公开(公告)号：US4525481A

公开(公告)日：1985-06-25

申请号：US584076

申请日：1984-02-27

Applicant: Jiang-Jen Lin ,  John F. Knifton

Inventor： Jiang-Jen Lin ,  John F. Knifton

IPC: C07C29/157 ,  C07C45/49 ,  C07C27/06

CPC classification number: C07C29/157 ,  C07C45/49

Abstract: Acetaldehyde is prepared by contacting hydrogen and carbon monoxide with a catalyst system comprising an iodide-free ruthenium powder, an iodide-free quaternary phosphonium or ammonium base or salt and a halide-free cobalt-containing compound, such as cobalt(III) acetylacetonate or dicobalt octacarbonyl. Conducting the reaction in a substantially inert solvent such as p-dioxane is preferred.

Abstract translation: 通过使氢气和一氧化碳与包含不含碘化物的钌粉末，不含碘化物的鏻或铵碱或盐的无卤素的含钴化合物（例如乙酰丙酮钴（III））或 八羰基二钴。 在基本惰性的溶剂如对二恶烷中进行反应是优选的。

公开(公告)号：US4476326A

公开(公告)日：1984-10-09

申请号：US463380

申请日：1983-02-03

Applicant: Jiang-Jen Lin ,  John F. Knifton

Inventor： Jiang-Jen Lin ,  John F. Knifton

IPC: C07C29/32 ,  C07C45/49

CPC classification number: C07C29/32 ,  C07C45/49

Abstract: Ethanol and/or acetaldehyde are prepared in good yield by contacting methanol, hydrogen and carbon monoxide with a catalyst system comprising a cobalt-containing compound and a promoter in the presence of an inert oxygenated solvent at a temperature of from about 50.degree. C. to about 350.degree. C. and a pressure of at least 500 psig or greater. The combination of cobalt-containing compound and promoter may be (a) a cobalt-containing compound with an organo-sulphur compound, (b) an iodide-containing cobalt compound with a nitrogen-containing compound as promoter, and (c) a cobalt-containing compound with 1,1'-bis(diphenylphosphino)ferrocene.

Abstract translation: 通过在惰性氧化溶剂存在下，在约50℃至约50℃的温度下，使甲醇，氢气和一氧化碳与包含含钴化合物和助催化剂的催化剂体系接触，以良好的产率制备乙醇和/或乙醛， 约350℃和至少500psig或更大的压力。 含钴化合物和促进剂的组合可以是（a）含有有机硫化合物的含钴化合物，（b）含氮化合物与含氮化合物作为助催化剂的钴化合物，和（c）钴 （二苯基膦基）二茂铁的化合物。

公开(公告)号：US4436837A

公开(公告)日：1984-03-13

申请号：US428491

申请日：1982-09-29

Applicant: Jiang-Jen Lin

Inventor： Jiang-Jen Lin

IPC: C07C29/157 ,  C07C27/06

CPC classification number: C07C29/157

Abstract: This invention concerns a process for making alkanols and esters which comprises reacting a mixture of CO and H.sub.2 at a pressure of about 500 psig or greater and at a temperature of at least 150.degree. C. in the presence of a catalyst system comprising a ruthenium-containing compound, a samarium compound and a quaternary phosphonium salt, in the presence of an inert, oxygenated solvent.

Abstract translation: 本发明涉及一种制备链烷醇和酯的方法，该方法包括在约500psig或更高的压力和至少150℃的温度下，在包含钌 - 含锶化合物，钐化合物和季鏻盐，在惰性的含氧溶剂的存在下进行。

公开(公告)号：US4409405A

公开(公告)日：1983-10-11

申请号：US377724

申请日：1982-05-13

Applicant: Jiang-Jen Lin ,  John F. Knifton

Inventor： Jiang-Jen Lin ,  John F. Knifton

IPC: C07C29/32 ,  C07C45/49 ,  C07C29/00

CPC classification number: C07C29/32 ,  C07C45/49

Abstract: Ethanol is formed by contacting a mixture of carbon monoxide, hydrogen and methanol with a catalyst comprising a cobalt-containing compound and a germanium-containing compound, such as dicobalt octacarbonyl and triphenylgermanium hydride in the presence of an inert, oxygenated hydrocarbon solvent at a temperature of about 50.degree. to about 350.degree. C. and at a pressure of about 500 psig or greater.

