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公开(公告)号:JP2002194185A
公开(公告)日:2002-07-10
申请号:JP2000390099
申请日:2000-12-22
Applicant: TORAY INDUSTRIES
Inventor: TAKAHASHI KOZO , MATSUI RYOSUKE , YOSHIDA MINORU
Abstract: PROBLEM TO BE SOLVED: To provide a polyester film for a molding process which exhibits a stable performance for a long time even in a severe environment for use such as in an oxygen atmosphere or a water atmosphere. SOLUTION: This film for a molding process is composed of a polyester of which the main constituent is an ethylene terephtalate unit and/or an ethylene naphthalate unit. The film has a melting point in the range of 180-270 deg.C and contains α-tocopherol in the range of 0.01-2 wt.%.
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公开(公告)号:JP2002120280A
公开(公告)日:2002-04-23
申请号:JP2000315155
申请日:2000-10-16
Applicant: TORAY INDUSTRIES
Inventor: HASHIMOTO KOKICHI , TAKAHASHI KOZO , YOSHIDA MINORU
Abstract: PROBLEM TO BE SOLVED: To provide a biaxially stretched polyester film for molding showing excellent environmental resistance, transparency, printability, moldability and beautifulness. SOLUTION: A biaxially stretched polyester film for molding has an ethyleneterephthalate unit and/or an ethylenenaphthalate unit as a major component wherein the polyester film shows a melting point of not lower than 245 deg.C and has a face orientation coefficient (fn), a heat shrinkage SrMD(%)} in the lengthwise direction at 190 deg.C and a heat shrinkage SrTD(%)} in the widthwise direction at 190 deg.C each within a specific range.
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公开(公告)号:JP2002113835A
公开(公告)日:2002-04-16
申请号:JP2000310697
申请日:2000-10-11
Applicant: TORAY INDUSTRIES
Inventor: KIMURA MASAHIRO , YAMANE NOBUHISA , YOSHIDA MINORU
Abstract: PROBLEM TO BE SOLVED: To provide a polyester film which is excellent in flexibility, molding processability, and appearance and can be used appropriately in an application in which the film is laminated on a layer of a metal or a nonmetallic material (paper, a nonwoven fabric, a polymer material, etc.), for molding. SOLUTION: In the laminated polyester film, a polyester layer A and a polyester layer B which meet formulas (1) and (2) XA>XB>=0 (1) and 3
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公开(公告)号:JP2002103443A
公开(公告)日:2002-04-09
申请号:JP2000303203
申请日:2000-10-03
Applicant: TORAY INDUSTRIES
Inventor: TAKAHASHI KOZO , HASHIMOTO KOKICHI , YOSHIDA MINORU
Abstract: PROBLEM TO BE SOLVED: To provide a biaxially oriented polyester film for molding which has elongation and flexibility and is excellent in heat resistance, vapor deposition properties, and surface processing properties such as printability. SOLUTION: The polyester film is formed from a polyester containing ethylene terephthalate units and/or ethylene naphthalate units as main components, the melting point of the film is 245-265 deg.C, the surface orientation coefficient is 0.11-0.15, and the surface haze is 0-1.5%.
