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    Process for producing polymer
    11.
    发明申请
    Process for producing polymer 审中-公开
    生产聚合物的方法

    公开(公告)号：US20090209715A1

    公开(公告)日：2009-08-20

    申请号：US11921767

    申请日：2006-06-09

    Applicant: Kazuei Ohuchi ,  Daisuke Fukushima ,  Hideyuki Higashimura

    Inventor： Kazuei Ohuchi ,  Daisuke Fukushima ,  Hideyuki Higashimura

    IPC: C08F232/00 ,  C08F226/06 ,  C08F24/00

    CPC classification number: C08G61/125 ,  C08G73/10 ,  C09K11/06 ,  C09K2211/1416 ,  C09K2211/145 ,  H01L51/0035 ,  H01L51/0039 ,  H01L51/5012 ,  H05B33/14

    Abstract: A process for producing a polymer, characterized by comprising the following step (A) and step (B). (A) A step in which a polymer having repeating units represented by the general formula (1): —Ar1— (wherein Ar1 represents an arylene, divalent heterocyclic, or divalent aromatic amine group having at least one C—H bond on the aromatic ring) is used as a raw material and one or more of the C—H bond(s) on the aromatic ring are converted to thereby produce a polymer having repeating units which have one or more characteristic groups X and are represented by the general formula (2): (wherein X represents a characteristic group; Ar2 represents an arylene group, heterocyclic group, or aromatic amine group which each has a valence of n+2 and in each of which n of the C—H bonds on the aromatic ring of Ar1 have been converted into a C—X bond; and n is an integer of 1-4) (hereinafter, this polymer is referred to as polymer having the characteristic group (X)). (B) A step in which the polymer having the characteristic group (X) produced in the step (A) is reacted with a compound having a characteristic group (Y) which reacts with the characteristic group (X) to form a bond.

    Abstract translation: 一种制备聚合物的方法，其特征在于包括以下步骤（A）和步骤（B）。 （A）具有由通式（1）表示的重复单元的聚合物：-Ar1-（其中Ar1表示亚芳基，二价杂环，或芳香环上具有至少一个CH键的二价芳香族胺基） 用作原料，将芳环上的一个或多个CH键转化成由具有一个或多个特征基团X并由通式（2）表示的重复单元的聚合物： （其中X表示特征基团; Ar 2表示各自具有n + 2的化合价的亚芳基，杂环基或芳香族胺基，并且其中Ar1芳香环上的n个nN都已转化为 CX键; n为1-4的整数）（以下，将该聚合物称为具有特征基团（X）的聚合物）。 （B）将具有在步骤（A）中制造的特征基团（X）的聚合物与具有与特征基团（X）反应的特征基团（Y）的化合物反应以形成键的步骤。

    Cyclic compound, its metal complex and modified metal complex
    16.
    发明授权
    Cyclic compound, its metal complex and modified metal complex 有权
    环状化合物，其金属络合物和改性金属络合物

    公开(公告)号：US08546291B2

    公开(公告)日：2013-10-01

    申请号：US12811025

    申请日：2008-09-05

    Applicant: Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura ,  Yusuke Ishii

    Inventor： Tadafumi Matsunaga ,  Nobuyoshi Koshino ,  Hideyuki Higashimura ,  Yusuke Ishii

    IPC: B01J31/22 ,  C07D471/22 ,  C07D487/22 ,  C07F15/06 ,  C07F19/00 ,  C07F15/04 ,  C07F1/08 ,  C08F26/06

    CPC classification number: H01M4/8652 ,  C07D207/335 ,  C07D471/04 ,  C07D471/22 ,  C07D487/22 ,  H01G9/2018 ,  H01L51/0083 ,  H01L51/009 ,  H01M4/9008 ,  H01M4/9075 ,  H01M4/9091 ,  H01M4/923 ,  H01M4/925 ,  H01M4/928 ,  H01M8/0289 ,  H01M8/1016 ,  Y02E10/542 ,  Y02E60/521

    Abstract: A compound represented by formula (1): wherein Y1 to Y4 each independently represent any one of the following groups: in which Rα represents a hydrogen atom or a monovalent hydrocarbon group; P1 to P4 each independently represent a group of atoms necessary for forming a heterocyclic ring together with each of Y1 to Y4 and the two carbon atoms adjacent to each of Y1 to Y4, respectively; P5 and P6 each independently represent a group of atoms necessary for forming a cyclic skeleton together with the carbon atom to which Z1 bonds or Z2 bonds and the two carbon atoms adjacent to the carbon atom to which Z1 bonds or Z2 bonds; P1 and P2, P2 and P6, P6 and P4, P4 and P3, P3 and P5, and P5 and P1 may further combine with each other to form a ring; Q1 and Q2 each independently represent a connecting group or a direct binding; and Z1 and Z2 each independently represent any one of the following groups; —NRβ2, —ORβ, —SRβ, —PRβ2 in which Rβ represents a hydrogen atom or a monovalent hydrocarbon group, and when plural Rβs are present, these plural Rβs may be the same or different from each other.

