Abstract:
Specified copolymers of tert-butylstyrene are dissolved in a liquid aliphatic hydrocarbon fuel, especially an aircraft fuel, by the steps of (i) blending the finely-divided copolymer with a non-solvent hydroxylic liquid miscible with the fuel, (ii) mixing the blend into the fuel so as to give a copolymer concentration of 0.1-1% by weight, and (iii) dissolving in the fuel so treated an amino compound in an amount of 0.01-0.6 mole per 100 g of copolymer present. The copolymers thus dissolved impart to the fuel a resistance towards mist formation when the fuel is subjected to conditions of shock.
Abstract:
Mannich condensation products useful in gasoline as carburetor detergents; the condensation compositions having the formula ##STR1## wherein Z is an alkyl- and hydroxy-substituted benzyl group wherein the alkyl has 20 to 1000 carbon atoms; n is 2; x, y, and c are each 0 or 1; x+y=0 or 1; with the proviso that when x is 0 and y is 0, then c is 0; when x is 1 and y is 0, then c is 1 and when x is 0 and y is 1, then c is 1.
Abstract translation:曼尼希缩合产物在汽油中用作化油器洗涤剂; 具有式“IMAGE”的缩合组合物,其中Z是烷基和羟基取代的苄基,其中烷基具有20至1000个碳原子; n为2; x,y和c各自为0或1; x + y = 0或1; 条件是当x为0且y为0时,c为0; 当x为1且y为0时,则c为1,当x为0且y为1时,则c为1。
Abstract:
Mannich condensation products useful in gasoline as carburetor detergents; the condensation compositions having the formula ##STR1## wherein Z is an alkyl - and hydroxy - substituted benzyl group wherein the alkyl has 20 to 1000 carbon atoms, n is 2 or 3; R is an alkyl of 1 to 20 carbon atoms; a, x and c are each 0 or 1; and b is 0 to 5; with the provisos that when a = 0, then b is at least 1 and c = 1; when a = 1 and x = 0, then b and c = 0; and when a = 1 and x = 1, then c = 1.
Abstract:
Compounds having the formula ##STR1## wherein X is alkyl, hydrogen, hydroxyl, oxygen radical, alkenyl, CH.sub.2 CH.sub.2 OCH.sub.3 or CH.sub.2 C.tbd.CH;R.sup.1 is alkyl or phenethyl; andR.sup.2 is alkyl,Are good light stabilizers. These compounds are prepared for example, from acetonlyacetone, an appropriate amine hydrochloride and sodium cyanide to give N-substituted 2,5-dimethyl-2,5-dicyanopyrrolidines which are coverted by standard techniques to the corresponding dicarboxylic acid. These esters are prepared by alkylation of appropriate alkali metal salts.
Abstract translation:具有式“IMAGE”的化合物,其中X是烷基,氢,羟基,氧基,烯基,CH 2 CH 2 OCH 3或CH 2 C 3 CH 3; R1是烷基或苯乙基; 并且R2是烷基,是良好的光稳定剂。 这些化合物例如由丙酮丙酮,适宜的胺盐酸盐和氰化钠制备得到N-取代的2,5-二甲基-2,5-二氰基吡咯烷,其通过标准技术覆盖到相应的二羧酸上。 这些酯通过适当的碱金属盐的烷基化制备。
Abstract:
Substituted 1,2-dihydropyridines of the formula ##SPC1##In which R and R.sup.2 are selected from the group consisting of hydrogen, --NH.sub.2, silyl, silyl linked via oxygen, silyl linked via nitrogen, sulfamyl, organosulfonamido, nitro, organic radical, organic radical linked via oxygen, organic radical linked via sulfur, organic radical linked via nitrogen, organic radical linked via --SO-- and organic radical linked via --SO.sub.2 --; with the proviso that the R.sup.2 groupings when joined together form an ortho condensed cyclic or polycyclic hydrocarbon; R.sup.1 is a member selected from the group consisting of hydrogen, --NH.sub.2, silyl, silyl linked via oxygen, silyl linked via nitrogen, sulfamyl, organosulfonamido, nitro, organic radical, organic radical linked via oxygen, organic radical linked via sulfur, organic radical linked via nitrogen, organic radical linked via --SO-- organic radical linked via --SO.sub.2 --, mercapto, sulfino and sulfo; R.sup.3 is a member selected from the group consisting of hydrogen, halogen, and methyl; and Z is a member selected from the group consisting of halogen and an electron-withdrawing group containing an electronegative atom doubly or triply bonded to a more positive atom which atom is singly bonded to the carbon atom attached to the pyridine ring. Exemplary of such compositions is 1,4-bis(trimethylsilyl)-2-(1-cyanoethyl)-1,2-dihydropyridine. The compounds of the invention are useful as antioxidants for polyphenyl ethers, as stabilizers for halogenated polyhydrocarbons, as curing agents for silicones and epoxide resins, as dyeing improvers for polyesters and as fuel additives for imparting hypergolic properties.
