公开(公告)号：US4450070A

公开(公告)日：1984-05-22

申请号：US320989

申请日：1981-11-13

Applicant: Robert E. Hefner, Jr.

Inventor： Robert E. Hefner, Jr.

IPC: B03D1/004 ,  B03D1/01 ,  B03D1/02 ,  B03B1/00

CPC classification number: B03D1/02 ,  B03D1/006 ,  B03D1/01 ,  B03D1/011 ,  B03D2201/02 ,  B03D2203/08

Abstract: Froth flotation of oxidized coal in the presence of certain imidazoline or imidazolinium salts improves both the selectivity and recovery attained. Imidazolines found particularly efficacious are those bearing a fatty alkyl group in the 2- position and an N-aminoethyl or N-hydroxyethyl group. Preferred imidazolinium salts are those corresponding to the following formula: ##STR1## wherein R is a C.sub.6 to C.sub.22 alkyl or alkenyl group.

Abstract translation: 在某些咪唑啉或咪唑啉鎓盐存在下，氧化煤的浮选浮选提高了选择性和回收率。 发现特别有效的咪唑啉是在2-位具有脂肪烷基和N-氨基乙基或N-羟乙基的那些。 优选的咪唑啉鎓盐是对应于下式的那些：其中R是C 6至C 22烷基或链烯基。

公开(公告)号：US4425227A

公开(公告)日：1984-01-10

申请号：US308491

申请日：1981-10-05

Applicant: Scott L. Smith

Inventor： Scott L. Smith

IPC: B03B9/02 ,  B03D1/016 ,  B03D1/02 ,  B03D3/06 ,  C10C3/00 ,  C10G1/04 ,  B03B1/00

CPC classification number: C10C3/007 ,  B03B9/02 ,  B03D1/002 ,  B03D1/006 ,  B03D1/016 ,  B03D1/02 ,  B03D3/06 ,  C10G1/047 ,  B03D2201/002 ,  B03D2201/005 ,  B03D2201/02 ,  B03D2203/006

Abstract: A method for upgrading the bitumen content of tar sands, wherein a raw tar sand slurry admixture of tar sands, water, collectors, and dispersing/wetting agents is milled; conditioned and then separated by a series of froth flotations at ambient temperatures from about 2.degree. C. to about 25.degree. C. to recover a concentrated bitumen tar sand product which may be processed by conventional means to recover oil from the bitumen. Enhanced recovery of bitumen may be accomplished by moderate heating in one or more of the flotation zones to about 50.degree. C. The method permits recovery and recycle of various components used in processing of the tar sand.

Abstract translation: 提高焦油砂的沥青含量的方法，其中研磨焦油砂，水，收集剂和分散/润湿剂的原焦油砂浆料混合物; 然后通过一系列泡沫浮选在约2℃至约25℃的环境温度下分离，以回收可通过常规方法加工以从沥青回收油的浓缩沥青焦油砂产品。 可以通过在一个或多个浮选区中适度加热至约50℃来实现沥青的增强的回收。该方法允许在焦油砂的加工中使用的各种组分的回收和再循环。

公开(公告)号：US4363724A

公开(公告)日：1982-12-14

申请号：US181658

申请日：1980-08-26

Applicant: George W. Panzer ,  William Boyer

Inventor： George W. Panzer ,  William Boyer

IPC: B03D1/012 ,  B03D1/02

CPC classification number: B03D1/012 ,  B03D1/02 ,  B03D2201/02 ,  B03D2203/02

Abstract: A method of beneficiating ore containing barite by a froth flotation process. C.sub.8-34 alpha olefin sulfonates and salts thereof are the active component in compositions which are effective barite collectors and frothers. Additionally, the alpha olefin sulfonates can be admixed with C.sub.8-34 alkyl sulfates, salts thereof, tall oil fatty acids, salts thereof, mahogany petroleum sulfonates, salts thereof, sulfosuccinamates, salts thereof, as well as with admixtures of these compounds to achieve compositions which are efficient barite collectors and frothers.

