公开(公告)号：US20120302669A1

公开(公告)日：2012-11-29

申请号：US13567936

申请日：2012-08-06

Applicant: Jiang-Jen Lin ,  Yu-Min Chen ,  Yi-Lin Liao

Inventor： Jiang-Jen Lin ,  Yu-Min Chen ,  Yi-Lin Liao

IPC: C09K21/12 ,  C08K3/34 ,  C08L63/02

CPC classification number: C09K21/12 ,  C07F9/067 ,  C08K5/5399 ,  C08L63/00

Abstract: A phosphorous flame retardant primarily includes hexachlorotriphosphazene (HCP) having poly(oxyalkylene)amine substitutes. The poly(oxyalkylene)amine includes at least two end groups. The phosphorous flame retardant can further include layered silicate clay. The layered silicate clay can be intercalated and modified with the poly(oxyalkylene)amine substitutes of HCP to effectively promote thermal stability. The flame retardant, phosphazene-poly(oxyalkylene)amine adducts, can be applied to a polymer. By the cross-linking between them, the flame-retarding property of the polymer can be improved. Also provided is a method for producing the flame retardant of phosphazene-poly(oxyalkylene)amine adducts and application thereof to a polymer.

Abstract translation: 磷阻燃剂主要包括具有聚（氧化烯）胺替代物的六氯三磷腈（HCP）。 聚（氧化烯）胺包括至少两个端基。 磷阻燃剂还可以包括层状硅酸盐粘土。 层状硅酸盐粘土可以用HCP的聚（氧化烯）胺替代物插层和改性，以有效地促进热稳定性。 阻燃剂，磷腈 - 聚（氧化烯）胺加合物可以应用于聚合物。 通过它们之间的交联，可以提高聚合物的阻燃性能。 还提供了制备磷腈 - 聚（氧化烯）胺加合物的阻燃剂的方法及其在聚合物中的应用。

公开(公告)号：US08318844B2

公开(公告)日：2012-11-27

申请号：US13109919

申请日：2011-05-17

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Rui-Xuan Dong ,  Hui-Fen Lin ,  Yueh-Hsien Wu

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Rui-Xuan Dong ,  Hui-Fen Lin ,  Yueh-Hsien Wu

IPC: C08K3/08

CPC classification number: C08G18/6674 ,  C08G18/4833 ,  C08G59/50 ,  C08K3/18 ,  C08K9/08 ,  C08K2201/011

Abstract: The present invention provides an oil-dispersible composite of metallic nanoparticles and a method for synthesizing the same. The composite primarily includes metallic nanoparticles and an oily polymeric polymer such as polyurethane (PU). The oily polymeric polymer serves as a carrier of the metallic nanoparticles by chelating therewith so that the metallic nanoparticles are dispersed uniformly. In the method of the present invention, the metallic ions are first chelated by the oily polymeric polymer and then reduced into nanoparticles. The composite of the present invention is about 5 to 100 nm in particle size.

Abstract translation: 本发明提供一种金属纳米粒子的油分散性复合体及其合成方法。 复合材料主要包括金属纳米颗粒和油性聚合物聚合物如聚氨酯（PU）。 油性聚合物聚合物通过与其螯合而用作金属纳米颗粒的载体，使得金属纳米颗粒均匀分散。 在本发明的方法中，金属离子首先被油性聚合物聚合物螯合，然后还原成纳米颗粒。 本发明的复合体的粒径为约5〜100nm。

公开(公告)号：US20120171449A1

公开(公告)日：2012-07-05

申请号：US13311429

申请日：2011-12-05

Applicant: Jiang-Jen LIN ,  Ya-Chi WANG ,  Yi-Lin LIAO ,  Chih-Wei CHIU

Inventor： Jiang-Jen LIN ,  Ya-Chi WANG ,  Yi-Lin LIAO ,  Chih-Wei CHIU

IPC: B32B19/00 ,  B29D7/01 ,  B32B19/02

CPC classification number: C08J5/18 ,  B29D7/01 ,  C08J2329/04 ,  C09K21/02

Abstract: To produce an anti-flame film, nanoscale silicate platelets (NSP) are first diluted with water or an organic solvent; the dispersion is then dried on a surface to remove the water or organic solvent and finally an almost inorganic and flexible film with a thickness of 1 to 1,000 μm is obtained. The film has a regularly layered alignment of primary platelet (1 nm thickness) structure. The NSP film has excellent anti-flame and heat insulation properties that can effectively shield a flame of more than 800° C. without apparent deformation in shape. The NSP can be blended with polymers with a composition over 30% or preferably 70% of NSP to make composite films with significant improvement in flame and heat shielding.

