公开(公告)号：US06319973B1

公开(公告)日：2001-11-20

申请号：US09358810

申请日：1999-07-22

Applicant: Markus Lemm ,  Kai Lemke ,  Dieter Grafl

Inventor： Markus Lemm ,  Kai Lemke ,  Dieter Grafl

IPC: C08J310

CPC classification number: C09D201/00

Abstract: Solvent-free applicable curable coating material containing as binder inorganic polymers and/or organic polymers, cross-linkers and sliding aids.

Abstract translation: 含有无机聚合物和/或有机聚合物，交联剂和滑动助剂的无溶剂的可固化涂料。

公开(公告)号：US6147142A

公开(公告)日：2000-11-14

申请号：US155370

申请日：1998-09-28

Applicant: Michael Geck ,  Walter Goeblmeier ,  Bernward Deubzer ,  Ekkehard Patrick ,  Helmut Oswaldbauer

Inventor： Michael Geck ,  Walter Goeblmeier ,  Bernward Deubzer ,  Ekkehard Patrick ,  Helmut Oswaldbauer

IPC: C08F283/12 ,  C09D7/12 ,  C09D151/08 ,  C09D201/00 ,  C08L83/04 ,  C08F8/00 ,  C08G77/04 ,  C08G77/38

CPC classification number: C09D151/085 ,  C08F283/12 ,  C09D201/00 ,  C09D7/125 ,  C09D7/1266 ,  C09D7/1275 ,  C08L2207/53 ,  Y10S525/902

Abstract: Previously cross-linked silicone elastomer particles with an organic-polymer shell are used as constituents for formulating aqueous coating compositions based on water-soluble or water-dilutable binders. The silicone elastomer particles contain: (a) 5 to 95% by weight, with respect to the total weight of the copolymer, of a nuclear polymer of general formula (R.sub.2 SiO.sub.2/2).sub.x (RSiO.sub.3/2).sub.y (SiO.sub.4/2).sub.z, in which x=5 to 99.5% by mole, y=0.5 to 95% by mole, z=0 to 30% by mole, and (b) 5 to 95% by weight, with respect to the total weight of the copolymer of a shell made of an organopolymer from mono- or poly-ethylenically unsaturated monomers; and R stands for the same or different monovalent alkyl or alkenyl radicals with 1 to 6 carbon atoms, aryl radicals or substituted hydrocarbon radicals.

Abstract translation: PCT No.PCT / EP97 / 02093 Sec。 371日期：1998年9月28日 102（e）1998年9月28日PCT PCT 1997年4月24日PCT公布。 公开号WO97 / 41183 日期1997年11月6日上述使用有机聚合物壳的交联硅氧烷弹性体颗粒作为配制基于水溶性或水可稀释粘合剂的水性涂料组合物的组分。 硅氧烷弹性体颗粒包含：（a）相对于共聚物的总重量，通式（R2SiO2 / 2）x（RSiO3 / 2）y（SiO4 / 2）的核聚合物为5〜95重量％ z，其中x = 5〜99.5摩尔％，y = 0.5〜95摩尔％，z = 0〜30摩尔％，（b）5〜95重量％ 由单或多烯属不饱和单体的有机聚合物制成的壳共聚物; R代表具有1至6个碳原子的相同或不同的一价烷基或烯基，芳基或取代的烃基。

公开(公告)号：US6130273A

公开(公告)日：2000-10-10

申请号：US219551

申请日：1994-03-29

Applicant: Roger Owen Edwards ,  Gregory Ian Foster ,  Kevin Hilton Green ,  Garry Michael McKay

Inventor： Roger Owen Edwards ,  Gregory Ian Foster ,  Kevin Hilton Green ,  Garry Michael McKay

IPC: B05D1/40 ,  C08L67/00 ,  C09D5/00 ,  C09D5/03 ,  C09D133/06 ,  C09D167/00 ,  C09D167/02 ,  C09D201/00 ,  C08J3/20 ,  C08K3/10 ,  C08K31/00

CPC classification number: C09D167/00 ,  C09D201/00 ,  C08L67/00

Abstract: The present invention discloses solventless composition suitable for application as a hot melt to a substrate, said composition comprising a mixture or alloy of resins, selected such that the averaged glass transition temperature (Tg) of the combined unreacted resins is greater than -30.degree. and less than +60.degree. C. The melt viscosity of the unreacted resins are selected so that the combined resin mix has a melt viscosity of from about 0.05 to 25 Poise when measured at 180.degree. C. and at a shear rate of 10,000 Hz.