Abstract translation: 通过泡沫浮选法对含有重晶石的矿石进行选矿的方法。 C8-34α烯烃磺酸盐及其盐是有效的重晶石收集剂和起泡剂的组合物中的活性组分。 此外，α-烯烃磺酸盐可以与C 8〜34烷基硫酸盐，其盐，妥尔油脂肪酸，其盐，桃花心木石油磺酸盐，其盐，磺基琥珀酸盐，其盐以及这些化合物的混合物混合以实现组合物 它们是有效的重晶石收集器和起泡器。

公开(公告)号：US4362552A

公开(公告)日：1982-12-07

申请号：US7314

申请日：1979-01-29

Applicant: Vojislav Petrovich

Inventor： Vojislav Petrovich

IPC: B03D1/008 ,  B03D1/01 ,  B03D1/02 ,  C01G39/02 ,  C01G41/02 ,  C22B3/00

CPC classification number: B03D1/02 ,  B03D1/008 ,  B03D1/01 ,  C01G39/02 ,  C01G41/02 ,  B03D2201/02 ,  B03D2201/04 ,  B03D2203/04

Abstract: Beneficiation of metallic ores selected from the group of zinc, bismuth, cobalt, nickel, titanium, zirconium, thorium, chromium, molybdenum, wolfram, and uranium, by froth flotation process using commercial amines in conjunction with oxalic acid or alkali oxalates to obtain pure concentrates of said metal values comprises; adding to a water suspension of finely divided ore of amine type collectors and an adequate amount of oxalic acid or a soluble oxalate which acting in conjunction activate and levitate in the froth by usual froth flotation process the metal values of zinc, bismuth, cobalt, nickel, titanium, zirconium, chromium, and uranium minerals; and for molybdenum and wolfram recovering the pulp of mineral slurry are oxidized with hydrogen peroxide, or any strong oxidizing agent and proceed as described above.

Abstract translation: 通过使用商业胺与草酸或碱草酸盐结合的泡沫浮选法，从锌，铋，钴，镍，钛，锆，钍，铬，钼，钨和铀中选出的金属矿石的获得，以获得纯 所述金属值的浓缩物包括： 加入细碎的胺型收集器的水悬浮液和足够量的草酸或可溶性草酸盐，其通过通常的泡沫浮选法在泡沫中起作用并浮起，锌，铋，钴，镍的金属值 ，钛，锆，铬和铀矿物; 并且对于钼和钨回收矿物浆料的纸浆，用过氧化氢或任何强氧化剂氧化并如上所述进行。

公开(公告)号：US4317715A

公开(公告)日：1982-03-02

申请号：US207339

申请日：1980-11-14

Applicant: Vaino V. H. Hintikka ,  Kaarlo M. J. Saari

Inventor： Vaino V. H. Hintikka ,  Kaarlo M. J. Saari

IPC: B03D1/001 ,  B03D1/02

CPC classification number: B03D1/01 ,  B03D1/002 ,  B03D1/008 ,  B03D2201/02 ,  B03D2203/06

Abstract: A process for the separate recovery of phosphate and carbonate minerals from finely-divided phosphate-carbonate-silicate ores or concentrates with a carbonate to phosphate ratio of over 1 is disclosed, in which an anionic collector agent is added to an aqueous slurry of these ores and concentrates, the slurry is then exposed to froth-flotation in order to separate a silicate-bearing residue from phosphate-carbonate concentrate, thereafter(a) the combined phosphate-carbonate concentrate is either treated with a base in order to remove the collector-agent coatings from the surfaces of the mineral particles, whereafter the combined concentrate is froth-flotated with a cationic collector agent using a depressing agent for carbonate in order to recover the phosphate concentrate and the carbonate concentrate separately, or(b) the aqueous slurry to which the anionic collector agent has been added and which has been froth-flotated is treated with sulfur dioxide or carbon dioxide in order to inactivate the collector-agent coatings on the surfaces of the carbonate minerals, whereafter the slurry is froth-flotated in order to obtain separately recovery of a phosphate concentrate and a carbonate concentrate.