Abstract translation: 通过使一氧化碳，氢气和甲醇的混合物与含有钴的化合物和含锗化合物如八羰基二钴和三苯基氢化锗在惰性的含氧烃溶剂的存在下，在温度 约50℃至约350℃和约500psig或更大的压力。

公开(公告)号：US4374285A

公开(公告)日：1983-02-15

申请号：US223514

申请日：1981-01-08

Applicant: Jiang-Jen Lin ,  John F. Knifton

Inventor： Jiang-Jen Lin ,  John F. Knifton

IPC: B01J23/00 ,  B01J23/46 ,  B01J27/00 ,  B01J27/08 ,  B01J31/00 ,  B01J31/02 ,  B01J31/18 ,  B01J31/20 ,  B01J31/22 ,  B01J31/30 ,  C07B61/00 ,  C07C27/00 ,  C07C29/32 ,  C07C31/08 ,  C07C67/00

CPC classification number: C07C29/32 ,  B01J23/46 ,  B01J27/08 ,  B01J31/0239 ,  B01J31/30 ,  B01J2531/0211 ,  B01J2531/821 ,  B01J31/0268 ,  B01J31/20 ,  B01J31/2234 ,  Y02P20/52

Abstract: Ethanol is prepared by contacting methanol, hydrogen and carbon monoxide with a catalyst system comprising a ruthenium compound, a quaternary phosphonium or ammonium base or salt and a cobalt compound such as cobalt iodide.

Abstract translation: 通过使甲醇，氢气和一氧化碳与包含钌化合物，季鏻或铵碱或盐的钴催化剂体系和钴化合物如碘化钴接触来制备乙醇。

公开(公告)号：US20210051961A1

公开(公告)日：2021-02-25

申请号：US16876081

申请日：2020-05-17

Applicant: Jiang-Jen Lin ,  J & V Consultant Corporation

Inventor： Jiang-Jen Lin ,  Shui-Fa Hou ,  Sheng-Yen Shen ,  Fang-Yi Ye ,  Ting-Yueh Hou ,  Chun-Fan Chen ,  Yi-Chen Lee

IPC: A01N59/16 ,  A01N25/08 ,  A23K20/28 ,  A23K20/20 ,  A23K10/30 ,  A23K40/10

Abstract: Metallic oxides nanoparticles are stably adsorbed on silicate clay (such as nanosilicate platelets, NSPs) to form the metallic oxide/silicate clay nano-composite. The metallic oxides nanoparticles may be ZnO, CuO, Fe3O4, MgO or CaO. Optionally, silver nanoparticles are also adsorbed on the silicate clay for applications. Different from polymer dispersants, the silicate clay has high surface area and charge density so that the metallic oxides are not wrapped and thus perform better bactericidal efficacies.

公开(公告)号：US08951330B2

公开(公告)日：2015-02-10

申请号：US13549417

申请日：2012-07-14

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Chao-Po Hsu ,  Wei-Li Lin ,  Yueh-Hsien Wu

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Chao-Po Hsu ,  Wei-Li Lin ,  Yueh-Hsien Wu

IPC: B22F9/24 ,  B22F1/00 ,  B82Y30/00

CPC classification number: B22F9/24 ,  B22F1/0018 ,  B82Y30/00 ,  Y10S977/896

Abstract: The present invention provides a method for producing silver nanoparticles by employing ethanolamine. The method of this invention can be easily operated and no organic solvent is required. Ethanolamine first reacts with copolymers of poly(styrene-co-maleic anhydride) (abbreviated as SMA) to generate polymeric polymers. The polymeric polymers then reduce silver ions to silver atoms which are dispersed in the form of silver nanoparticles. Functional groups of the polymeric polymers can chelate with silver ions and be stably compatible with water or organic solvents, whereby the silver nanoparticles can be stably dispersed without aggregation and the produced silver nanoparticles.

Abstract translation: 本发明提供使用乙醇胺制造银纳米粒子的方法。 本发明的方法可以容易地操作，不需要有机溶剂。 乙醇胺首先与聚（苯乙烯 - 共 - 马来酸酐）（缩写为SMA）的共聚物反应生成聚合物聚合物。 聚合物聚合物然后将银离子还原成以银纳米颗粒形式分散的银原子。 聚合物聚合物的官能团可以与银离子螯合并与水或有机溶剂稳定地相容，由此可以稳定地分散银纳米颗粒而不会聚集，并且所制备的银纳米颗粒。

公开(公告)号：US08491699B2

公开(公告)日：2013-07-23

申请号：US12836762

申请日：2010-07-15

Applicant: Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Chao-Po Hsu ,  Wei-Li Lin ,  Yueh-Hsien Wu

Inventor： Jiang-Jen Lin ,  Wei-Cheng Tsai ,  Chao-Po Hsu ,  Wei-Li Lin ,  Yueh-Hsien Wu