Abstract translation: 为了生产防火膜，首先用水或有机溶剂稀释纳米硅酸盐血小板（NSP）; 然后在表面上干燥分散体以除去水或有机溶剂，最后得到厚度为1-1000μm的几乎无机和柔性的膜。 该膜具有初级血小板（1nm厚度）结构的规则分层排列。 NSP薄膜具有优异的抗火焰和隔热性能，可有效屏蔽800°C以上的火焰，无明显变形。 NSP可以与NSP的组成超过30％或优选70％的聚合物混合，以制备具有明显改善火焰和热屏蔽性能的复合膜。

公开(公告)号：US20120123037A1

公开(公告)日：2012-05-17

申请号：US13109919

申请日：2011-05-17

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Rui-Xuan Dong ,  Hui-Fen Lin ,  Yueh-Hsien Wu

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Rui-Xuan Dong ,  Hui-Fen Lin ,  Yueh-Hsien Wu

IPC: C08G18/83 ,  C08L75/08 ,  C08K5/11 ,  B82B3/00 ,  B82B1/00

CPC classification number: C08G18/6674 ,  C08G18/4833 ,  C08G59/50 ,  C08K3/18 ,  C08K9/08 ,  C08K2201/011

Abstract: The present invention provides an oil-dispersible composite of metallic nanoparticles and a method for synthesizing the same. The composite primarily includes metallic nanoparticles and an oily polymeric polymer such as polyurethane (PU). The oily polymeric polymer serves as a carrier of the metallic nanoparticles by chelating therewith so that the metallic nanoparticles are dispersed uniformly. In the method of the present invention, the metallic ions are first chelated by the oily polymeric polymer and then reduced into nanoparticles. The composite of the present invention is about 5 to 100 nm in particle size.

Abstract translation: 本发明提供一种金属纳米粒子的油分散性复合体及其合成方法。 复合材料主要包括金属纳米颗粒和油性聚合物聚合物如聚氨酯（PU）。 油性聚合物聚合物通过与其螯合而用作金属纳米颗粒的载体，使得金属纳米颗粒均匀分散。 在本发明的方法中，金属离子首先被油性聚合物聚合物螯合，然后还原成纳米颗粒。 本发明的复合体的粒径为约5〜100nm。

公开(公告)号：US08168698B2

公开(公告)日：2012-05-01

申请号：US12567674

申请日：2009-09-25

Applicant: Jiang-Jen Lin ,  Chih-Wei Chiu ,  Chien-Chia Chu

Inventor： Jiang-Jen Lin ,  Chih-Wei Chiu ,  Chien-Chia Chu

IPC: C08K9/06 ,  C08K3/34

CPC classification number: C01B33/12 ,  B82Y30/00 ,  C01P2002/08 ,  C01P2002/72 ,  C01P2002/78 ,  C01P2004/04 ,  C01P2004/22 ,  C01P2004/64 ,  C09C1/42 ,  Y10T428/2982

Abstract: A method for producing random form of nanosilicate platelets comprises mixing and acidifying an exfoliating agent with an inorganic acid to form an acidified exfoliating agent; intercalating layered inorganic silicate clay with the acidified exfoliating agent to form a mixture; and dissolving the mixture in a solvent and reacting it with a hydroxide or chloride of alkali metal or alkaline-earth metal. The hyperbranched polyamines serving as the exfoliating agent are prepared by polymerizing poly(oxypropylene)-triamine and diglycidyl ether of bisphenol-A (DGEBA). Hydrophilic amine groups of the exfoliating agent are acidified and then reacted with the layered inorganic silicate clay through cation exchange reaction and physical clay exfoliation to give random form of nanosilicate platelets.

