公开(公告)号：US20140291199A1

公开(公告)日：2014-10-02

申请号：US14246508

申请日：2014-04-07

Applicant: Auterra, Inc.

Inventor： Kyle E. Litz ,  Jennifer L. Vreeland ,  Jonathan P. Rankin ,  Mark N. Rossetti ,  Tracey M. Jordan ,  Trent A. McCaskill

IPC: C10G27/12

CPC classification number: C10G27/12 ,  C10G19/073 ,  C10G19/08 ,  C10G27/04 ,  C10G53/12 ,  C10G53/14 ,  C10G2300/201 ,  C10G2300/308 ,  C10G2300/805

Abstract: A method of upgrading a heteroatom-containing hydrocarbon feed by removing heteroatom contaminants is disclosed. The method includes contacting the heteroatom-containing hydrocarbon feed with an oxidant to oxidize the heteroatoms, contacting the oxidized-heteroatom-containing hydrocarbon feed with caustic and a selectivity promoter, and removing the heteroatom contaminants from the heteroatom-containing hydrocarbon feed. The oxidant may be used in the presence of a catalyst.

Abstract translation: 公开了一种通过除去杂原子污染物来升级含杂原子的烃进料的方法。 该方法包括使含杂原子的烃进料与氧化剂接触以氧化杂原子，使含氧化的含杂原子的烃进料与苛性碱和选择性促进剂接触，以及从含杂原子的烃进料中除去杂原子污染物。 氧化剂可以在催化剂存在下使用。

公开(公告)号：US08771501B2

公开(公告)日：2014-07-08

申请号：US12989278

申请日：2009-03-27

Applicant: Jean Cosyns ,  Olivier Ducreux ,  Quentin Debuisschert ,  Fabienne Le Peltier

Inventor： Jean Cosyns ,  Olivier Ducreux ,  Quentin Debuisschert ,  Fabienne Le Peltier

IPC: C10G45/04 ,  C10G69/08

CPC classification number: C10G45/04 ,  B01D53/04 ,  B01D53/75 ,  B01D53/8662 ,  B01D2253/104 ,  B01D2255/1021 ,  B01D2255/1023 ,  B01D2255/202 ,  B01D2255/204 ,  B01D2257/2045 ,  B01D2257/2064 ,  C10G25/003 ,  C10G35/04 ,  C10G45/10 ,  C10G69/08 ,  C10G2300/201

Abstract: The invention concerns a process for purification by elimination of chlorine in the form of hydrogen chloride and organochlorine compounds by contacting in the presence of hydrogen of at least a part of the effluent from a reforming, aromatics production, dehydrogenation, isomerisation or hydrogenation zone, said part of the effluent comprising olefins, hydrogen chloride and organochlorine compounds, on an elimination zone comprising a chain arrangement of two masses, the first mass being a mass comprising at least one metal from group VIII deposited on a mineral carrier and the second mass being a hydrogen chloride adsorbent.

Abstract translation: 本发明涉及一种通过以氯化氢和有机氯化合物的形式消除氯的纯化方法，其通过在氢气存在下与来自重整，芳族化合物生产，脱氢，异构化或氢化区的至少一部分流出物接触来进行纯化，所述方法 包含烯烃，氯化氢和有机氯化合物的一部分流出物在包括两个质量块的链排列的消除区上，第一质量块是包含至少一种沉积在矿物载体上的来自第VIII族的金属的物质，第二质量是 氯化氢吸附剂。

公开(公告)号：US20140171710A1

公开(公告)日：2014-06-19

申请号：US13715845

申请日：2012-12-14

Applicant: Cedrick Mahieux ,  Sven Ivar Hommeltoft

Inventor： Cedrick Mahieux ,  Sven Ivar Hommeltoft

IPC: C07C7/148

CPC classification number: C07C7/14883 ,  C07C7/14858 ,  C07C7/173 ,  C10G29/00 ,  C10G29/205 ,  C10G53/00 ,  C10G53/04 ,  C10G53/16 ,  C10G2300/1096 ,  C10G2300/201 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10G2400/10 ,  C07C9/14 ,  C07C9/00