Abstract translation: 本发明公开了一种无溶剂组合物，适合作为热熔胶应用于基材，所述组合物包含树脂的混合物或合金，其选择使得组合的未反应树脂的平均玻璃化转变温度（Tg）大于-30℃， 选择未反应树脂的熔体粘度，使得当在180℃和10,000Hz的剪切速率下测量时，组合的树脂混合物的熔体粘度为约0.05至25泊。

公开(公告)号：US6013733A

公开(公告)日：2000-01-11

申请号：US38107

申请日：1998-03-11

Applicant: Debra L. Singer ,  Kurt G. Olson ,  Kurt A. Humbert ,  Karen A. Barkac ,  Mark E. Wozniak

Inventor： Debra L. Singer ,  Kurt G. Olson ,  Kurt A. Humbert ,  Karen A. Barkac ,  Mark E. Wozniak

IPC: C09D7/47 ,  C09D201/00 ,  C08L23/04 ,  C08L33/14 ,  C08L63/00 ,  C08L67/00 ,  C08L77/00

CPC classification number: C09D7/06 ,  C09D201/00 ,  Y10T428/31692

Abstract: Curable coating compositions comprising either a liquid or particulate curable film-forming resinous material, a flow control agent which is a copolymer and optionally a carrier for the liquid resinous material. The copolymer is from at least one non-amino, non-hydroxyl and non-acid functional alkyl acrylate or methacrylate containing from 1 to 20 carbon atoms in the alkyl group, and functional monomer of either (i) amino functional acrylates and methacrylates in an effective amount to give the copolymer an amine value in the range from 2 to 70, or (ii) acid functional acrylate and methacrylate in an effective amount to give the copolymer an acid value in the range of from 10 to 30. Additionally, with either functional monomer (i) or (ii) another functional comonomer (iii) can be present in the copolymer which is hydroxyalkyl acrylate and/or hydroxyalkyl methacrylate and/or caprolactone polyol monomer. Comonomer (iii) can be present in the copolymer in an effective amount to give the copolymer a hydroxyl number is in the range of about 0 to 100.

Abstract translation: 可固化的涂料组合物包括液体或颗粒状可固化成膜树脂材料，流动控制剂，其是共聚物和任选的液体树脂材料的载体。 该共聚物来自烷基中至少一个含有1-20个碳原子的非氨基，非羟基和非​​酸官能的丙烯酸酯或甲基丙烯酸烷基酯，和（i）氨基官能的丙烯酸酯和甲基丙烯酸酯的官能单体 有效量使得共聚物的胺值在2-70范围内，或（ii）酸官能丙烯酸酯和甲基丙烯酸酯有效量，以使共聚物的酸值在10至30的范围内。另外， 在丙烯酸​​羟烷基酯和/或甲基丙烯酸羟烷基酯和/或己内酯多元醇单体的共聚物中可以存在官能单体（i）或（ii）另一功能性共聚单体（iii）。 共聚单体（iii）可以以有效的量存在于共聚物中，得到共聚物，羟值在约0-100范围内。

公开(公告)号：US5902847A

公开(公告)日：1999-05-11

申请号：US689146

申请日：1996-07-30

Applicant: Junpei Yanagi ,  Haruo Furuse ,  Kazuhiko Ohnishi ,  Masaaki Yamaya ,  Masahiro Yoshizawa

Inventor： Junpei Yanagi ,  Haruo Furuse ,  Kazuhiko Ohnishi ,  Masaaki Yamaya ,  Masahiro Yoshizawa

IPC: C09D201/00 ,  C08K5/09

CPC classification number: C09D201/00

Abstract: A coating composition prepared by mixing an organic solvent based coating composition with (1) a silicone compound having organofunctional group and hydrolyzable group in one molecule and containing a specified silicon structural unit, or (2) a silicone compound consisting of a partial cohydrolysis.cndot.condensation product of a silane mixture of alkoxysilane compound containing at least one organofunctional group selected from the group consisting of (meth)acryloyl group, vinyl group, haloalkyl group, amino group, epoxy group and mercapto group with tetraalkoxysilane compound.

Abstract translation: 通过将有机溶剂型涂料组合物与（1）具有有机官能团的硅氧烷化合物和可水解基团并在一分子中混合并含有特定的硅结构单元而制备的涂料组合物，或（2）由部分共水解缩合 含有选自（甲基）丙烯酰基，乙烯基，卤代烷基，氨基，环氧基和巯基中的至少一个有机官能团的烷氧基硅烷化合物与四烷氧基硅烷化合物的硅烷混合物的产物。

