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公开(公告)号:US11476022B2
公开(公告)日:2022-10-18
申请号:US17000610
申请日:2020-08-24
Applicant: ROGERS CORPORATION
Inventor: Li Zhang , Yajie Chen
Abstract: In an aspect, a composition comprises a plurality of magnetic particles. The magnetic particles each independently comprise a nickel ferrite core having the formula Ni1−xMxPe2+yO4, wherein M is at least one of Zn, Mg, Co, Cu, Al, Mn, or Cr; x is 0 to 0.95, and y=−0.5 to 0.5; and an iron nickel shell at least partially surrounding the core, wherein the iron nickel shell comprises iron, nickel, and optionally M. In another aspect, a method of forming the magnetic particles comprises heat treating a plurality of nickel ferrite particles in a hydrogen atmosphere to form the plurality of magnetic particles having the iron nickel shell on the nickel ferrite core. In yet another aspect, a composite can comprise the magnetic particles and a polymer.
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公开(公告)号:US20210065943A1
公开(公告)日:2021-03-04
申请号:US17000610
申请日:2020-08-24
Applicant: ROGERS CORPORATION
Inventor: Li Zhang , Yajie Chen
Abstract: In an aspect, a composition comprises a plurality of magnetic particles. The magnetic particles each independently comprise a nickel ferrite core having the formula Ni1−xMxPe2+yO4, wherein M is at least one of Zn, Mg, Co, Cu, Al, Mn, or Cr; x is 0 to 0.95, and y=−0.5 to 0.5; and an iron nickel shell at least partially surrounding the core, wherein the iron nickel shell comprises iron, nickel, and optionally M. In another aspect, a method of forming the magnetic particles comprises heat treating a plurality of nickel ferrite particles in a hydrogen atmosphere to form the plurality of magnetic particles having the iron nickel shell on the nickel ferrite core. In yet another aspect, a composite can comprise the magnetic particles and a polymer.
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公开(公告)号:US20200161034A1
公开(公告)日:2020-05-21
申请号:US16676736
申请日:2019-11-07
Applicant: ROGERS CORPORATION
Inventor: Yajie Chen , Xiaoyu Zhang , Li Zhang , Yuanyuan Xing
Abstract: A multilayer film includes a substrate; a first magnetic layer disposed on the substrate and a second magnetic layer disposed on the first magnetic layer. The first magnetic layer includes Fe(50-80)N(10-20)B(1-20)M(0-10), wherein M is Si, Ta, Zr, Ti, Co, or a combination thereof. The second magnetic layer includes Fe(50-90)N(10-50) or Fe(60-90)N(1-10)Ta(5-30). The multilayer magnetic film has, over a frequency range of 50 MHz to 10 GHz, a magnetic permeability of greater than or equal to 1800 over a selected frequency band in the frequency range; a magnetic loss tangent of less than or equal to 0.3 over a selected frequency band in the frequency range; and a cutoff frequency of greater than or equal to 1 GHz, or greater than or equal to 2 GHz.
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4.
公开(公告)号:US11783975B2
公开(公告)日:2023-10-10
申请号:US17069371
申请日:2020-10-13
Applicant: ROGERS CORPORATION
Inventor: Li Zhang , Yajie Chen
CPC classification number: H01F1/344 , C01G49/009 , C08K3/22 , C08K7/18 , H01F41/0246 , C01P2002/32 , C01P2002/52 , C01P2002/60 , C01P2002/72 , C01P2004/24 , C01P2004/32 , C01P2004/61 , C01P2004/62 , C01P2006/42 , C08K2003/2296 , C08K2201/004 , C08K2201/005 , C08K2201/01 , C08K2201/011
Abstract: Described herein is a nanocrystalline ferrite having the formula Ni1−x−yMyCoxFe2+zO4, wherein M is at least one of Zn, Mg, Cu, or Mn, x is 0.01 to 0.8, y is 0.01 to 0.8, and z is −0.5 to 0.5, and wherein the nanocrystalline ferrite has an average grain size of 5 to 100 nm. A method of forming the nanocrystalline ferrite can comprise high energy ball milling.
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公开(公告)号:US20210261433A1
公开(公告)日:2021-08-26
申请号:US17166352
申请日:2021-02-03
Applicant: ROGERS CORPORATION
Inventor: Yajie Chen , Li Zhang , Shawn Williams
Abstract: In an aspect, a Co2Z ferrite has the formula: (Ba1−xSrx)3Co2+yMyFe24−2y−zO41. M is at least one of Mo, Ir, or Ru. The variable x can be 0 to 0.8, or 0.1 to 0.8. The variable y can be 0 to 0.8, or 0.01 to 0.8. The variable z can be −2 to 2. The Co2Z ferrite can have an average grain size of 5 to 100 nanometers, or 30 to 80, or 10 to 40 nanometers as measured using at least one of transmission electron microscopy, field emission scanning electron microscopy, or x-ray diffraction.
