PROCESS FOR PREPARING BRANCHED ORGANOPOLYSILOXANES

    公开(公告)号:US20210171716A1

    公开(公告)日:2021-06-10

    申请号:US17268709

    申请日:2018-08-24

    Inventor: Marko PRASSE

    Abstract: Branched organopolysiloxanes are prepared from alkoxysilanes and polydiorganosiloxanes over two stages by basic equilibration and subsequent acid-catalyzed reaction with water to the desired degree of condensation, wherein the entire process does not require the use of additional organic solvent, no wastewater is generated and the process is particularly suitable for the controlled production of so-called DT resins.

    CURABLE ORGANOPOLYSILOXANE COMPOSITIONS
    4.
    发明申请

    公开(公告)号:US20200325337A1

    公开(公告)日:2020-10-15

    申请号:US16646845

    申请日:2017-09-15

    Abstract: Addition curable composition containing specific silicone resins containing aliphatically unsaturated groups and an. organic compound containing unsaturated groups such as acrylate or methacrylate groups are suitable when used with fine and coarse fillers to produce artificial stone with both high hardness and high flexural strength.

    METHOD FOR PRODUCING ORGANOPOLYSILOXANES

    公开(公告)号:US20170349709A1

    公开(公告)日:2017-12-07

    申请号:US15535453

    申请日:2016-07-21

    CPC classification number: C08G77/06 C08G77/18

    Abstract: Highly condensed silicon resins are obtained by a three step continuous procedure without the use of organic solvent, by preliminarily forming a partial alkoxylate by reacting a chlorosilane with alcohol containing no or a minimal amount of water, feeding the partial alkoxylate to a reaction column to form a silicone resin of low degree of condensation, and further condensing the silicone resin intermediate thus formed to produce a silicone resin product.

    PROCESS FOR PREPARING BRANCHED ORGANOPOLYSILOXANES

    公开(公告)号:US20250019498A1

    公开(公告)日:2025-01-16

    申请号:US18715775

    申请日:2021-12-03

    Inventor: Marko PRASSE

    Abstract: A process for preparing branched organopolysiloxanes includes organopolysiloxanes O that have a glass transition temperature (Tg) of 5° C. to 100° C. and contain units of the general formula (I), RaSi(OR1)bO(4-a-b)/2 (I). Silanes of the general formula (II), RnSi(OR1)4-n (II), are reacted with water, catalytic amounts of an acidic catalyst K, and optionally alcohol A. No other solvent apart from alcohol A is used throughout the entire process. Alcohol A is selected from methanol, ethanol or a mixture of methanol and ethanol. The organopolysiloxanes O have average molecular weights Mw in the range of 500 to 20,000 g/mol (weight average) with a polydispersity (PD) of at most 20.

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