    Abstract translation: 由式（1）表示的化合物：其中Y 1至Y 4各自独立地表示以下基团中的任一个：其中Ralpha表示氢原子或一价烃基; P1〜P4各自独立地表示与Y 1〜Y 4中的每一个以及Y1〜Y4中的每个相邻的2个碳原子一起形成杂环所需的原子团。 P5和P6各自独立地表示与Z1键或Z2键以及与Z1键或Z2键相邻的碳原子相邻的两个碳原子一起形成环状骨架所必需的一组原子; P1和P2，P2和P6，P6和P4，P4和P3，P3和P5，P5和P1可以进一步组合形成环; Q1和Q2各自独立地表示连接基团或直接结合; Z1和Z2各自独立地表示以下基团中的任何一个; -NRbeta2，-ORbeta，-SRbeta，-PRbeta2，其中Rbeta表示氢原子或一价烃基，当存在多个Rbetas时，这些多个Rbetas可以相同或不同。

    LAYERED STRUCTURE, ELECTRONIC DEVICE USING SAME, AROMATIC COMPOUND, AND METHOD FOR MANUFACTURING SAID COMPOUND
    17.
    发明申请
    LAYERED STRUCTURE, ELECTRONIC DEVICE USING SAME, AROMATIC COMPOUND, AND METHOD FOR MANUFACTURING SAID COMPOUND 有权
    层状结构，使用其的电子设备，芳族化合物和制造化合物的方法

    公开(公告)号：US20130119369A1

    公开(公告)日：2013-05-16

    申请号：US13812678

    申请日：2011-07-29

    Applicant: Arihiro Yashiro ,  Hideyuki Higashimura ,  Rui Ishikawa ,  Masanobu Tanaka

    Inventor： Arihiro Yashiro ,  Hideyuki Higashimura ,  Rui Ishikawa ,  Masanobu Tanaka

    IPC: H01L51/00

    CPC classification number: H01L51/0035 ,  C07C211/56 ,  C07C211/63 ,  C07D209/86 ,  C07F5/025 ,  C07F9/5407 ,  C07F9/5442 ,  C07F9/5456 ,  C07F9/5728 ,  C08G61/12 ,  C08G2261/1424 ,  C08G2261/312 ,  C08G2261/3162 ,  C08G2261/411 ,  C08G2261/512 ,  C08G2261/91 ,  C08G2261/92 ,  C08G2261/95 ,  H01L51/5056 ,  Y02E10/549 ,  Y02P70/521

    Abstract: The present invention provides: a layered structure having a substrate and a hole injection and/or hole transport layer comprising an aromatic compound having, on a side chain, at least one type of group having a cationic center;an electronic device having the layered structure; an aromatic compound having, on a hydrocarbon side chain, at least one type of group having a cationic center; an aromatic compound having a leaving group on a hydrocarbon side chain; and a method for manufacturing the aromatic compound having, on a hydrocarbon side chain, at least one type of group having a cationic center, the method comprising reacting the aromatic compound having a leaving group on a hydrocarbon side chain with a specific nitrogen compound, phosphorus compound, sulfur compound, or a combination of two or more of these compounds, thereby converting the aromatic compound into an onium salt thereof. When used as an electronic device material, and particularly as a hole transport and/or hole injection material, the aromatic compound can achieve a higher current density at a given voltage.

    Abstract translation: 本发明提供：具有基材和空穴注入和/或空穴传输层的层状结构，所述空穴注入和/或空穴传输层包含芳族化合物，所述芳族化合物在侧链上具有至少一种具有阳离子中心的基团; 具有层状结构的电子设备; 在烃侧链上具有至少一种具有阳离子中心的基团的芳族化合物; 在烃侧链上具有离去基团的芳族化合物; 以及在烃侧链具有至少一种具有阳离子中心的基团的芳香族化合物的制造方法，其特征在于，使烃侧链上具有离去基团的芳香族化合物与特定的氮化合物反应， 化合物，硫化合物或两种或更多种这些化合物的组合，从而将芳族化合物转化成其鎓盐。 当用作电子器件材料，特别是用作空穴传输和/或空穴注入材料时，芳族化合物可以在给定电压下实现更高的电流密度。

    LUMINESCENT SILVER COMPLEX
    18.
    发明申请
    LUMINESCENT SILVER COMPLEX 审中-公开
    发光银复合物