IPC: B22F9/24 ,  B82Y40/00

CPC classification number: B22F9/24 ,  B22F1/0018 ,  B82Y30/00 ,  Y10S977/896

Abstract: The present invention provides a method for producing silver nanoparticles by employing ethanolamine. The method of this invention can be easily operated and no organic solvent is required. Ethanolamine first reacts with a mixture of poly(oxyalkylene)-amine/epoxy or copolymers of poly(styrene-co-maleic anhydride) (abbreviated as SMA) to generate polymeric polymers. The polymeric polymers then reduce silver ions to silver atoms which are dispersed in the form of silver nanoparticles. Functional groups of the polymeric polymers can chelate with silver ions and be stably compatible with water or organic solvents, whereby the silver nanoparticles can be stably dispersed without aggregation and the produced silver nanoparticles.

Abstract translation: 本发明提供使用乙醇胺制造银纳米粒子的方法。 本发明的方法可以容易地操作，不需要有机溶剂。 乙醇胺首先与聚（氧化烯） - 胺/环氧树脂或聚（苯乙烯 - 共 - 马来酸酐）（缩写为SMA）的共聚物的混合物反应生成聚合物聚合物。 聚合物聚合物然后将银离子还原成以银纳米颗粒形式分散的银原子。 聚合物聚合物的官能团可以与银离子螯合并与水或有机溶剂稳定地相容，由此可以稳定地分散银纳米颗粒而不会聚集，并且所制备的银纳米颗粒。

公开(公告)号：US08487043B2

公开(公告)日：2013-07-16

申请号：US12751987

申请日：2010-03-31

Applicant: Jiang-Jen Lin ,  Yu-Min Chen ,  Yi-Lin Liao

Inventor： Jiang-Jen Lin ,  Yu-Min Chen ,  Yi-Lin Liao

IPC: C08K5/5399 ,  C07F9/02 ,  C09K21/12

CPC classification number: C09K21/12 ,  C07F9/067 ,  C08K5/5399 ,  C08L63/00

Abstract: A phosphorous flame retardant primarily includes hexachlorotriphosphazene (HCP) having poly(oxyalkylene)amine substitutes. The poly(oxyalkylene)amine includes at least two end groups. The phosphorous flame retardant can further include layered silicate clay. The layered silicate clay can be intercalated and modified with the poly(oxyalkylene)amine substitutes of HCP to effectively promote thermal stability. The flame retardant, phosphazene-poly(oxyalkylene)amine adducts, can be applied to a polymer. By the cross-linking between them, the flame-retarding property of the polymer can be improved. Also provided is a method for producing the flame retardant of phosphazene-poly(oxyalkylene)amine adducts and application thereof to a polymer.

公开(公告)号：US20130005920A1

公开(公告)日：2013-01-03

申请号：US13612456

申请日：2012-09-12

Applicant: Jiang-Jen Lin ,  Wood-Hi Cheng ,  Yi-Fen Lan ,  Jin-Chen Chiu ,  Jhe-Wei Lin ,  Chia-Ming Chang

Inventor： Jiang-Jen Lin ,  Wood-Hi Cheng ,  Yi-Fen Lan ,  Jin-Chen Chiu ,  Jhe-Wei Lin ,  Chia-Ming Chang

IPC: C08L79/08

CPC classification number: C08L79/08 ,  B82Y30/00 ,  C08J3/2053 ,  C08J5/005 ,  C08J2379/08 ,  C08K3/041 ,  H05K9/009

Abstract: A CNT-PI complex primarily includes polyimide (PI) and carbon nanotubes (CNT) dispersed in the polyimide. The method for producing the CNT-PI complex first disperses carbon nanotubes in a solvent by adding a dispersant and using an ultrasonic oscillator. Then the carbon nanotubes dispersion is mixed with polyamic acid to give a CNT-PI dispersion. The CNT-PI dispersion is then dried to form a film or layer of the CNT-PI complex. The dispersant used in this invention is an ionic liquid including organic cations and inorganic anions. The produced CNT-PI complex possesses good electromagnetic shielding effectiveness and presents better networked structures and electrical conductivity.

Abstract translation: CNT-PI复合物主要包括分散在聚酰亚胺中的聚酰亚胺（PI）和碳纳米管（CNT）。 CNT-PI络合物的制造方法首先通过添加分散剂并使用超声波振荡器将碳纳米管分散在溶剂中。 然后将碳纳米管分散体与聚酰胺酸混合，得到CNT-PI分散体。 然后将CNT-PI分散体干燥以形成CNT-PI复合物的膜或层。 用于本发明的分散剂是包括有机阳离子和无机阴离子的离子液体。 生产的CNT-PI复合物具有良好的电磁屏蔽效能，并具有更好的网络结构和导电性。