Abstract:
A condensation product of an aldehyde, particularly formaldehyde which may be generated in situ, and an ether-amine of the formula HOCmH2m(OCnH2n)pNH2 where m, n and p are integers, particularly 2-(2''-hydroxyethoxy)ethylamine, is a biocide which is particularly effective against the microbes which attack hydrocarbon fractions, for example jet fuel, in the presence of water, the amount of which water may be very small. The biocide is especially useful as an additive in cutting or soluble oil emulsions to mitigate their degradation by micro-organisms.
Abstract:
A method for preparing amides by reacting a vicinal nitroketone with ammonia, a primary amine or a secondary amine at a temperature of from about 60* to about 130*C. The amides so prepared are useful as foam stabilizers, waterproofing agents, rust inhibitors, fuel oil additives, antistatic compounds, viscosity controllers, cosmetic components and high-temperature solvents.
Abstract:
N-hydroxyalkyl-N''-hydrocarbyl-hexahydropyridazines or Nalkoxyalkyl-N''-hydrocarbyl-hexahydropyridazines in which the hydrocarbyl is sec-alkyl or cycloalkyl. The novel compounds possess utility as additives to retard deterioration of organic substances due to weathering, oxidation, corrosion, etc., as curing catalysts for urethanes, as intermediates for preparing pharmaceuticals, etc.
Abstract:
APLHA-HYDROCARBYL OR BETA-HYDROCARBYL MONO-AND DIS LACTAMS, HYDROCARBYL TETRAHYDROPYRROLIDINES AND MIXTURES THEREOF ARE OBTAINED BY THE STEPS OF REDUCING A MALEIC ANHYDRIDE-OLEFIN ADDUCT WITH A METAL OR AMMONIUM HYDRIDE, IN THE PRESENCE OF A SOLVENT OF WHICH THE SAID ANHYDRIDE IS NOT ASSOCIATED, AND REACTING THE RESULTING PRODUCT WITH AN AMIDE, SUCH AS ALKYLENE-POLYAMINE, TO PRODUCT THE RESULTING PRODUCT. ALTERNATIVELY, THE MALEIC ANHYDRIDE-OLEFIN ADDUCT IS REACTED WITH THE AMINE OR POLYAMINE TO PRODUCE THE CORRESPONDING IMIDO OR BIS-IMIDO TYPE PRODUCT, FOLLOWED BY THE SAID REDUCING STEP. THE MALICE ANHYDRIDE-OLEFIN ADDUCT OF PARTICULAR INTEREST IS AN ALKENYLSUCCINIC ANHYDRIDE, PREFERABLY IN WHICH THE ALKENYL GROUP IS A RADICAL OF FROM ABOUT 6 TO ABOUT 600, AND PREFERABLY FROM ABOUT 20 TO ABOUT 300, CARBON ATOMS. THE PRODUCTS OF THIS INVENTION HAVE UTILITY AS DETERGENTS OT DISPERSANTS IN INDUSTRIAL ORGANIC FLUIDS, SUCH AS LUBRICATING OILS, AND FUELS. THE ALSO ACT AS NEUTRALIZING AGENTS, ANTICORROSION AGENTS AND THE LIKE.
Abstract:
Organic compositions, which are normally susceptible of corroding copper, are provided, containing, in an amount sufficient to inhibit such corrosion an N-acyl benzotriazole.