the oxygenated hydrocarbons in the pyrolysis gases are converted into hydrocarbons. The oxygen is removed as carbon oxides and water. A condensable portion (the vapors) of the pyrolysis gases is condensed to low oxygen biomass-derived pyrolysis oil.

Abstract translation: 提供了低氧生物质衍生的热解油及其从碳质生物质原料生产它们的方法。 碳质生物质原料在催化剂存在下热解，该催化剂包含基于贱金属的催化剂，贵金属基催化剂，经处理的沸石催化剂或其组合以产生热解气体。 在热解期间，催化剂催化脱氧反应，由此将热解气体中的至少一部分氧化烃转化成烃。 作为碳氧化物和水除去氧气。 热解气体的可冷凝部分（蒸汽）被冷凝成低氧生物质衍生的裂解油。

公开(公告)号：WO2009151690A2

公开(公告)日：2009-12-17

申请号：PCT/US2009037066

申请日：2009-03-13

Applicant: UOP LLC ,  MCCALL MICHAEL J ,  KOCAL JOSEPH A ,  BHATTACHARYYA ALAKANANDA ,  KALNES TOM N ,  BRANDVOLD TIMOTHY A

Inventor： MCCALL MICHAEL J ,  KOCAL JOSEPH A ,  BHATTACHARYYA ALAKANANDA ,  KALNES TOM N ,  BRANDVOLD TIMOTHY A

IPC: C10G67/02 ,  C07C2/08 ,  C10G45/04

CPC classification number: C10G3/47 ,  C10G3/46 ,  C10G3/49 ,  C10G3/52 ,  C10G45/02 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2300/80 ,  C10G2400/08 ,  Y02P30/20

Abstract: A hydrocarbon product stream having hydrocarbons with boiling points in the aviation fuel range is produced from renewable feedstocks such as plant and animal oils. The process involves treating a renewable feedstock by hydrogenating, deoxygenating, isomerization, and selectively hydrocracking the feedstock to produce paraffinic hydrocarbons having from 9 to 16 carbon atoms and a high iso/normal ratio in a single reaction zone containing a multifunctional catalyst, or set of catalysts, having hydrogenation, deoxygenation, isomerization and selective hydrocracking functions.

Abstract translation: 在航空燃料范围内具有沸点的烃的烃产物流由可再生原料如植物油和动物油生产。 该方法包括通过氢化，脱氧，异构化和选择性加氢裂化原料来处理可再生原料，以在含有多官能催化剂的单个反应区中产生具有9至16个碳原子和高异/正常比例的链烷烃，或一组 催化剂，具有氢化，脱氧，异构化和选择性加氢裂化功能。

公开(公告)号：WO2007073532A2

公开(公告)日：2007-06-28

申请号：PCT/US2006061830

申请日：2006-12-11

Applicant: UOP LLC ,  BRANDVOLD TIMOTHY A ,  KOCAL JOSEPH A

Inventor： BRANDVOLD TIMOTHY A ,  KOCAL JOSEPH A

CPC classification number: C07C29/48 ,  C07C29/095 ,  C07C29/80 ,  C07C67/035 ,  C07C69/63 ,  C07C31/04

Abstract: A process for the production of methanol from methane has been developed. The process involves reacting methane with an oxidant such as oxygen or a peroxide in the presence of a catalyst and a solvent in a reaction zone to produce an effluent stream comprising a methanol product. The effluent stream is next separated into a gaseous stream comprising unreacted methane and carbon dioxide and a liquid stream comprising the methanol product and solvent. Next the gaseous stream is further separated to provide a methane stream which is recycled to the reaction zone. Finally, a methanol stream is isolated and a solvent stream is recycled to the reaction zone.

