Abstract:
Three component additive combinations for improving the flow of distillate fuel oils comprise(A) a conventional distillate fuel flow improver(B) a lube oil pour depressant and(C) a polar compound other than certain specified nitrogen compounds which acts as an anti-agglomerant for wax particles in the fuel oil.
Abstract:
A low-pour fuel composition is prepared by blending with a gas oil a minor amount of a high asphaltene residuum, such as an Arabian Light 1050.degree. F. residuum, and from about 0.003 to about 0.50 weight percent of an oil-soluble copolymer which can be, for example, an ethylene-vinyl acetate copolymer or a block copolymer of the A--B--A type wherein the A block is derived from an ester of acrylic acid or methacrylic acid and an aliphatic alcohol and the B block is a copolymer of ethylene and vinyl acetate, etc.
Abstract:
Lubricating oil additives having both dispersant and viscosity-index improving properties are prepared by reacting a block copolymer with maleic anhydride and an alkane polyol. The block copolymer has the general configuration A-B wherein A is a monoalkenyl arene block and B is a selectively hydrogenated conjugated diene block having between 75 and 98 percent hydrogenated double bonds.
Abstract:
Polymers of 1,000 to 50,000 and preferably of 1,000 to 2,900 number average molecular weight, comprising 3 to 40 molar proportions of ethylene per molar proportion of an ethylenically unsaturated monomer, are prepared by free radical catalysts in a solvent at temperatures of less than 130.degree.C. in order to minimize ethylene branching, for use as wax crystal modifying agents, e.g. pour depressants and flow improvers for distillate mineral oil, e.g. middle distillate fuel oil.
Abstract:
Copolymers comprising within the range of 40 to 89 wt. percent ethylene, 10 to 40 wt. percent of vinyl ester of C2 to C4 monocarboxylic acid, and 1 to 30 wt. percent of unsaturated ester having a C10 to C22 alkyl group and having number average molecular weights within the range of 1,000 to 50,000, are useful in oil, e.g., as pour point depressants in distillate petroleum fuels and as dewaxing aids.
Abstract:
An additive composition comprises a polymer (A) and a condensation product (B) wherein Polymer (A) comprises the following monomer components: (i) one or more compounds of formula (I) (ii) one or more compounds of formula (II); and (iii) one or more compounds of formula (III); wherein condensation product (B) comprises the product formed by the reaction of an aliphatic aldehyde or ketone, or a reactive equivalent, with a substituted phenol or mixture of substituted phenols; The weight:weight ratio of the polymer (A) to the condensation product (B) is from 1:20 to 20:1.
Abstract:
Mineral oil compositions with trace portions of additives contain as additive a comb polymer containing ester linkages, either based on a) ethylene-vinylester copolymers modified by hydroxy groups or glycidyl groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and b) partially imidated and/or partially esterified maleic anhydride copolymers, wherein in the comb polymer based on a) and b) the modified ethylene-vinylester copolymer component is connected by means of ester linkages to the partially imidated and/or partially esterified maleic anhydride copolymer component, or a comb polymer containing ester linkages based on c) ethylene-vinylester copolymers modified by acid and/or acid anhydride groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and d) polyalcohols partially esterified with C12-C40-monocarboxylic acids wherein in the comb polymer based on c) and d) the ethylene-vinylester copolymer component modified by acid and/or acid anhydride groups is connected by means of ester linkages with the polyalcohol component partially esterified with C12-C40-monocarboxylic acids. The mineral oil compositions are suitable as flowable media to be transported at low temperatures and as mineral oil fuels with high lubricity and flowability.
Abstract:
The invention relates to the use of polymers which comprise, in copolymerized form, an α-olefin, at least one alkenyl ester and at least one ester of an α,β-unsaturated carboxylic acid with higher alcohols as an additive for fuel oils and lubricants and especially as a cold flow improver in fuel oils; to the fuel oils and lubricants additized with these polymers; and to additive packages comprising such copolymers. The invention also relates to quaternary and higher copolymers which comprise the abovementioned monomers in copolymerized form.
Abstract:
The present invention relates generally to gelled fuels and solvents. Specifically the invention relates to gel thickeners that reduce vapor pressure in fuels and solvents and are shear thinning (pseudoplastic or thixotropic) or are shear thickening and remain pourable and flowable. Still more specifically, the invention relates to nonaqueous gels made with diblock copolymers that reduce the Reid Vapor Pressure of gelled gasoline and lower the total volatility of gelled hydrocarbon solvents. These gels may contain secondary amino acid or triblock polymer gelling agents. The invention includes gel compositions and methods of making gels.