Abstract:
A fuse and filter arrangement for limiting and ameliorating electrode shorting in capacitive deionization water purification systems utilizing carbon aerogel, for example. This arrangement limits and ameliorates the effects of conducting particles or debonded carbon aerogel in shorting the electrodes of a system such as a capacitive deionization water purification system. This is important because of the small interelectrode spacing and the finite possibility of debonding or fragmentation of carbon aerogel in a large system. The fuse and filter arrangement electrically protect the entire system from shutting down if a single pair of electrodes is shorted and mechanically prevents a conducting particle from migrating through the electrode stack, shorting a series of electrode pairs in sequence. It also limits the amount of energy released in a shorting event. The arrangement consists of a set of circuit breakers or fuses with one fuse or breaker in the power line connected to one electrode of each electrode pair and a set of screens of filters in the water flow channels between each set of electrode pairs.
Abstract:
An electrically regeneratable electrochemical cell (30) for capacitive deionization and electrochemical purification and regeneration of electrodes includes two end plates (31, 32), one at each end of the cell (30). Two end electrodes (35, 36) are arranged one at each end of the cell (30), adjacent to the end plates (31, 32). An insulator layer (33) is interposed between each end plate (31, 32) and the adjacent end electrode (35, 36). Each end electrode (35, 36) includes a single sheet (44) of conductive material having a high specific surface area and sorption capacity. In one embodiment, the sheet (44) of conductive material is formed of carbon aerogel composite. The cell (30) further includes a plurality of generally identical double-sided intermediate electrodes (37-43) that are equidistally separated from each other, between the two end electrodes (35, 36). As the electrolyte enters the cell, it flows through a continuous open serpentine channel (65-71) defined by the electrodes, substantially parallel to the surfaces of the electrodes. By polarizing the cell (30), ions are removed from the electrolyte and are held in the electric double layers formed at the carbon aerogel surfaces of the electrodes. As the cell (30) is saturated with the removed ions, the cell (30) is regenerated electrically, thus significantly minimizing secondary wastes.
Abstract:
An apparatus and method for electrolytically treating water which includes one or more reactors. Each reactor has a liquid containing vessel and one or more pairs of electrodes. The electrodes are suitable for a continuous anodic or cathodic operation for treating water. A power source for each reactor provides voltage and current to the electrodes. A controller maintains the voltage and current provided to the electrodes. The duration of each voltage polarity applied to each electrode is substantially the same. The polarity of the voltage to the electrodes is periodically reversed during which there is a period of zero voltage applied to the electrodes between a first polarity and a second polarity. The period of zero voltage results in a substantial reduction of back e.m.f. of the reactor which enhances the service life and efficacy of the electrodes.
Abstract:
A production system of electrolyzed water includes an electrolyzer the interior of which is subdivided into an anode chamber and a cathode chamber by means of a cation permeable membrane, a diluted brine tank arranged to store an amount of diluted brine to be supplied into the anode and cathode chambers of the electrolyzer, first and second water supply conduits connecting the brine tank to the anode and cathode chambers respectively, and first and second electrically operated hydraulic pumps provided on the first and second water supply conduits to supply the diluted brine from the brine tank into the anode and cathode chambers. To prevent an electric motor for the hydraulic pumps from corrosion caused by backward flow of electrolyzed water in the production system, the hydraulic pumps are deactivated upon the lapse of a predetermined time after application of the DC voltage to an anode and a cathode in the anode and cathode chambers has been interrupted.
Abstract:
In a wet processing apparatus, an electrolytic cell, a first storing cell for storing anode active water of the electrolytic cell, a first processing cell for processing a target with the anode active water of the first storing cell, a second storing cell for storing cathode active water of the electrolytic cell, and a second processing cell for processing a target with the cathode active water of the second storing cell are provided. Also, a first reactivating feedback path is provided between the first processing cell and an anode region of the electrolytic cell, and a second reactivating feedback path is provided between the second processing cell and a cathode region of the electrolytic cell.
