Abstract:
The invention concerns the use of mixed hydroxydes of bivalent and trivalent metals with a three-dimensional spaced-lattice structure of the garnet type to control the thixotropic thickening of aqueous preparations, using swellable clays and/or other swellable layer-silicate compounds of natural and/or synthetic origin as visosity-increasing agents. The preferred garnet-type mixed hydroxydes are catoites of the basic structure Ca.sub.3 Al.sub.2 (OH).sub.12 a minor proportion of whose OH units can be exchanged for acid groups, in particular silicate groups.
Abstract:
New compounds of the formula I are described which are active, for example, as antioxidants, and also a process for their preparation: ##STR1## R.sub.1 and R.sub.2 are independently of one another C.sub.1 -C.sub.20 alkyl, allyl, methallyl, unsubstituted or C.sub.1 -C.sub.8 alkyl-substituted C.sub.5 -C.sub.12 cycloalkyl, C.sub.5 -C.sub.8 cycloalkenyl, phenyl or C.sub.7 -C.sub.9 phenylalkyl, A is a direct bond, --CH.sub.2 --, --(CH.sub.2).sub.2 -- or --CH.sub.2 --CH(CH.sub.3)--, E is --(CH.sub.2).sub.2 --, --CHR.sub.6 --CH.sub.2 -- or --CH.sub.2 CHR.sub.6 --, n is 1, 2 or 3, R.sub.3 is C.sub.1 -C.sub.18 alkyl or is C.sub.1 -C.sub.18 alkyl which is interrupted by --O-- or --S--, unsubstituted or C.sub.1 -C.sub.8 alkyl-substituted C.sub.5 -C.sub.12 cycloalkyl, phenyl, naphthyl, C.sub.7 -C.sub.9 phenylalkyl, C.sub.7 -C.sub.18 alkylphenyl or is of the formula ##STR2## R.sub.4 is phenyl, naphthyl, C.sub.7 -C.sub.9 phenylalkyl, C.sub.7 -C.sub.18 alkylphenyl or is a radical of the formula ##STR3## or NR.sub.3 R.sub.4 is a group of the formula ##STR4## R.sub.5 is hydrogen, C.sub.1 -C.sub.18 alkyl, allyl, methallyl, unsubstituted or C.sub.1 -C.sub.8 alkyl-substituted C.sub.5 -C.sub.12 cycloalkyl, phenyl or naphthyl, R.sub.6 is hydrogen, C.sub.1 -C.sub.20 alkyl or C.sub.2 -C.sub.20 alkyl which is interrupted by --O--, --S--, --NR.sub.7 -- or --C(O)O--, and R.sub.7 is hydrogen or C.sub.1 -C.sub.6 alkyl.
Abstract:
A composition for lubricating a metal workpiece prior to cold forming consists essentially of: an aqueous alkaline stearate compound present in an amount sufficient to impart metal lubrication between about 180.degree. F. and about 320.degree. F.; an aqueous alkaline palmitate compound present in an amount sufficient to impart metal lubrication below about 160.degree. F.; an aqueous metallic stearate compound present in an amount sufficient to impart metal lubrication between about 320.degree. F. and 440.degree. F.; a polymeric glycol present in an amount sufficient to provide temperature stability, act as a carrier for the aqueous compounds, and impart a waxy lubrication to the metal; a compound present in an amount sufficient to act as a carrier for the aqueous compounds and to provide a translucent film barrier on the metal; an alkaline buffering agent present in an amount sufficient to provide dispersion, viscosity and stability; a hydrotropic agent present in an amount sufficient to solubilize the lubricating composition. A process is disclosed for lubricating a metal workpiece outer surface prior to cold forming, the process comprising the step of disposing a non-reactive lubricating composition on the workpiece outer surface, the outer surface having been alkaline cleaned, hot water rinsed, acid pickled, and cold water rinsed.
Abstract:
A lubricant composition for treating non-ferrous metals and alloys is provided. In particular, the composition is used to treat metal substrates when the substrates are subjected to various metal working processes. The composition includes an emulsified ester that is combined with non-ferrous lubricating materials. The emulsified ester makes the lubricant water dispersible and therefore easily removable from the metal substrates after treatment. The composition of the present invention is extremely durable, biodegradable and environmentally safe.
Abstract:
Use of polymeric two-phase systems for removing microbial contaminants from industrial lubricating agents, a method of purifying microbial contaminated lubricating agents by mixing the lubricating agent with a polymeric two-phase system, allowing the mixture to separate so as to form a top-phase containing the lubricating agent and a bottom-phase containing at least part of the microbial contaminants, and separating at least a major part of the microbially enriched bottom-phase from the top-phase, a plant for microbial purification of lubricating agents comprising a mixing tank (4) having means (7, 8) for feeding microbially contaminated lubricating agent (S) to the mixing tank, means (13) for feeding a polymeric two-phase system to the mixing tank, a stirrer (5) in the mixing tank, means (9, 10) for feeding the mixture to a separation device (6) for separating the mixture into a top-phase (T) containing lubricating agents, and a bottom-phase (B) containing microbial contaminants, and means (18) for recovering the top-phase of the two-phase system, and a lubricating agent concentrate, in which at least part of the lubricating agent at the same time forms part of the top-phase component of the polymeric two-phase system.
Abstract:
A non-toxic coolant/lubricant is provided which is specifically designed for use in extremely high-load, high-stress machine operations, such as broaching. The composition of this coolant/lubricant includes about 8 to 15 wt % of molybdenum disulfide (MoS.sub.2) powder; about 2 to 6.6 wt % of soap flakes; about 6 to 12 wt % of a liquid polytetrafluoroethylene suspension; and about 66.4 to 84 wt % water. The liquid polytetrafluoroethylene component, which is a water-based suspension of polytetrafluoroethylene, serves as a replacement for toxic CCl.sub.4, which has been used to increase lubricity in coolant/lubricants comprising molybdenum disulfide. The replacement of CCl.sub.4 with liquid polytetrafluoroethylene in the present composition results in a non-toxic but still highly effective coolant/lubricant.
Abstract:
A lubricant composition including ethoxylated long chain primary alcohols and, preferably, boron compounds but excluding most other previously used organic lubricant materials gives superior results in tube pointing operations, especially with thick walled tubes, and is also useful for drawing operations, either subsequent to pointing or independently of pointing, where very high quality surface finishes are desired.
Abstract:
A stearate free solid lubricant for cold working of metals contains approximately equal amounts of an alkene-acrylate ionomer and an alkoxylated alcohol in which the alcohol moiety has from 18-60 carbon atoms and the alkoxylate block has about the same number of carbon atoms. This lubricant can be conveniently applied from aqueous solution/suspension and works effectively even when the underlying steel surface has no conversion coating, which is usually required with stearate lubricants for best results.
Abstract:
Alkaline diamine track lubricants for use with glass, aluminum and two-piece PET containers and other articles of manufacture are prepared from an admixture of an alkyl diamine and a water-soluble hydrotrope. The diamine lubricants are prepared without the neutralization thereof and have a corrosion inhibitor which is, preferably, a reducing agent and a biocide incorporated thereinto. A source of alkalinity may be employed, as well, to maintain the pH above 8.
Abstract:
A mandrel lubricant for use in the production of seamless tubes. The mandrel lubricant composed of graphite, clay minerals from the smectite class, a polysaccharide and optionally a surfactant. The coating of the mandrels that have passed through a cooling bath takes place in the form of an aqueous dispersion.