    公开(公告)号：US20110309304A1

    公开(公告)日：2011-12-22

    申请号：US13131993

    申请日：2009-11-30

    Applicant: Norifumi Kobayashi ,  Hideyuki Higashimura ,  Katsuhiro Suenobu

    Inventor： Norifumi Kobayashi ,  Hideyuki Higashimura ,  Katsuhiro Suenobu

    IPC: C09K11/06 ,  C07F5/02 ,  C07F15/00

    CPC classification number: C07F9/5045 ,  C07F1/005 ,  C07F9/5345 ,  C08K5/0091 ,  C09K11/06 ,  C09K2211/188 ,  H01L51/0091 ,  H01L51/5016

    Abstract: An luminescent device material which is inexpensive and exhibits excellent durability in the presence of oxygen can be provided using a luminescent silver complex which has an organic multidentate ligand, particularly, a luminescent silver complex wherein the organic multidentate ligand is coordinated to a phosphorus atom, a nitrogen atom, an oxygen atom, a sulfur atom, an arsenic atom, an oxygen anion, a nitrogen anion, or a sulfur anion, or a polymer of the luminescent silver complex.

    Abstract translation: 可以使用具有有机多齿配体的发光银络合物，特别是其中有机多齿配体与磷原子配位的发光银络合物，提供廉价且在氧存在下表现出优异的耐久性的发光器件材料 氮原子，氧原子，硫原子，砷原子，氧阴离子，氮阴离子或硫阴离子，或发光性银络合物的聚合物。

    Peroxide decomposition catalyst
    19.
    发明授权
    Peroxide decomposition catalyst 有权
    过氧化物分解催化剂

    公开(公告)号：US07988944B2

    公开(公告)日：2011-08-02

    申请号：US11993892

    申请日：2006-06-20

    Applicant: Takeshi Ishiyama ,  Hideyuki Higashimura ,  Hiroshi Takigawa

    Inventor： Takeshi Ishiyama ,  Hideyuki Higashimura ,  Hiroshi Takigawa

    IPC: C01B13/00 ,  G01N33/44 ,  C07F3/12

    CPC classification number: B01J31/2243 ,  B01J23/30 ,  B01J23/34 ,  B01J31/1815 ,  B01J31/183 ,  B01J31/2239 ,  B01J2531/0216 ,  B01J2531/025 ,  B01J2531/0258 ,  B01J2531/16 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845

    Abstract: An object of the present invention is to provide a catalyst which decomposes a peroxide effectively and economically under a high temperature while suppressing generation of free radicals, and the present invention provides a peroxide decomposition catalyst containing a base metal atom, wherein a value A indicating a free radical generation amount represented by the (equation 1) is not more than 0.20, and a value B indicating a reaction rate represented by the (equation 2), which can be easily applied to utility such as an agent for preventing deterioration of a polymer electrolyte-type fuel cell and a water electrolysis apparatus, and an antioxidant for medicaments, agrochemicals and foods. A=(Mw(S)/Mw)−1  (equation 1) (wherein Mw is a weight average molecular weight of poly(sodium 4-styrenesulfonate) after a hydrogen peroxide decomposition test in the test at 80° C. in the presence of poly(sodium 4-styrenesulfonate), and Mw(S) is a weight average molecular weight of poly(sodium 4-styrenesulfonate) before the test) B=N(PO)/N(cat)  (equation 2) (wherein N(po) is a mole number of hydrogen peroxide decomposed per 20 minutes in a hydrogen peroxide decomposition test in the (equation 1), and N(cat) is a mole number per metal atom of a catalyst used).

    Abstract translation: 本发明的目的在于提供一种在高温下有效且经济地分解过氧化物同时抑制自由基产生的催化剂，本发明提供了含有贱金属原子的过氧化物分解催化剂，其中A表示 由（式1）表示的自由基产生量不大于0.20，表示由（式2）表示的反应速度的值B，其可以容易地应用于防止聚合物劣化的试剂 电解质型燃料电池和水电解装置，以及用于药物，农药和食品的抗氧化剂。 A =（Mw（S）/ Mw）-1（式1）（式中，Mw是在80℃下在过氧化氢分解试验中聚（4-苯乙烯磺酸钠）的重均分子量， 的聚（4-苯乙烯磺酸钠），Mw（S）是试验前的聚（4-苯乙烯磺酸钠）的重均分子量）B = N（PO）/ N（cat）（式2）（式中，N （po）是在（式1）的过氧化氢分解试验中每20分钟分解的过氧化氢的摩尔数，N（cat）是使用的催化剂的每个金属原子的摩尔数）。

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