公开(公告)号：US5849412A

公开(公告)日：1998-12-15

申请号：US483399

申请日：1995-06-07

Applicant: Lev Bromberg ,  Elmer C. Lupton, Jr. ,  Barry Joseph Hand

Inventor： Lev Bromberg ,  Elmer C. Lupton, Jr. ,  Barry Joseph Hand

IPC: C08F2/44 ,  C08G18/08 ,  C08G18/16 ,  C08G18/42 ,  C08G18/50 ,  C08G18/70 ,  C08G18/79 ,  C08K9/10 ,  C09D7/00 ,  C09D7/12 ,  C09D201/00 ,  B32B5/16

CPC classification number: C08G18/0852 ,  C08G18/08 ,  C08G18/16 ,  C08G18/423 ,  C08G18/503 ,  C08G18/703 ,  C08G18/792 ,  C08K9/10 ,  C09D201/00 ,  C09D7/00 ,  C09D7/12 ,  C08G2190/00 ,  C08G2210/00 ,  C08G2220/00 ,  Y10T428/2984 ,  Y10T428/2985 ,  Y10T428/2987 ,  Y10T428/31928

Abstract: Methods and compositions for encapsulated polymeric gels swollen with nonaqueous reactive materials are provided. The methods include gel synthesis, swelling of a gel precursor with a first nonaqueous reactive material, and encapsulation of the swollen gel with a second nonaqueous reactive material. Gels precursors may be synthesized from crosslinking polymers, or alternatively, may be formed by crosslinking and polymerizing a monomer starting material. An accelerator may be utilized to facilitate swelling of the gel precursor with the first nonaqueous reactive material. Foams and composites may also be swollen with the first nonaqueous reactive material. The swollen gel is then contacted with a second nonaqueous reactive material such that an encapsulation layer is formed thereby. The encapsulated gels may be stored for subsequent use. The methods further include release of the first nonaqueous reactive material encapsulated within the gel under conditions which compromise the integrity of the encapsulation layer. The released first nonaqueous reactive material is then reacted with a nonaqueous reactive material, the reaction product being a useful product for a variety of applications such as coatings, adhesives, sealings, caulking, laminating materials, electrical coatings and the like.

公开(公告)号：US5744529A

公开(公告)日：1998-04-28

申请号：US573816

申请日：1995-12-18

Applicant: Derek William Butler ,  Thomas Easton ,  Peter Cheshire Hupfield

Inventor： Derek William Butler ,  Thomas Easton ,  Peter Cheshire Hupfield

IPC: C08L83/06 ,  C08F290/00 ,  C08F299/08 ,  C08G77/38 ,  C08G77/46 ,  C08L83/04 ,  C08L83/07 ,  C08L83/12 ,  C09D163/10 ,  C09D175/14 ,  C09D175/16 ,  C09D201/00 ,  C08K5/54

CPC classification number: C08G77/46 ,  C08G77/38 ,  C09D201/00 ,  C08L83/06 ,  C08L83/12

Abstract: A curable composition comprises a polysiloxane additive having at least one unit R.sub.a SiO.sub.(4-a)/2 and at least one unit R.sub.b R.sup.1 SiO.sub.(3-b)/2 wherein R is a C.sub.1-12 hydrocarbon, R.sup.1 is --(CH.sub.2).sub.n (OR.sup.2).sub.m X where R.sup.2 is C.sub.2-3 alkylene, a is 0, 1, 2 or 3 and b is 0, 1 or 2, and X is OH or --OCOCR.sup.3 .dbd.CH.sub.2 where R.sup.3 is H, methyl or ethyl, n is 2 to 5 and m is 8 to 50, provided where X is OH, n is 3 and m is 18. The compositions are useful with polyacrylates as overprint varnishes with improved stability of friction coefficients. Also disclosed is a method for making the additives.

Abstract translation: 可固化组合物包含具有至少一个单元RaSiO（4-a）/ 2和至少一个单元RbR1SiO（3-b）/ 2的聚硅氧烷添加剂，其中R是C1-12烃，R1是 - （CH2）n（ OR2）mX，其中R2是C2-3亚烷基，a是0,1,2或3，b是0,1或2，X是OH或-OCOCR3 = CH2，其中R3是H，甲基或乙基，n是2 其中X为OH，n为3，m为18，m为8至50。组合物可用作具有改进的摩擦系数稳定性的套印清漆的聚丙烯酸酯。 还公开了制备添加剂的方法。

公开(公告)号：US5262225A

公开(公告)日：1993-11-16

申请号：US962869

申请日：1992-10-19

Applicant: Bruce B. Wilson ,  Raymond E. Grunzinger

Inventor： Bruce B. Wilson ,  Raymond E. Grunzinger

IPC: C09D201/00 ,  G02B5/128 ,  G09F13/16 ,  B05D5/06 ,  B28B11/08

CPC classification number: G09F13/16 ,  C09D201/00 ,  G02B5/128 ,  Y10S362/812 ,  Y10S428/913 ,  Y10T428/24868 ,  Y10T428/24876 ,  Y10T428/252 ,  Y10T428/31688 ,  Y10T428/31699 ,  Y10T428/31855