Abstract translation: 已经开发了从甲烷生产甲醇的方法。 该方法包括使甲烷与氧化剂如氧气或过氧化物在催化剂和溶剂存在下在反应区中反应以产生包含甲醇产物的流出物流。 接着将流出物流分离成包含未反应的甲烷和二氧化碳的气态物流和包含甲醇产物和溶剂的液态物流。 接下来，将气体流进一步分离以提供循环到反应区的甲烷流。 最后，分离甲醇流并将溶剂流循环至反应区。

公开(公告)号：WO2012018524A3

公开(公告)日：2012-05-24

申请号：PCT/US2011044594

申请日：2011-07-20

Applicant: UOP LLC ,  TRAYNOR THOMAS ,  BRANDVOLD TIMOTHY A

Inventor： TRAYNOR THOMAS ,  BRANDVOLD TIMOTHY A

IPC: C10G45/04 ,  C10G3/00 ,  C10G65/04 ,  C10G69/02 ,  C10L1/02

CPC classification number: C10L1/02 ,  Y02P30/20

Abstract: Methods for producing low oxygen biomass-derived pyrolysis oil are provided. Starting biomass-derived pyrolysis oil is deoxygenated by exposing the biomass-derived oil to a first catalyst in the presence of hydrogen-containing gas at first hydroprocessing conditions to produce a partially deoxygenated biomass-derived pyrolysis oil. The first catalyst has a neutral catalyst support. The partially deoxygenated biomass-derived pyrolysis oil is exposed to a second catalyst in the presence of additional hydrogen-containing gas at second hydroprocessing conditions to produce a hydrocarbon product. The biomass-derived pyrolysis oil may be esterified prior to deoxygenation. A portion of the low oxygen biomass-derived pyrolysis oil is recycled.

Abstract translation: 提供了生产低氧生物质衍生的热解油的方法。 通过在第一加氢处理条件下在含氢气体存在下将生物质衍生的油暴露于第一催化剂以使生物质衍生的热解油脱氧以产生部分脱氧的生物质衍生的热解油。 第一种催化剂具有中性催化剂载体。 部分脱氧的生物质衍生的热解油在第二加氢处理条件下在另外的含氢气体的存在下暴露于第二催化剂以产生烃产物。 生物质衍生的热解油可以在脱氧之前被酯化。 低氧生物质衍生的热解油的一部分被再循环。

公开(公告)号：WO2012015635A2

公开(公告)日：2012-02-02

申请号：PCT/US2011044595

申请日：2011-07-20

Applicant: UOP LLC ,  KOCH MARK B ,  BRANDVOLD TIMOTHY A

Inventor： KOCH MARK B ,  BRANDVOLD TIMOTHY A

IPC: C10G19/00 ,  C10G3/00 ,  C10G19/073 ,  C10G33/00 ,  C10L1/02

CPC classification number: C10L1/02 ,  C10L1/04 ,  Y02P30/20

Abstract: Methods for producing phase stable, reduced acid biomass-derived pyrolysis oils are provided. Biomass-derived pyrolysis oil having a determined water content no greater than 30% by weight is provided. A base is mixed with the biomass-derived pyrolysis oil to produce reduced acid biomass-derived pyrolysis oil. A base is selected from an inorganic base or a nitrogen-containing base.

Abstract translation: 提供了用于生产相稳定的，减少的酸生物质衍生的热解油的方法。 提供具有不大于30重量％的确定水含量的生物质衍生的热解油。 将碱与生物质衍生的热解油混合以生产减少的酸生物质衍生的热解油。 碱选自无机碱或含氮碱。

公开(公告)号：WO2011087668A3

公开(公告)日：2011-10-27

申请号：PCT/US2010060276

申请日：2010-12-14

Applicant: UOP LLC ,  BRANDVOLD TIMOTHY A ,  FREY STANLEY J ,  ABRAHAMIAN VASKEN B ,  TRAYNOR THOMAS J

Inventor： BRANDVOLD TIMOTHY A ,  FREY STANLEY J ,  ABRAHAMIAN VASKEN B ,  TRAYNOR THOMAS J

IPC: B01J49/00 ,  C10G25/02

CPC classification number: B01J49/0069 ,  B01D15/20 ,  B01D15/203 ,  B01D15/362 ,  B01J49/06 ,  B01J49/53 ,  C10G2300/1011 ,  C10L1/02 ,  G01N30/50 ,  G01N30/96 ,  Y02P30/20

Abstract: Methods for regenerating acidic ion-exchange resins and reusing regenerants in such methods are provided. A spent ion-exchange resin is contacted with an alcohol ion-exchange regenerant. The spent ion-exchange resin is thereafter contacted with an acidic ion-exchange regenerant to recharge the acidic ion-exchange resin to produce a regenerated acidic ion-exchange resin. Metal- and water-containing biomass-derived pyrolysis oil is then contacted with the regenerated acidic ion-exchange resin to produce low metal, water-containing biomass-derived pyrolysis oil. The regenerated acidic ion-exchange resin may be recycled. The spent alcohol and acid ion-exchange regenerants may be recovered and recycled.