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公开(公告)号:US11574752B2
公开(公告)日:2023-02-07
申请号:US16930907
申请日:2020-07-16
Applicant: ROGERS CORPORATION
Inventor: Yajie Chen , Robert C. Daigle , Li Zhang
Abstract: A magnetic fiber comprises a core comprising a spinel ferrite of formula Me1-xMxFeyO4, wherein Me is Mg, Mn, Fe, Co, Ni, Cu, Zn, or a combination thereof, x=0 to 0.25, and y=1.5 to 2.5, wherein the core is solid or at least partially hollow; and a shell at least partially surrounding the core, and comprising a Me1-xMxFey alloy, wherein when the core is solid with Me=Ni and x=0 the magnetic fiber has a diameter of greater than 0.3 micrometer. A magneto-dielectric material having a magnetic loss tangent of less than or equal to 0.03 at 1 GHz comprises a polymer matrix; and a plurality of the magnetic fibers.
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公开(公告)号:US11508503B2
公开(公告)日:2022-11-22
申请号:US16378676
申请日:2019-04-09
Applicant: ROGERS CORPORATION
Inventor: Yajie Chen , Kevin Ring , Li Zhang , Michael S. White
Abstract: A grain-oriented M-type hexagonal ferrite has the formula MeFe12O19, and a dopant effective to provide planar magnetic anisotropy and magnetization in a c-plane, or a cone anisotropy, in the hexagonal crystallographic structure wherein Me is Sr+, Ba2+ or Pb2+, and wherein greater than 30%, preferably greater than 80%, of c-axes of the ferrite grains are aligned perpendicular to the c-plane.
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8.
公开(公告)号:US20210225566A1
公开(公告)日:2021-07-22
申请号:US17069371
申请日:2020-10-13
Applicant: ROGERS CORPORATION
Inventor: Li Zhang , Yajie Chen
Abstract: Described herein is a nanocrystalline ferrite having the formula Ni1-x-y MyCoxFe2+zO4, wherein M is at least one of Zn, Mg, Cu, or Mn, x is 0.01 to 0.8, y is 0.01 to 0.8, and z is −0.5 to 0.5, and wherein the nanocrystalline ferrite has an average grain size of 5 to 100 nm. A method of forming the nanocrystalline ferrite can comprise high energy ball milling.
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公开(公告)号:US11691892B2
公开(公告)日:2023-07-04
申请号:US17166352
申请日:2021-02-03
Applicant: ROGERS CORPORATION
Inventor: Yajie Chen , Li Zhang , Shawn Williams
CPC classification number: C01G51/66 , C08K3/22 , H01F1/348 , C01P2004/04 , C01P2004/64 , C08K2003/2265 , C08K2201/001 , C08K2201/005 , C08K2201/01 , C08K2201/011
Abstract: In an aspect, a Co2Z ferrite has the formula: (Ba1-xSrx)3Co2+yMyFe24-2y-zO41. M is at least one of Mo, Ir, or Ru. The variable x can be 0 to 0.8, or 0.1 to 0.8. The variable y can be 0 to 0.8, or 0.01 to 0.8. The variable z can be −2 to 2. The Co2Z ferrite can have an average grain size of 5 to 100 nanometers, or 30 to 80, or 10 to 40 nanometers as measured using at least one of transmission electron microscopy, field emission scanning electron microscopy, or x-ray diffraction.
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公开(公告)号:US11682509B2
公开(公告)日:2023-06-20
申请号:US16676736
申请日:2019-11-07
Applicant: ROGERS CORPORATION
Inventor: Yajie Chen , Xiaoyu Zhang , Li Zhang , Yuanyuan Xing
CPC classification number: H01F1/16 , H01F1/38 , H01F41/18 , H01F41/32 , Y10T428/32
Abstract: A multilayer film includes a substrate; a first magnetic layer disposed on the substrate and a second magnetic layer disposed on the first magnetic layer. The first magnetic layer includes Fe(50-80)N(10-20)B(1-20)M(0-10), wherein M is Si, Ta, Zr, Ti, Co, or a combination thereof. The second magnetic layer includes Fe(50-90)N(10-50) or Fe(60-90)N(1-10)Ta(5-30). The multilayer magnetic film has, over a frequency range of 50 MHz to 10 GHz, a magnetic permeability of greater than or equal to 1800 over a selected frequency band in the frequency range; a magnetic loss tangent of less than or equal to 0.3 over a selected frequency band in the frequency range; and a cutoff frequency of greater than or equal to 1 GHz, or greater than or equal to 2 GHz.
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