Abstract: We provide a method for making hydrocarbon products with reduced organic halide contamination, comprising: a. separating an effluent from an ionic liquid catalyzed hydrocarbon conversion reaction into: i. a hydrocarbon fraction comprising an organic halide contaminant and from greater than zero to less than 5000 wppm olefins; and ii. a used ionic liquid catalyst fraction comprising a used ionic liquid catalyst; and b. contacting the hydrocarbon fraction with an aromatic hydrocarbon reagent and an ionic liquid catalyst to reduce a level of the organic halide contaminant to from greater than zero to 20 wppm in a finished hydrocarbon product.

Abstract translation: 我们提供一种制备具有降低的有机卤化物污染物的烃产品的方法，包括：a。 将来自离子液体催化的烃转化反应的流出物分离成：i。 包含有机卤化物污染物和大于0至小于5000wppm烯烃的烃馏分; 和ii。 使用的离子液体催化剂级分包含使用的离子液体催化剂; 和b。 使烃馏分与芳族烃试剂和离子液体催化剂接触，以将成品烃产物中的有机卤化物污染物的含量降至大于0至20wppm。

公开(公告)号：US08674161B2

公开(公告)日：2014-03-18

申请号：US13380316

申请日：2010-06-22

Applicant: Heidi Mediaas ,  Knut Grande ,  Hege Kummernes ,  Jens Emil Vindstad

Inventor： Heidi Mediaas ,  Knut Grande ,  Hege Kummernes ,  Jens Emil Vindstad

IPC: C07C7/12

CPC classification number: C10G25/003 ,  C10G25/12 ,  C10G2300/1033 ,  C10G2300/201 ,  C10G2300/44

Abstract: A method for isolation and quantification of naphthenate forming acids (ARN-acids) in crude oils is disclosed. The method involves selective absorbtion/adsorption of ARN acids by a solid medium. Isolation of the solid medium and transferring the ARN acids to an organic solvent which can by analysed for its ARN acid content.

Abstract translation: 公开了一种用于分离和定量原油中形成环烷酸的酸（ARN-酸）的方法。 该方法涉及通过固体培养基选择性吸附/吸附ARN酸。 分离固体介质并将ARN酸转移到可以通过分析其ARN酸含量的有机溶剂中。

公开(公告)号：US08603430B2

公开(公告)日：2013-12-10

申请号：US12400640

申请日：2009-03-09

Applicant: Joseph M. Norbeck ,  Chan Seung Park ,  Arun Sk Raju ,  Kiseok Kim

Inventor： Joseph M. Norbeck ,  Chan Seung Park ,  Arun Sk Raju ,  Kiseok Kim

IPC: C01B3/24 ,  C01B3/38

CPC classification number: C01B3/34 ,  C01B2203/00 ,  C01B2203/0233 ,  C01B2203/04 ,  C01B2203/0495 ,  C01B2203/06 ,  C01B2203/062 ,  C01B2203/0827 ,  C01B2203/0833 ,  C01B2203/0838 ,  C01B2203/0883 ,  C01B2203/0894 ,  C01B2203/1205 ,  C01B2203/1258 ,  C01B2203/1276 ,  C01B2203/146 ,  C01B2203/148 ,  C01B2203/1642 ,  C01B2203/84 ,  C10G1/002 ,  C10G2/30 ,  C10G2/32 ,  C10G2300/1003 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/201 ,  C10J3/00 ,  C10J3/54 ,  C10J3/66 ,  C10J3/721 ,  C10J3/723 ,  C10J2300/06 ,  C10J2300/0903 ,  C10J2300/0906 ,  C10J2300/0916 ,  C10J2300/092 ,  C10J2300/093 ,  C10J2300/0946 ,  C10J2300/0966 ,  C10J2300/0973 ,  C10J2300/0983 ,  C10J2300/165 ,  C10J2300/1659 ,  C10J2300/1671 ,  C10J2300/1675 ,  C10J2300/1693 ,  C10J2300/1807 ,  C10J2300/1853 ,  C10J2300/1884 ,  C10J2300/1892 ,  C10K1/143 ,  C10K1/16 ,  C10K1/165 ,  C10K3/005 ,  C10K3/006 ,  Y02E20/18 ,  Y02E50/32 ,  Y02P20/128 ,  Y02P20/145 ,  Y02P30/20