Abstract: A curable polymer composition for use in providing a dimensionally stable coating comprises a semi-interpenetrating polymer network. The semi-interpenetrating polymer network includes a reactive polymer component, cross-linking agent, and non-reactive polymer component. The non-reactive polymer component has a molecular weight of about 7,000-30,000, and preferably about 15,000. In preferred embodiments, the reactive polymer has a molecular weight of about 30,000-200,000, and preferably about 40,000-60,000. Spacecoat compositions made with formulations described, exhibit good long-term stability, and resistance to failure upon embossing of a substrate to which the retroreflective sheeting is applied.

Abstract translation: 用于提供尺寸稳定涂层的可固化聚合物组合物包括半互穿聚合物网络。 半互穿聚合物网络包括反应性聚合物组分，交联剂和非反应性聚合物组分。 非反应性聚合物组分的分子量为约7,000-30,000，优选约15,000。 在优选的实施方案中，反应性聚合物的分子量为约30,000-200,000，优选约40,000-60,000。 用所述制剂制成的太空涂料组合物表现出良好的长期稳定性，并且在施加定向反光片材的基材的压花时具有耐破坏性。

公开(公告)号：US5130198A

公开(公告)日：1992-07-14

申请号：US515533

申请日：1990-04-27

Applicant: Robert G. Swisher ,  Peter C. Gaa ,  James W. Kasunic

Inventor： Robert G. Swisher ,  Peter C. Gaa ,  James W. Kasunic

IPC: C08J5/06 ,  C08G18/10 ,  C08K3/00 ,  C08K3/10 ,  C08K3/30 ,  C08K3/32 ,  C08K5/17 ,  C08K5/37 ,  C08K5/53 ,  C08K5/5313 ,  C08K5/5435 ,  C08K5/544 ,  C09D5/02 ,  C09D7/12 ,  C09D175/00 ,  C09D175/04 ,  C09D201/00 ,  D06M11/00 ,  D06M11/71 ,  D06M13/02 ,  D06M13/11 ,  D06M13/244 ,  D06M13/248 ,  D06M13/252 ,  D06M13/282 ,  D06M13/285 ,  D06M13/322 ,  D06M13/342 ,  D06M13/345 ,  D06M13/50 ,  D06M13/51 ,  D06M13/513 ,  D06M101/00 ,  D06M101/16 ,  D06M101/30 ,  D06M101/34 ,  D06M101/36 ,  D06M101/40

CPC classification number: C09D175/04 ,  C08G18/10 ,  C08K3/0041 ,  C08K5/17 ,  C09D201/00 ,  C09D5/024 ,  Y10T428/2962 ,  Y10T428/31601

Abstract: Polymeric-containing compositions having improved oxidative stability have the polymer and at least two stabilizing agents. These agents are selected from low temperature antioxidants such as alkali metal and alkaline earth metal hypo or hydrogen phosphites, high temperature antioxidants such as: alkali metal or alkaline earth metal phenylphosphonates, thioethers like dialkyl thioalkylionate and polymers thereof and metal deactivating agents like polydentate ligands and ethylene diamine-tetracidic acid compounds. The composition can be a coating composition for substrates including those like fibrous material including fibers, bundles of fibers, strands, roving, flakes and beads. The composition can be present as a dried residue on the substrate. For fibrous substrates, the composition also has at least one organofunctional silane coupling agent, may also have processing aids such as epoxy polyester polymers and/or lubricants. In addition, the polymeric-containing composition can have a crosslinking agent in an effective amount to produce a dried residue of limited swellability from the composition.

公开(公告)号：US4985500A

公开(公告)日：1991-01-15

申请号：US197149

申请日：1988-05-23

Applicant: Shosaku Yamamoto ,  Kazuo Kakinuma

Inventor： Shosaku Yamamoto ,  Kazuo Kakinuma

IPC: C08L101/00 ,  C09D5/00 ,  C09D201/00

CPC classification number: C09D201/00 ,  Y10T428/31551

Abstract: A primer composition usable for steel sheets and plastic sheets in vehicle bodies consists essentially of a component (A) consisting essentially of at least one resin having a glass transition temperature of not higher than -20.degree. C., preferably not lower than -75.degree. C., and an elongation at break of not less than 400%, preferably not greater than 900%, at 20.degree. C. and a component (B) consisting essentially of at least one crosslinking resin, the weight ratio of solid content of (A) to (B) being 70-99:30-1.