Abstract translation: 提供了在这种方法中再生酸性离子交换树脂和再利用再生剂的方法。 将废弃的离子交换树脂与醇离子交换再生剂接触。 然后将废弃的离子交换树脂与酸性离子交换再生剂接触以对酸性离子交换树脂再充电以产生再生的酸性离子交换树脂。 然后将含金属和含水的生物质衍生的热解油与再生的酸性离子交换树脂接触以产生低金属，含水生物质的热解油。 再生的酸性离子交换树脂可以再循环。 废乙醇和酸离子交换再生剂可以回收和再循环。

公开(公告)号：WO2010074923A3

公开(公告)日：2010-09-10

申请号：PCT/US2009066700

申请日：2009-12-04

Applicant: UOP LLC ,  BRANDVOLD TIMOTHY A ,  MCCALL MICHAEL J

Inventor： BRANDVOLD TIMOTHY A ,  MCCALL MICHAEL J

IPC: C10G3/00 ,  C10L1/04

CPC classification number: C10L1/08 ,  C10G3/46 ,  C10G3/50 ,  C10G45/58 ,  C10G47/00 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1022 ,  C10G2300/1037 ,  C10G2300/4081 ,  C10G2300/80 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/28 ,  C10L1/06 ,  Y02E50/13 ,  Y02P30/20 ,  Y02T50/678

Abstract: A process for producing a fuel or fuel blending component from co-processing at least two different classes of renewable feedstocks, is presented. One feedstock comprises glycerides and free fatty acids in feedstocks such as plant and animal oils while the other feedstock comprises biomass derived pyrolysis oil. The source of the animal or plant oil and the biomass may be the same renewable source.

Abstract translation: 介绍了一种通过协同处理至少两种不同种类的可再生原料来生产燃料或燃料调合组分的方法。 一种原料在原料如植物油和动物油中包含甘油酯和游离脂肪酸，而另一种原料包含生物质衍生的热解油。 动物或植物油的来源和生物质可以是相同的可再生资源。

公开(公告)号：WO2012166402A2

公开(公告)日：2012-12-06

申请号：PCT/US2012038747

申请日：2012-05-21

Applicant: UOP LLC ,  TRAYNOR THOMAS ,  BRANDVOLD TIMOTHY A ,  ABRAHAMIAN JENNIFER F

Inventor： TRAYNOR THOMAS ,  BRANDVOLD TIMOTHY A ,  ABRAHAMIAN JENNIFER F

IPC: C10G45/08 ,  B01J23/28 ,  B01J23/74 ,  C10G3/00 ,  C10G65/00

CPC classification number: B01J23/883 ,  C10G3/46 ,  C10G65/04 ,  C10G2300/1011 ,  Y02P30/20

Abstract: Embodiments of methods and catalysts for deoxygenating a biomass-derived pyrolysis oil are provided. The method comprises the step of contacting the biomass-derived pyrolysis oil with a first deoxygenating catalyst in the presence of hydrogen at first predetermined hydroprocessing conditions to form a first low-oxygen biomass-derived pyrolysis oil effluent. The first deoxygenating catalyst comprises a neutral catalyst support, nickel, cobalt, and molybdenum. The first deoxygenating catalyst comprises nickel in an amount calculated as an oxide of from 0.1 to 1.5 wt. %.

Abstract translation: 提供了用于脱氧生物质衍生的热解油的方法和催化剂的实施方案。 该方法包括在第一预定加氢处理条件下，在氢存在下使生物质衍生的热解油与第一脱氧催化剂接触的步骤，以形成第一低氧生物质衍生的热解油流出物。 第一脱氧催化剂包括中性催化剂载体，镍，钴和钼。 第一脱氧催化剂包含以0.1至1.5重量％的氧化物计算的量的镍。 ％。