Abstract:
Copolymers are described of at least 75% by weight of tert-butyl styrene, from 1% to 24% by weight of a copolymerizable second monomer and from 1% to 10% by weight of methacrylic acid, the copolymers having certain specified solubility and rheological characteristics in AVTUR 50 aviation kerosene. A process for making the copolymers by aqueous emulsion polymerization of the monomers under certain defined conditions is also described. The copolymers are useful as additives to liquid hydrocarbon aircraft fuels for the purpose of reducing the tendency of such fuels to form inflammable mists under shock conditions.
Abstract:
A crude oil composition having a low pour point is prepared by incorporating into a waxy crude oil an effective pour depressant amount of an oil-soluble polymer, such as vinyl acetate-ethylene-propylene or butylene terpolymer or a graft copolymer in which propylene or butylene is grafted onto an ethylene-vinyl acetate copolymer backbone or basic chain. The terpolymer may be added with mixing directly to the heated crude or in hydrocarbon solution such as a solution of the terpolymer in a middle distillate or kerosene. In another aspect, this invention relates to a process for the pipeline transportation of the crude oil compositions previously described.
Abstract:
Crude oils and residual fuel oils having improved pour point and flow properties are obtained by incorporating therein a small amount of a new terpolymer prepared from ethylene, a vinyl ester, and a dialkylvinyl carbinol. The terpolymer has a number average molecular weight of about 500-10,000 and suitably contains 45-80 wt. % ethylene, 10-25 wt. % vinyl ester of a fatty acid having up to about eight carbon atoms and 10-30 wt. % dialkylvinyl carbinol wherein the alkyl groups have up to about six carbon atoms.
Abstract:
Polymers of 1,000 to 50,000 and preferably of 1,000 to 2,900 number average molecular weight, comprising 3 to 40 molar proportions of ethylene per molar proportion of an ethylenically unsaturated monomer, are prepared by free radical catalysts in a solvent at temperatures of less than 130.degree.C. in order to minimize ethylene branching, for use as wax crystal modifying agents, e.g. pour depressants and flow improvers for distillate mineral oil, e.g. middle distillate fuel oil.
Abstract:
Described herein are associative polymers capable of controlling one or more physical and/or chemical properties of non-polar compositions and related compositions, methods and systems.
Abstract:
Described herein are associative polymers capable of controlling one or more physical and/or chemical properties of non-polar compositions and related compositions, methods and systems.
Abstract:
A copolymer obtained by copolymerization of at least: an apolar monomer (ma) with the following formula (I), where u=0 or I, w=0 or I, E=-0- or —NH(Z)—, or —O—CO—, or —NH—CO— or —CO—NH—, wherein Z is H or an alkyl group, and G is a group selected among an alkyl, an aromatic ring and an arylalkyl; and a polar monomer (mb) selected among those of the following formula (II), wherein t=0 or I, Q is selected among the oxygen atom and the —NR′— group, wherein R′ is selected among a hydrogen atom and hydrocarbon chains, and R is a hydrocarbon chain substituted by at least one quaternary ammonium group and optionally one or more hydroxyl groups. The invention also relates to the use of such a copolymer as a detergent additive in a liquid fuel of an internal combustion engine.