Asymmetric disulfides in lubricant compositions
    161.
    发明授权
    Asymmetric disulfides in lubricant compositions 失效
    润滑剂组合物中不对称二硫化物

    公开(公告)号:US4959167A

    公开(公告)日:1990-09-25

    申请号:US305834

    申请日:1989-02-02

    Applicant: Henri Dubas

    Inventor: Henri Dubas

    Abstract: Lubricant compositions or hydraulic fluid compositions containing(a) at least one lubricant or one hydraulic fluid and(b) at least one compound of the formula ##STR1## in which R.sup.1 and R.sup.2 are identical or different and are each an alkyl group having 1 to 30 C atoms, an unsubstituted or C.sub.1 -C.sub.8 alkyl-substituted cycloalkyl group having 5 to 12 C atoms or an unsubstituted or C.sub.1 -C.sub.12 -alkyl-substituted C.sub.6 -C.sub.10 aryl group, or R.sup.1 and R.sup.2 together are an unsubstituted or C.sub.1 -C.sub.12 alkyl-substituted alkylene group haivng 2 to 20 C atoms or an arylene group having 6 to 20 C atoms, and R.sup.5 and R.sup.6 are identical or different and are each an alkyl group having 1 to 30 C atoms, or R.sup.5 and R.sup.6 together are an unsubstituted or C.sub.1 -C.sub.12 alkyl-substituted alkylene group having 2 to 20 C atoms or an alkylene group which has 2 to 10 C atoms and is interrupted by --O--, --S-- or --NR.sup.9 --, in which R.sup.9 is H or C.sub.1 -C.sub.4 alkyl, and X is O or S.

    Abstract translation: 含有(a)至少一种润滑剂或一种液压油的润滑剂组合物或液压流体组合物和(b)至少一种式(I)的化合物,其中R 1和R 2相同或不同并且各自为烷基 具有1至30个C原子,未取代的或具有5至12个碳原子的C 1 -C 8烷基取代的环烷基或未取代或C 1 -C 12烷基取代的C 6 -C 10芳基,或者R 1和R 2一起是未取代的或C1- 具有2至20个C原子的C 12烷基取代的亚烷基或具有6至20个碳原子的亚芳基,R 5和R 6相同或不同,并且各自为具有1至30个碳原子的烷基,或者R 5和R 6一起为 未取代的或具有2〜20个碳原子的C 1〜C 12烷基取代的亚烷基或具有2〜10个碳原子并被-O - , - S-或-NR 9 - 中断的亚烷基,其中R 9为H或C1- C4烷基,X是O或S.

    Polymerization of cationic N,N-dimethylalkylamine type monomers
    165.
    发明授权
    Polymerization of cationic N,N-dimethylalkylamine type monomers 失效
    阳离子N,N-二甲基烷基胺型单体的聚合

    公开(公告)号:US4853447A

    公开(公告)日:1989-08-01

    申请号:US136108

    申请日:1987-12-21

    Abstract: A homogeneous free radical copolymerization process for the formation of a copolymer of acrylamide and an cationic monomer derive from allyl halide and N,N-dimethyl alkylamines which comprises the steps of:(a) forming a mixture of acrylamide monomer and the cationic monomer derive from allyl halide and N,N-dimethyl alkylamines and under a nitrogen atmosphere;(b) adding deoxygenated water to said mixture to form a homogeneous reaction solution;(c) adding a free radical initiator to said homogeneous reaction solution to initiate polymerization of said acrylamide monomer and said cationic monomer derived from allyl halide and N,N-dimethylalkylamines; and(d) copolymerizing said acrylamide monomer and said cationic monomer derive from said allyl halide and said N,N-dimethyl alkylamines at a sufficient temperature and for a sufficient period of time to form said copolymer of acrylamide without the formation of substantial amounts of particulates or phase separation occurring, said copolymer having an intrinsic viscosity of about 1 to about 10 dl/g, said copolymer having the formula: ##STR1## wherein n is 6 to 22 straight chained or branched alkyl or cycloalkyl group and X is about 90 to about 99.9 mole %, and Y is about 0.1 to about 10.0 mole %.

    Abstract translation: 用于形成丙烯酰胺和阳离子单体的共聚物的均匀的自由基共聚方法来自烯丙基卤化物和N,N-二甲基烷基胺,其包括以下步骤:(a)形成丙烯酰胺单体和阳离子单体的混合物,衍生自 烯丙基卤和N,N-二甲基烷基胺,并在氮气氛下; (b)向所述混合物中加入脱氧水以形成均匀的反应溶液; (c)向所述均相反应溶液中加入自由基引发剂以引发所述丙烯酰胺单体和衍生自烯丙基卤化物和N,N-二甲基烷基胺的所述阳离子单体的聚合; 和(d)使所述丙烯酰胺单体和所述阳离子单体在足够的温度下从所述烯丙基卤化物和所述N,N-二甲基烷基胺中共聚,并持续足够的时间以形成所述丙烯酰胺的共聚物,而不形成大量的颗粒 或相分离,所述共聚物的特性粘度为约1至约10dl / g,所述共聚物具有下式:其中n为6至22个直链或支链烷基或环烷基,X为约90至 约99.9摩尔%,Y为约0.1至约10.0摩尔%。

    Aqueous fluids thickened with fatty acid modified polyoxyalkylene
diamines
    170.
    发明授权
    Aqueous fluids thickened with fatty acid modified polyoxyalkylene diamines 失效
    用脂肪酸改性聚氧化烯二胺增稠的水溶液

    公开(公告)号:US4795581A

    公开(公告)日:1989-01-03

    申请号:US36650

    申请日:1987-04-10

    Abstract: Aqueous fluids are thickened with fatty acid modified polyoxyalkylene diamines. The polyoxyalkylene diamines are of the formula:H.sub.2 NCH(CH.sub.3)CH.sub.2 O(CH.sub.2 CH(R)O).sub.x CH.sub.2 CH(CH.sub.3)NH.sub.2wherein:R is methyl or hydrogen andx is a number selected to give the diamine a molecular weight of 3000 to 9000.The fatty acid is a hydrophobic mono- or dicarboxylaic acid of 12 to 36 carbon atoms. The ratio of amine equivalent: acid ranges from 1:0.5 to 1:1.The aqueous fluids optionally incorporate ethylene glycol. They are useful for water/glycol based hydraulic fluids, cosmetics and surfactants.

    Abstract translation: 水性流体用脂肪酸改性聚氧化烯二胺增稠。 聚氧化烯二胺具有下式:H 2 NCH(CH 3)CH 2 O(CH 2 CH(R)O)x CH 2 CH(CH 3)NH 2其中:R是甲基或氢,x是选定的数字,得到二胺的分子量为3000-9000。 脂肪酸是12至36个碳原子的疏水单羧酸或二羧酸。 胺当量:酸的比例为1:0.5至1:1。 含水流体任选地加入乙二醇。 它们可用于水/乙二醇型液压油,化妆品和表面活性剂。

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