Abstract: Systems and methods for processing a methane rich producer gas are provided in which the producer gas is preferably produced via steam-hydrogasification. The product stream from the steam-hydrogasification is then subjected to autothermal reforming, steam is removed after the reforming step via condensation, and sulfur impurities are subsequently eliminated. In most preferred aspects, the process pressure is substantially maintained throughout all steps, typically in a range of 150 psi to 500 psi.

Abstract translation: 提供了用于处理富含甲烷的生产气体的系统和方法，其中生产气体优选通过蒸汽加氢气化生产。 然后将来自蒸汽加氢气化的产物流进行自热重整，在重整步骤之后通过冷凝除去蒸汽，随后除去硫杂质。 在最优选的方面，过程压力基本上保持在所有步骤中，通常在150psi至500psi的范围内。

公开(公告)号：US08591725B2

公开(公告)日：2013-11-26

申请号：US12757384

申请日：2010-04-09

Applicant: Kandasamy Meenakshi Sundaram ,  Ujjal K. Mukherjee ,  Ronald M. Venner

Inventor： Kandasamy Meenakshi Sundaram ,  Ujjal K. Mukherjee ,  Ronald M. Venner

IPC: C10G9/16

CPC classification number: C10G9/16 ,  C10G75/04 ,  C10G2300/104 ,  C10G2300/201 ,  C10G2300/308 ,  C10G2300/4075 ,  C10G2300/44 ,  C10G2400/20 ,  C10L1/1616 ,  C10L10/00 ,  C10L10/06 ,  C10L2290/545 ,  C10L2290/60

Abstract: A method for selecting a solvent or mixture of solvents useful for mitigating deposit formation, cleaning existing deposits, and/or decreasing the rate of deposit formation is disclosed. Decreasing the rate at which deposits may form and/or increasing the rate at which deposits may be removed can dramatically improve process economics (e.g., decreasing down time as a result of deposit formation). In one aspect, embodiments disclosed herein relate to a process for dispersing foulants in a hydrocarbon stream, including the steps of: determining a nature of foulants in a hydrocarbon stream; selecting a solvent or a mixture of solvents suitable to disperse the foulants based upon the determined nature; and contacting the foulants with the selected solvent or mixture of solvents.

Abstract translation: 公开了一种用于选择可用于缓解沉积物形成，清洁现有沉积物和/或降低沉积物形成速率的溶剂或溶剂混合物的方法。 降低存款可能形成和/或提高存款可能被移除的速度的速度可以显着地改善流程经济性（例如由于存款形成而减少时间）。 在一个方面，本文公开的实施方案涉及将污染物分散在烃流中的方法，包括以下步骤：确定烃流中的污染物的性质; 基于确定的性质选择适于分散污染物的溶剂或溶剂混合物; 并将污垢与选定的溶剂或溶剂混合物接触。

公开(公告)号：US20130306311A1

公开(公告)日：2013-11-21

申请号：US13895754

申请日：2013-05-16

Applicant: Russell Evan Cooper ,  Dennis John O'Rear ,  Darrell Lynn Gallup ,  Lyman Arnold Young ,  Sujin Yean

Inventor： Russell Evan Cooper ,  Dennis John O'Rear ,  Darrell Lynn Gallup ,  Lyman Arnold Young ,  Sujin Yean

IPC: C10G21/08 ,  E21B43/40 ,  E21B43/34

CPC classification number: C10G21/08 ,  B01D53/64 ,  B01D2257/602 ,  C10G2300/201 ,  C10G2300/205 ,  E21B43/34 ,  E21B43/40

Abstract: Trace amount levels of non-volatile mercury in crude oil are reduced by contacting the crude oil with a water stream containing at least a monatomic water-soluble sulfur species such as sulfides and hydrosulfides. The non-volatile mercury is extracted into the water phase forming a mercury rich wastewater, yielding a treated crude oil having at less than 50% of the original non-volatile mercury level. The wastewater can disposed or recycled by injection into a reservoir. In one embodiment, the water stream consists essentially of produced water.

