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    Epoxidized polyfarnesene and methods for producing the same
    131.
    发明授权
    Epoxidized polyfarnesene and methods for producing the same 有权

    公开(公告)号：US10745503B2

    公开(公告)日：2020-08-18

    申请号：US16104384

    申请日：2018-08-17

    Applicant: FINA TECHNOLOGY, INC.

    Inventor： Herbert Chao ,  Taejun Yoo ,  Sabrina Nehache

    IPC: C08L63/08 ,  C08L63/00 ,  C08G59/34 ,  C08G59/20 ,  C08F236/22 ,  C08F36/22 ,  C08F136/22 ,  C08C19/02 ,  C08G59/02 ,  C08C19/06

    Abstract: Aspects of the present invention relate to polymers, and particularly to farnesene polymers functionalized with one or more oxirane groups and, optionally, one or more hydroxyl groups. According to one aspect of the invention, provided is an epoxidized and optionally hydroxyl-functionalized polyfarnesene. The epoxidized farnesene polymer has at least one of a side chain or a main backbone functionalized with at least one oxirane group and, optionally, at least one terminal end functionalized with a hydroxyl group. In accordance with another aspect of the invention, a method is provided for preparing an epoxidized and optionally hydroxyl-functionalized polyfarnesene. The method includes epoxidizing a farnesene polymer, which may optionally contain one or more terminal hydroxyl groups, to functionalize at least one of a side chain or a main backbone of the farnesene polymer with an oxirane group.

    Articles having improved clarity, prepared from propylene-ethylene copolymers
    132.
    发明授权
    Articles having improved clarity, prepared from propylene-ethylene copolymers 有权

    公开(公告)号：US10428166B2

    公开(公告)日：2019-10-01

    申请号：US14986089

    申请日：2015-12-31

    Applicant: FINA TECHNOLOGY, INC.

    Inventor： Douglas Burmaster ,  Owen Hodges ,  J. Layne Lumus ,  Lu Ann Kelly ,  Mark Murphy

    IPC: C08J5/00 ,  C08F210/06 ,  C08F210/16 ,  C08L23/14

    Abstract: Molded articles are prepared from propylene-ethylene copolymers and exhibiting improved clarity and strength properties. Articles prepared include bottles and other thin-walled articles. The articles are prepared using an isotactic propylene-ethylene random copolymer resin having an ethylene content of from about 0.5 to about 3 percent by total weight of copolymer, with a xylene solubles content of less than about 1.5 percent. The injection molded article may exhibit less than about 20 percent haze, as determined by ASTM D1003, at a thickness of about 0.08 inch (2.03 mm). Articles may also be prepared from similar copolymers having an ethylene content greater than about 3 percent by total weight of copolymer, with a xylene solubles content of less than about 4 percent by total weight of copolymer. These articles may exhibit less than about 13 percent haze, as determined by ASTM D1003, at a thickness of about 0.08 inch (2.03 mm).

    Methods of catalyst activation
    134.
    发明授权
    Methods of catalyst activation 有权

    公开(公告)号：US10246535B2

    公开(公告)日：2019-04-02

    申请号：US14990899

    申请日：2016-01-08

    Applicant: FINA TECHNOLOGY, INC.

    Inventor： Kenneth P. Blackmon ,  David Ribour ,  Shabbir Malbari ,  Tim Coffy ,  Michel Daumerie

    IPC: C08F210/06 ,  C08F10/00 ,  C08F4/649 ,  C08F4/646

    Abstract: A method comprising preparing a multi-component catalyst system comprising a catalyst and a cocatalyst, and adjusting the level of at least one component of the catalyst system to maintain a user-desired level of catalyst activity throughout a process, wherein the component comprises a catalyst activator and wherein the catalyst activator comprises the catalyst or the cocatalyst. A method comprising contacting a polymerization catalyst system comprising a Ziegler-Natta catalyst and a cocatalyst with a catalyst activator at least twice during a polymerization process, wherein the polymerization process is carried out in a reactor system comprising multiple reactor types.

    Injection stretch blow molded articles and random copolymers for use therein
    137.
    发明授权
    Injection stretch blow molded articles and random copolymers for use therein 有权

    公开(公告)号：US10113020B2

    公开(公告)日：2018-10-30

    申请号：US14735329

    申请日：2015-06-10

    Applicant: FINA TECHNOLOGY, INC.

    Inventor： Luyi Sun ,  Mark Leland

    IPC: C08F210/06 ,  B29C49/00 ,  B29C49/06 ,  C08K5/00 ,  C08K3/01 ,  B29C49/10 ,  B29K23/00 ,  B29L31/00 ,  B29L7/00 ,  B29L22/00

    Abstract: A polymer composition adapted for use in injection stretch blow molding may include a metallocene random propylene-based copolymer in the absence of a clarifier. The metallocene random propylene-based copolymer may exhibit a melting point of from 105° C. to less than 175° C., a recrystallization temperature ranging from 85° C. to 100° C. as measured by DSC, a microtacticity ranging from 89% to 99%, a molecular weight (Mw) ranging from 170,000 to 210,000, and a melt flow rate of from about 1 dg/min. to about 40 dg/min. A method of forming an injection stretch blow molded (ISBM) article may include providing the metallocene random propylene-based copolymer, injection molding the metallocene random propylene-based copolymer in the absence of a clarifier into a preform, and stretch-blowing the preform into an article.

    FARNESENE-BASED MACROMONOMERS AND METHODS OF MAKING AND USING THE SAME
    140.
    发明申请
    FARNESENE-BASED MACROMONOMERS AND METHODS OF MAKING AND USING THE SAME 审中-公开

    公开(公告)号：US20180072826A1

    公开(公告)日：2018-03-15

    申请号：US15266330

    申请日：2016-09-15

    Applicant: Fina Technology, Inc.

    Inventor： Steven K. Henning ,  Taejun Yoo ,  Herbert S. Chao

    IPC: C08F36/22 ,  C08F20/18 ,  A61K8/81 ,  A61Q19/00 ,  C09J147/00 ,  C09J133/10 ,  C10M145/14

    Abstract: A macromonomer precursor is provided that includes a polymeric chain derived from farnesene and a single functional terminal end. The functional terminal end may include a hydroxyl group, an amino group, an epoxy group, an isocyanato group, or a carboxylic acid group. The terminal end of the macromonomer precursor may then be reacted with a (meth)acrylate to form a macromonomer having a (meth)acrylate functionalized terminal end that may be (co)polymerized with radically polymerizable monomers, such as alkyl(meth)acrylate monomers. Alternatively, a copolymer may be obtained by first deriving a poly(meth)acrylate from (meth)acrylate monomers having reactive groups that would allow the macromonomer precursors to be grafted onto the poly(meth)acrylate in a second step. The resulting copolymer may be incorporated as an additive in various formulations, such as a lubricant, a hydraulic fluid, a cosmetic composition, and an adhesive composition.

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