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公开(公告)号:JP2002097261A
公开(公告)日:2002-04-02
申请号:JP2001213545
申请日:2001-07-13
Applicant: TORAY INDUSTRIES
Inventor: KIMURA MASAHIRO , NIINUMADATE HIROSHI , YOSHIDA MINORU
Abstract: PROBLEM TO BE SOLVED: To provide a polyester film very suitable as a molded, processed and printed product, or a processing film in molding, processing and printing. SOLUTION: The polyester film has, as a constituent component, a polyester A containing at least two or more of glycol components selected from ethylene glycol, butanediol and propanediol, and satisfies the formula: M/P
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公开(公告)号:JP2001106747A
公开(公告)日:2001-04-17
申请号:JP2000230656
申请日:2000-07-31
Applicant: TORAY INDUSTRIES
Inventor: CHIBA TOMONORI , KAGEISHI KAZUJI , YOSHIDA MINORU
IPC: G03F7/038 , C08F2/44 , C08F2/46 , C08F290/04 , G03F7/26
Abstract: PROBLEM TO BE SOLVED: To obtain a light sensitive resin composition excellent in photocurable properties, and exhibiting homogeneous curability in the running direction of the light, and further to provide a method for producing the composition. SOLUTION: This light sensitive resin composition is obtained by reacting the carboxy group in an acrylic resin having a high light transmission, with an epoxy-containing acrylic unsaturated material, and having acrylic unsaturated bond. The light sensitive resin composition comprises the acrylic resin having the acrylic unsaturated double bond in the side chain, 5,000-200,000 weight average molecular weight, 3,000-50,000 number average molecular weight, 1.2-5.0 Mw/Mn and
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公开(公告)号:JPH06228418A
公开(公告)日:1994-08-16
申请号:JP1564993
申请日:1993-02-02
Applicant: TORAY INDUSTRIES
Inventor: YOSHIDA MINORU , SAKAMOTO JUN , SASAKI TOSHIHIRO
Abstract: PURPOSE:To obtain a composition providing a film having a surface hardly injured, showing excellent scratching resistance and wear resistance by blending an aromatic polyester with a fluorine compound and inert particles having specific particle diameters, respectively. CONSTITUTION:The composition comprises (A) 0.01-2 pts.wt. of fluorine compound (preferably calcium fluoride) having 0.002-0.2mum average diameter of primary particles, (B) 0.01-5 pts.wt. of inert particles having 0.2-1mum average diameter of primary particles and (C) 99.98-93 pts.wt. of an aromatic polyester (preferably polyethylene terephthalate). The component B is preferably titanium oxide in the case of inorganic particles and preferably a divinylbenzene homopolymer in the case of organic particles. The component A and the inert inorganic particles are added to the polyester reaction system by a method of supplying them in a state of a glycol slurry and the inert organic particles are incorporated with the polyester in a shape of a slurry using water, etc.
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公开(公告)号:JPH06157877A
公开(公告)日:1994-06-07
申请号:JP30842392
申请日:1992-11-18
Applicant: TORAY INDUSTRIES
Inventor: SAKAMOTO JUN , YOSHIDA MINORU , SUZUKI MASARU
Abstract: PURPOSE:To obtain a resin composition useful for obtaining a film excellent in scratch and abrasion resistances by mixing a thermoplastic polyester with a specified calcium carbonate and phosphorus and specifying the terminal carboxyl concentration. CONSTITUTION:This resin composition is prepared by mixing a thermoplastic polyester (e.g. polyethylene terephthalate) with 0.05-10wt.% vateritic calcium carbonate surfacetreated with a polycarboxylic acid compound (e.g. sodium polyacrylate) and having a mean particle diameter of 0.01-5mum and 40-250ppm of phosphorus (for example, one added in the form of trimethyl phosphate) and has a terminal carboxyl concentration in the range of 10-100 equivalents per 10 g of the polymer.
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公开(公告)号:JPH05171014A
公开(公告)日:1993-07-09
申请号:JP34382091
申请日:1991-12-26
Applicant: TORAY INDUSTRIES
Inventor: AOYAMA MASATOSHI , YOSHIDA MINORU , SUZUKI MASARU
Abstract: PURPOSE:To prepare a polyester compsn. which does not clog a polymer filter in the molding step and is useful for preparing a film or fiber excellent in abrasion resistance by compounding a specific arom. polyester with a particulate zirconium oxide. CONSTITUTION:An arom. polyester obtd. by copolymerizing at least one compd. having a sulfonic acid (or metal sulfonate) group with other necessary comonomers (e.g. one obtd. from dimethyl 5-sodiumsulfoisophthalate, dimethyl terephthalate, and ethylene glycol) is compounded with a particulate zirconium oxide pref. having a mean particle diameter of 0.005-3mum, still pref. 0.005-0.2mum.
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公开(公告)号:JPH05163371A
公开(公告)日:1993-06-29
申请号:JP33017291
申请日:1991-12-13
Applicant: TORAY INDUSTRIES
Inventor: SAKAMOTO JUN , YOSHIDA MINORU , SUZUKI MASARU
Abstract: PURPOSE:To provide the title film excellent in the resistance to scratch and abrasion. CONSTITUTION:The title film contains zirconium oxide particles. In the film, the particles are dispersed in the form of aggregates having a ratio of the length parallel to the direction of film length to the length vertical to the film surface of 0.5-0.6.
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