Abstract translation: 通过使原油与至少含有单原子水溶性硫物质如硫化物和氢硫化物的水流接触来降低原油中微量的非挥发性汞。 非挥发性汞被提取到水相中，形成富含汞的废水，产生的处理原油的含量低于原始非挥发性汞含量的50％。 废水可以通过注入设置或回收到储存器中。 在一个实施方案中，水流基本上由生产的水组成。

公开(公告)号：US20130248419A1

公开(公告)日：2013-09-26

申请号：US13847945

申请日：2013-03-20

Applicant: Ibrahim A. ABBA ,  Raheel SHAFI ,  Abdennour BOURANE ,  Essam SAYED ,  Abdul Rahman Zafer AKHRAS

Inventor： Ibrahim A. ABBA ,  Raheel SHAFI ,  Abdennour BOURANE ,  Essam SAYED ,  Abdul Rahman Zafer AKHRAS

IPC: C10G69/06 ,  C10G51/04

CPC classification number: C10G69/06 ,  C10G9/16 ,  C10G11/00 ,  C10G45/00 ,  C10G47/00 ,  C10G49/007 ,  C10G51/02 ,  C10G51/04 ,  C10G51/06 ,  C10G55/04 ,  C10G55/06 ,  C10G67/10 ,  C10G69/00 ,  C10G69/04 ,  C10G2300/201 ,  C10G2300/308 ,  C10G2400/20 ,  C10G2400/22 ,  C10G2400/30

Abstract: An integrated hydrotreating, steam pyrolysis and catalytic cracking process for the production of olefins and aromatic petrochemicals from a crude oil feedstock is provided. Crude oil and hydrogen are charged to a hydroprocessing zone under conditions effective to produce a hydroprocessed effluent, which is thermally cracked in the presence of steam in a steam pyrolysis zone to produce a mixed product stream. Heavy components are catalytically cracked, which are derived from one or more of the hydroprocessed effluent, a heated stream within the steam pyrolysis zone, or the mixed product stream catalytically cracking. Catalytically cracked products are produced, which are combined with the mixed product stream and the combined stream is separated, and olefins and aromatics are recovered as product streams.

Abstract translation: 提供了一种用于从原油原料生产烯烃和芳族石油化工的综合加氢处理，蒸汽热解和催化裂化方法。 在有效地产生加氢处理的流出物的条件下，将原油和氢气加入加氢处理区，该加氢处理流出物在蒸汽热解区的蒸汽存在下被热裂解以产生混合产物流。 重组分被催化裂解，其衍生自一种或多种加氢处理的流出物，蒸汽热解区内的加热流，或混合产物流催化裂解。 产生催化裂化产物，将其与混合产物流混合，并将合并的流分离，并将烯烃和芳族化合物作为产物流回收。

公开(公告)号：US20130233768A1

公开(公告)日：2013-09-12

申请号：US13865062

申请日：2013-04-17

Applicant: Abdennour BOURANE ,  Raheel SHAFI ,  Essam SAYED ,  Ibrahim A. ABBA ,  Abdul Rahman Zafer AKHRAS

Inventor： Abdennour BOURANE ,  Raheel SHAFI ,  Essam SAYED ,  Ibrahim A. ABBA ,  Abdul Rahman Zafer AKHRAS

IPC: C10G69/06 ,  C10G67/04

CPC classification number: C10G55/04 ,  C10G9/36 ,  C10G21/003 ,  C10G45/00 ,  C10G67/0463 ,  C10G67/049 ,  C10G69/06 ,  C10G2300/201 ,  C10G2300/308 ,  C10G2300/4081 ,  C10G2400/20 ,  C10G2400/30