Abstract translation: 制备随机形式的纳米硅酸盐血小板的方法包括将去角质剂与无机酸混合并酸化以形成酸化的去角质剂; 将层状无机硅酸盐粘土与酸化的去角质剂嵌入以形成混合物; 并将该混合物溶解在溶剂中并与碱金属或碱土金属的氢氧化物或氯化物反应。 用作脱皮剂的超支化多胺通过聚合双酚-A（DGEBA）的聚（氧丙烯） - 三胺和二缩水甘油醚来制备。 将去角质剂的亲水胺基酸化，然后通过阳离子交换反应和物理粘土剥离与层状无机硅酸盐粘土反应，得到随机形式的纳米硅酸盐血小板。

公开(公告)号：US20110301369A1

公开(公告)日：2011-12-08

申请号：US13007906

申请日：2011-01-17

Applicant: Jiang-Jen Lin ,  Ying-Chiao Wang ,  Pei-Ru Li

Inventor： Jiang-Jen Lin ,  Ying-Chiao Wang ,  Pei-Ru Li

IPC: C07F5/06

CPC classification number: A01N25/04 ,  A01N25/30 ,  A01N25/34 ,  A01N31/02 ,  A01N33/12 ,  A01N55/02 ,  A01N59/00 ,  A01N61/00 ,  A01N2300/00

Abstract: The present invention provides an exfoliated clay/surfactant complex for inhibiting microorganisms, viruses or plant pests. The weight ratio of the exfoliated clay to the surfactant can range from 99/1 to 1/99. Preferably, the exfoliated clay is an inorganic layered clay on a nano scale and the surfactant is cationic, nonionic, anionic or amphoteric.

Abstract translation: 本发明提供了用于抑制微生物，病毒或植物害虫的剥离粘土/表面活性剂复合物。 剥离粘土与表面活性剂的重量比可以为99/1至1/99。 优选地，剥离粘土是纳米尺度的无机层状粘土，表面活性剂是阳离子，非离子，阴离子或两性的。

公开(公告)号：US20110236430A1

公开(公告)日：2011-09-29

申请号：US13012767

申请日：2011-01-24

Applicant: Jiang-Jen Lin ,  Hong-Lin Su ,  Fu-Chuo Peng ,  Chia-Yu Chu ,  Ying-Fang Chiu ,  Pei-Ru Li ,  Hsi-Tai Sun

Inventor： Jiang-Jen Lin ,  Hong-Lin Su ,  Fu-Chuo Peng ,  Chia-Yu Chu ,  Ying-Fang Chiu ,  Pei-Ru Li ,  Hsi-Tai Sun

IPC: A61K33/24 ,  A61K9/00 ,  A61K33/00 ,  A61K33/38 ,  A61K33/34 ,  A61K33/26 ,  A61P17/02 ,  A61P31/00 ,  B82Y5/00

CPC classification number: A61K47/02 ,  A61K33/06 ,  A61K33/24 ,  A61K33/26 ,  A61K33/34 ,  A61K33/38 ,  A61K45/06 ,  B82Y5/00 ,  A61K2300/00

Abstract: The present invention provides a method for controlling toxicity of metallic particles and a low-toxicity composite of metallic nanoparticles and inorganic clay. The metallic nanoparticles are effective in preventing infection and in skinning over, and thus suitable for treating scalds/burns. In the composite, the weight ratio of metallic nanoparticles to inorganic clay preferably ranges 0.1/99.9 to 6.0/94.0 in a size of about 5 to 100 nm. Preferably, the metal is silver and the inorganic clay is nano silicate platelets.

Abstract translation: 本发明提供一种控制金属颗粒毒性的方法和金属纳米粒子和无机粘土的低毒复合物。 金属纳米粒子有效预防感染和皮肤剥落，因此适合于治疗烫伤/烧伤。 在复合材料中，金属纳米粒子与无机粘土的重量比优选为约5〜100nm的0.1 / 99.9〜6.0 / 94.0的范围。 优选地，金属是银，无机粘土是纳米硅酸盐血小板。

公开(公告)号：US08013048B2

公开(公告)日：2011-09-06

申请号：US12140507

申请日：2008-06-17

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Yen-Chi Hsu ,  Wen-Hsin Chang

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Yen-Chi Hsu ,  Wen-Hsin Chang

IPC: C08K3/08 ,  C08K5/3415 ,  C08K5/20 ,  C08K5/107 ,  C08K5/05 ,  C08F26/00

CPC classification number: C08F26/00

Abstract: The present invention discloses a polymeric polyamine which can be produced by polymerizing polyoxyalkylene-amine and a linker. The linker can be anhydride, carboxylic acid, epoxy, isocyanate or poly(styrene-co-maleic anhydride) copolymers (SMA). The present invention also discloses a method for stabilizing the Ag nanoparticles with polymeric polyamine. The polymeric polyamine serving as a stabilizer or dispersant is mixed with a water solution of silver salt and then a reducer is provided to reduce the silver ions and form an organic or a water solution of Ag nanoparticles. Water or solvent of this solution can be further removed through a heating, freezing or decompression process, and thus solid content of the solution can be increased. The concentrated solution also can be diluted to obtain a stable dispersion without aggregation.

