Clear semi-crystalline articles with improved heat resistance

    公开(公告)号:US09982125B2

    公开(公告)日:2018-05-29

    申请号:US15492685

    申请日:2017-04-20

    Abstract: A clear, semi-crystalline, strain induced crystallized article comprising at least one polyester which comprises: (a) a dicarboxylic acid component comprising: i) 95 to 99.99 mole % of terephthalic acid residues; and ii) 0.01 to 5 mole % of isophthalic acid; and (b) a glycol component comprising: i) 4.9 to 10.2 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and ii) 89.8 to 95.1 mole % of 1,4-cyclohexanedimethanol residues, wherein the polyester is solid stated and has an inherent viscosity from 0.76 to 1.1 dL/g and a glass transition temperature (Tg) of 90 to 110° C. The article has strain induced crystallinity from 15% to 35% when stretched at a draw ratio of 3 to 4 times at a temperature 10° C. above the Tg or from 23.2% to 35% when stretched at a draw ratio of 3.5 to 4.5 times at a temperature 20° C. above the Tg.

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