公开(公告)号：US20060011510A1

公开(公告)日：2006-01-19

申请号：US11153558

申请日：2005-06-14

Applicant: Hiroshi Toshima ,  Satoshi Abe

Inventor： Hiroshi Toshima ,  Satoshi Abe

IPC: C10G65/12

CPC classification number: B01J35/10 ,  B01J21/12 ,  B01J23/85 ,  B01J23/883 ,  B01J35/0006 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  B01J35/1085 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0203 ,  B01J37/036 ,  C10G65/12 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206 ,  C10G2300/301

Abstract: A method is disclosed for hydroprocessing a heavy hydrocarbon oil, comprising a first hydroprocessing step of bringing a heavy hydrocarbon oil into contact with a Catalyst (1) with a certain specific surface area and pore size distribution in the presence of hydrogen in a first reaction zone containing the Catalyst (1), and a second hydroprocessing step of bringing the hydroprocessed oil obtained from the first reaction zone into contact with a Catalyst (2) with a certain specific surface area and pore size distribution in the presence of hydrogen in a second reaction zone containing the Catalyst (2). The method is an improvement in decreasing or inhibiting the sediment formation, while highly hydroprocessing a heavy hydrocarbon oil containing a large amount of impurities such as sulfur, micro carbon residue (MCR), metals, nitrogen and asphaltene, especially a heavy oil containing a large amount of heavy vacuum residue, to adequately remove the impurities.

公开(公告)号：US20050049405A1

公开(公告)日：2005-03-03

申请号：US10790060

申请日：2004-03-02

Applicant: Yoshihito Watanabe ,  Takafumi Ueno ,  Satoshi Abe

Inventor： Yoshihito Watanabe ,  Takafumi Ueno ,  Satoshi Abe

IPC: C07C35/02 ,  C07B61/00 ,  C07C51/36 ,  C07C53/122 ,  C07C231/12 ,  C07C233/05 ,  C07K14/00 ,  C07K14/795 ,  C07K14/805

CPC classification number: B01J31/003 ,  C07K14/805

Abstract: The metal complex-protein composite of the present invention includes a protein having a cavity and a metal complex and has a specific structure that the metal complex is received in the cavity of the protein. Here the metal complex is prepared by complexation of a metal ion, which is selected among the group consisting of rhodium, ruthenium, and palladium, with a ligand. The metal complex-protein composite of the invention functions as a hydrogenation catalyst of an olefin in water. The metal complex-protein composite is thus effectively applied to hydrogenation of water-soluble substrates and has environmental advantages over organic solvents.

Abstract translation: 本发明的金属络合物 - 蛋​​白质复合物包括具有空腔和金属络合物的蛋白质，并且具有金属络合物容纳在蛋白质的空腔中的特定结构。 这里，金属络合物是通过将选自铑，钌和钯的金属离子与配体络合而制备的。 本发明的金属络合蛋白复合物作为烯烃在水中的氢化催化剂起作用。 因此，金属络合物 - 蛋​​白质复合物有效地用于水溶性底物的氢化，并且具有优于有机溶剂的环境优点。