Abstract translation: 公开了从碳酸盐与磷酸盐比率超过1的细碎磷酸盐 - 碳酸盐 - 硅酸盐矿石或浓缩物中分离回收磷酸盐和碳酸盐矿物的方法，其中将阴离子捕收剂加入到这些矿石的含水浆料中 和浓缩物，然后将浆料暴露于浮选浮选，以将含硅酸盐的残余物与磷酸盐 - 碳酸盐浓缩物分离，此后（a）将组合的磷酸盐 - 碳酸盐浓缩物用碱处理以除去收集器 - 将矿物颗粒表面的试剂涂层，然后用阳离子收集剂用碳酸盐抑制剂将组合的浓缩物泡沫浮选，以分别回收磷酸盐浓缩物和碳酸盐浓缩物，或（b）将含水浆料 其中添加了阴离子捕收剂并且已经被泡沫浮选的物质用二氧化硫或二氧化碳处理 灭活碳酸盐矿物表面上的收集剂剂涂层，之后将浆料浮选，以便分别回收磷酸盐浓缩物和碳酸盐浓缩物。

公开(公告)号：US4309282A

公开(公告)日：1982-01-05

申请号：US139957

申请日：1980-04-14

Applicant: Eugene L. Smith, Jr. ,  Andrew C. Poulos ,  Richard E. Ellwanger

Inventor： Eugene L. Smith, Jr. ,  Andrew C. Poulos ,  Richard E. Ellwanger

IPC: B03D1/008 ,  B03D1/012 ,  B03D1/02

CPC classification number: B03D1/021 ,  B03D1/008 ,  B03D1/012 ,  B03D1/016 ,  B03D2201/002 ,  B03D2201/02 ,  B03D2203/06

Abstract: Froth flotation of phosphate ore in the presence of residual organic polymeric flocculants is improved in recovery when a collector comprising a fatty acid derived from vegetable or mineral oils and a surface active agent is employed.

Abstract translation: 当存在含有源自植物油或矿物油的脂肪酸和表面活性剂的收集器时，在残留的有机聚合物絮凝剂存在下，磷酸盐矿石的泡沫浮选得到改善。

公开(公告)号：US4305815A

公开(公告)日：1981-12-15

申请号：US107814

申请日：1979-12-28

Applicant: Robert E. Hefner, Jr.

Inventor： Robert E. Hefner, Jr.

IPC: B03D1/01 ,  B03D1/02

CPC classification number: B03D1/01 ,  B03D1/006 ,  B03D1/02 ,  B03D2201/02 ,  B03D2203/08

Abstract: Condensation products of a fatty acid or fatty acid ester and a hydroxyalkylated polyalkylenepolyamine are useful as conditioners to improve the recovery of clean coal in a froth flotation process. The presence of these condensation products in the flotation medium is particularly effective to enhance the recovery of oxidized bituminous coal.

Abstract translation: 脂肪酸或脂肪酸酯和羟烷基化聚亚烷基多胺的缩合产物可用作调节剂，以改善泡沫浮选工艺中清洁煤的回收率。 浮选介质中这些缩合产物的存在对于提高氧化烟煤的回收特别有效。

公开(公告)号：US4288315A

公开(公告)日：1981-09-08

申请号：US24215

申请日：1979-03-26

Applicant: John C. Morrisey, IV ,  Ulus R. Smith

Inventor： John C. Morrisey, IV ,  Ulus R. Smith

IPC: B03D1/06 ,  B03D1/002 ,  B02B1/02

CPC classification number: B03D1/002 ,  B03D1/008 ,  B03D2201/02 ,  B03D2201/06 ,  B03D2203/10

Abstract: An improvement is provided in a process for the flotation of an acid grade fluorspar enriched concentrate, having a sulfide sulfur content not greater than about 0.02%, from a fluorspar ore containing in addition to fluorspar substantial amounts of gangue minerals and metallic sulfide accessory minerals. The invention utilizes in this conventional flotation process an alkali metal sulfide, preferably sodium sulfide, as a depressor reagent, in substitution of environmentally objectionable sodium cyanide, to depress the flotation of metallic sulfide minerals, thereby rendering a flotation concentrate low in sulfide sulfur content while substantially reducing associated environmental effects.