Abstract:
An electrochemical cell for capacitive deionization and electrochemical purification and regeneration of electrodes includes two oppositely disposed, spaced-apart end plates, one at each end of the cell. Two generally identical single-sided end electrodes, are arranged one at each end of the cell, adjacent to the end plates. An insulator layer is interposed between each end plate and the adjacent end electrode. Each end electrode includes a single sheet of conductive material having a high specific surface area and sorption capacity. In the preferred embodiment, the sheet of conductive material is formed of carbon aerogel composite. The cell further includes a plurality of generally identical double-sided intermediate electrodes that are equidistally separated from each other, between the two end electrodes. As the electrolyte enters the cell, it flows through a continuous open serpentine channel defined by the electrodes, substantially parallel to the surfaces of the electrodes. By polarizing the cell, ions are removed from the electrolyte and are held in the electric double layers formed at the carbon aerogel surfaces of the electrodes. As the cell is saturated with the removed ions, the cell is regenerated electrically, thus significantly minimizing secondary wastes.
Abstract:
A method of making water having a low salt content by desalination comprising the steps of alternately arranging pluralities of cation exchange membranes and monovalent anion selective anion exchange membranes or pluralities of anion exchange membranes and monovalent cation selective cation membranes between electrodes thereby alternately forming pluralities of the diluting cells and concentrating cells of an electrodialysis tank; feeding a salt containing water including hardly soluble salts to the plurality of diluting cells of the electrodialysis tank; feeding electricity to the electrodes; maintaining the salt concentration of the concentrated solution in the plurality of concentrating cells to a value of not less than 700 ppm; and retaining as much as possible the polyvalent anions forming the hardly soluble salts in the salt containing water.
Abstract:
A thin film electrocoagulation liquid treatment apparatus includes a nonconductive housing formed by opposite top and bottom walls, opposite side walls, and tubular end members with slots therethrough which define a treatment chamber. Pluralities of elongated electrodes extend between the side walls and are spaced along the top and bottom walls in spaced apart interleaved relation to define a serpentine fluid treatment path. The tubular end members form fluid connections, one end member receiving liquid to be treated from a supply conduit and the other discharging the treated liquid to a discharge conduit. A DC power supply has opposite poles thereof connected respectively to the sets of electrodes in such a manner that the polarity on succeeding electrodes is opposite. The first two electrodes in the flow direction of the fluid path are preferably connected to the negative pole of the power supply. A treatment process employing the treater apparatus includes pressure differential monitoring across the treater and flow direction reversal to avoid clogging the treater and temperature differential monitoring across the treater to optimize the consumption of electrical power by the process.
Abstract:
An apparatus for the production of sterilized and calcium-ion water includes: a housing structure; an electrolytic cell with electrical terminals and electrodes installed in the housing structure; a plurality of electromagnetic valves separately provided at a water-intake pipe and a water-drain pipe in communication with the electrolytic cell; a setting switch disposed in the housing structure and electrically coupled with the electrolytic cell for adjusting the current intensity of electrolysis therewith; a hydraulic-pressure switch provided at a water pressure pipe for the control of the water-level in the electrolytic cell; an ultraviolet sterilizing tank connected to the electrolytic cell for sterilizing the electrolyzed water; and a control circuit respectively coupled with the electrolytic cell, the electromagnetic valves and the setting and hydraulic switches; whereby, calcium-ion water can be effectively produced for drinking purposes.
Abstract:
An electrodeionization apparatus and process are provided for removing ions from liquids. Liquid to be purified is passed through depleting compartments containing mixed anion and cation exchange resin beads while a second liquid is passed through concentrating compartments free of ion exchange resin beads. Ions, under influence of a D.C. potential, pass from the depleting compartments into the concentrating compartments through ion permeable membranes. The beads in the depleting compartments are housed within subcompartments of controlled width and thickness and are retained therein by the ion permeable membranes which are secured to the wall of the subcompartments.