Abstract translation: 本发明公开了一种聚合多胺，其可通过聚合聚氧亚烷基 - 胺和连接体而制备。 接头可以是酐，羧酸，环氧，异氰酸酯或聚（苯乙烯 - 共 - 马来酸酐）共聚物（SMA）。 本发明还公开了一种用聚合多胺稳定Ag纳米颗粒的方法。 用作稳定剂或分散剂的聚合多胺与银盐水溶液混合，然后提供还原剂以还原银离子并形成Ag纳米颗粒的有机或水溶液。 该溶液的水或溶剂可以通过加热，冷冻或减压方法进一步除去，从而可以提高溶液的固体含量。 浓缩溶液也可以稀释以获得稳定的分散体而不凝聚。

公开(公告)号：US20110024699A1

公开(公告)日：2011-02-03

申请号：US12843050

申请日：2010-07-26

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Rui-Xuan Dong ,  Wei-Li Lin ,  Chao-Po Hsu

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Rui-Xuan Dong ,  Wei-Li Lin ,  Chao-Po Hsu

IPC: H01B1/02 ,  C08F222/08 ,  B22F9/16

CPC classification number: C08F222/08 ,  B22F9/24 ,  B22F2998/00 ,  C08F222/1006 ,  C08F222/38 ,  C30B7/14 ,  C30B29/02 ,  H01B1/22 ,  B22F1/0018

Abstract: A polymeric polymer containing poly(oxyethylene)-amine and its application to preparation of silver nanoparticles. The polymeric polymer is prepared from poly(oxyethylene)-amine and a linker, for example, poly(styrene-co-maleic anhydride) (SMA) or dianhydride. The polymeric polymer can chelate silver ions and reduce them to silver atoms which are dispersed as nanoparticles. No additional reducing agent is needed and more than 30% of solid content of the nanoparticles solution can be achieved without aggregation. The prepared silver nanoparticles are both hydrophilic and hydrophobic and therefore are compatible with polymers.

Abstract translation: 含聚（氧乙烯） - 胺的聚合物聚合物及其在制备银纳米颗粒中的应用。 聚合物聚合物由聚（氧乙烯） - 胺和接头例如聚（苯乙烯 - 共 - 马来酸酐）（SMA）或二酐制备。 聚合物聚合物可以螯合银离子并将其还原成分散为纳米颗粒的银原子。 不需要额外的还原剂，并且可以在没有聚集的情况下实现超过30％的纳米颗粒溶液的固体含量。 所制备的银纳米颗粒是亲水和疏水的，因此与聚合物相容。

公开(公告)号：US20110011208A1

公开(公告)日：2011-01-20

申请号：US12836762

申请日：2010-07-15

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Chao-Po Hsu ,  Wei-Li Lin ,  Yueh-Hsien Wu

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Chao-Po Hsu ,  Wei-Li Lin ,  Yueh-Hsien Wu

IPC: B22F9/16

CPC classification number: B22F9/24 ,  B22F1/0018 ,  B82Y30/00 ,  Y10S977/896

Abstract: The present invention provides a method for producing silver nanoparticles by employing ethanolamine. The method of this invention can be easily operated and no organic solvent is required. Ethanolamine first reacts with a mixture of poly(oxyalkylene)-amine/epoxy or copolymers of poly(styrene-co-maleic anhydride) (abbreviated as SMA) to generate polymeric polymers. The polymeric polymers then reduce silver ions to silver atoms which are dispersed in the form of silver nanoparticles. Functional groups of the polymeric polymers can chelate with silver ions and be stably compatible with water or organic solvents, whereby the silver nanoparticles can be stably dispersed without aggregation and the produced silver nanoparticles.

Abstract translation: 本发明提供使用乙醇胺制造银纳米粒子的方法。 本发明的方法可以容易地操作，不需要有机溶剂。 乙醇胺首先与聚（氧化烯） - 胺/环氧树脂或聚（苯乙烯 - 共 - 马来酸酐）（缩写为SMA）的共聚物的混合物反应生成聚合物聚合物。 聚合物聚合物然后将银离子还原成以银纳米颗粒形式分散的银原子。 聚合物聚合物的官能团可以与银离子螯合并与水或有机溶剂稳定地相容，由此可以稳定地分散银纳米颗粒而不会聚集，并且所制备的银纳米颗粒。