Abstract translation: 在除了含有大量的脉石矿物和金属硫化物附属矿物之外，还含有除了含有大量石榴石矿物和金属硫化物附属矿物的萤石矿石之外，还可以从含有不超过约0.02％的硫化物硫含量的酸性氟石富集浓缩物浮选过程中得到改进。 本发明在这种常规浮选方法中利用碱金属硫化物，优选硫化钠作为抑制剂，代替环境不利的氰化钠，以抑制金属硫化物矿物的浮选，从而使浮选精矿的硫化物硫含量低，同时 大大减少相关的环境影响。

公开(公告)号：US4274950A

公开(公告)日：1981-06-23

申请号：US51905

申请日：1979-06-25

Applicant: Etienne Larribau ,  Pierre Tozzolino

Inventor： Etienne Larribau ,  Pierre Tozzolino

IPC: B03D1/012 ,  B03D1/02

CPC classification number: B03D1/012 ,  B03D2201/02 ,  B03D2203/02

Abstract: Process using collectors for the flotation of minerals which allow the separation or enrichment of certain minerals, even at pH values around 7. These collectors are organic sulphides of the type R--S--R', in which the two groups R and R' are different and at least one of them preferably carries a substituent including oxygen or sulphur. The collectors are desirably used in a proportion of 10-100 ppm in relation to the weight of the mineral subject to flotation.

Abstract translation: 使用收集器进行浮选矿物质的过程，即使在约7左右的pH值下，也能够分离或富集某些矿物质。这些收集器是RS-R'类型的有机硫化物，其中R和R'两个基团不同， 其中至少一个优选携带包含氧或硫的取代基。 相对于经过浮选的矿物的重量，收集器希望以10-100ppm的比例使用。

公开(公告)号：US4274866A

公开(公告)日：1981-06-23

申请号：US91077

申请日：1979-11-05

Applicant: Ralph W. M. Lai ,  Edwin L. Owen

Inventor： Ralph W. M. Lai ,  Edwin L. Owen

IPC: B03B9/00 ,  B03D1/008 ,  B03D1/02 ,  C22B47/00 ,  C22B1/16

CPC classification number: C22B47/0072 ,  B03B9/00 ,  B03D1/002 ,  B03D1/008 ,  B03D1/02 ,  B03D1/1493 ,  B03D1/16 ,  B03D2201/005 ,  B03D2201/02 ,  Y10S423/04

Abstract: A process in which manganese is recovered from manganese nodules after the nodules have been treated to recover base metals such as copper, nickel, cobalt, and molybdenum. The process includes the steps of reacting the manganese in the nodules to yield a carbonate and subjecting the manganese carbonate to flotation. The manganese carbonate froth is collected from the top of a flotation cell, is dried to produce a manganese concentrate, and is sintered to produce a synthetic manganese oxide. Sintering of such concentrates at 1000.degree. C. yields a product containing greater than 50% manganese.The effect of reagent dosage, pH control, and temperature control on the yield of the synthetic manganese oxide is also disclosed.

Abstract translation: 在处理结节后，从锰结节中回收锰以回收贱金属如铜，镍，钴和钼的方法。 该方法包括使锰在结节中反应以产生碳酸盐并使碳酸锰进行浮选的步骤。 从浮选槽的顶部收集碳酸锰泡沫，干燥生成锰浓缩物，并烧结以产生合成的氧化锰。 这种浓缩物在1000℃的烧结产生含有大于50％锰的产物。 还公开了试剂用量，pH值控制和温度控制对合成氧化锰产量的影响。