Abstract: A process is provided that is directed to a steam pyrolysis zone integrated with a solvent deasphalting zone and a hydrotreating zone to permit direct processing of crude oil feedstocks to produce petrochemicals including olefins and aromatics. The integrated solvent deasphalting, hydrotreating and steam pyrolysis process for the direct processing of a crude oil to produce olefinic and aromatic petrochemicals comprises: charging the crude oil to a solvent deasphalting zone with an effective amount of solvent for producing a deasphalted and demetalized oil stream and a bottom asphalt phase; charging the deasphalted and demetalized oil stream and hydrogen to a hydroprocessing zone operating under conditions effective to produce a hydroprocessed effluent reduced having a reduced content of contaminants, an increased paraffinicity, reduced Bureau of Mines Correlation Index, and an increased American Petroleum Institute gravity; thermally cracking the hydroprocessed effluent in the presence of steam to produce a mixed product stream; separating the mixed product stream; purifying hydrogen recovered from the mixed product stream and recycling it to the hydroprocessing zone; recovering olefins and aromatics from the separated mixed product stream; and recovering pyrolysis fuel oil from the separated mixed product stream.

Abstract translation: 提供了一种方法，其涉及与溶剂脱沥青区和加氢处理区整合的蒸汽热解区，以允许原油原料直接加工以生产包括烯烃和芳族化合物的石化产品。 用于直接加工原油以生产烯烃和芳族石油化学品的综合溶剂脱沥青，加氢处理和蒸汽热解过程包括：用有效量的溶剂将原油装入溶剂脱沥青区，用于产生脱沥青和脱金属的油料流， 底部沥青相; 将脱沥青和脱金属的油流和氢气加氢到加氢处理区，在有效地产生具有降低的污染物含量，增加的链烷烃含量，减少的矿山相关指数和增加的美国石油公司重力的加氢处理流出物的条件下操作; 在蒸汽存在下对加氢处理的流出物进行热裂解以产生混合产物流; 分离混合产物流; 净化从混合产物流中回收的氢并将其再循环到加氢处理区; 从分离的混合产物流中回收烯烃和芳族化合物; 并从分离的混合产物流中回收热解燃料油。

公开(公告)号：US08524074B2

公开(公告)日：2013-09-03

申请号：US13211418

申请日：2011-08-17

Applicant: Michael L. Braden ,  Samuel A. Lordo

Inventor： Michael L. Braden ,  Samuel A. Lordo

IPC: C10G29/20 ,  C10G29/00

CPC classification number: C10G25/003 ,  C10G29/20 ,  C10G31/08 ,  C10G53/02 ,  C10G2300/1044 ,  C10G2300/201 ,  C10G2300/202 ,  C10G2300/205

Abstract: The invention is directed towards a method of removing mercury bearing species from a hydrocarbon containing fluid. The method comprises the steps of: i) adding dithiocarbamate polymer to the fluid in an amount such that the number of mercury bonding sites on the polymer exceeds the amount of mercury atoms by at least 10% and ii) removing the mercury bearing dithiocarbamate polymer with a water/oil separation device. The invention relies upon an unexpected reversal in the solubility of dithiocarbamate polymer at very high concentrations. Because of the high solubility the polymer remains within the water phase of the hydrocarbon fluid and can be removed without the need for cumbersome precipitation methods and complicated solid liquid separation devices. As a result, the invention allows mercury contaminated crude oil to be easily rid of its mercury with easy to use equipment already present in a typical oil refinery.

Abstract translation: 本发明涉及从含烃流体中除去含汞物质的方法。 该方法包括以下步骤：i）向流体中加入二硫代氨基甲酸酯聚合物，其量使得聚合物上的汞结合位置的数量超过汞原子数量至少10％，和ii）除去带有二硫代氨基甲酸酯的聚合物与 水/油分离装置。 本发明依赖于二硫代氨基甲酸酯聚合物在非常高的浓度下的溶解度的意想不到的逆转。 由于高溶解度，聚合物保留在烃流体的水相中，并且可以被除去，而不需要繁琐的沉淀方法和复杂的固体分液装置。 因此，本发明允许汞污染的原油通过在典型的炼油厂中已经存在的易于使用的设备容易地除去其汞。